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Communication

In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives

1
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
2
BGI, BGI-Shenzhen, Shenzhen 518083, China
3
Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 210009, China
*
Author to whom correspondence should be addressed.
These authors contributed equally to this work.
Academic Editors: Akio Baba and Makoto Yasuda
Received: 20 March 2018 / Revised: 19 April 2018 / Accepted: 20 April 2018 / Published: 23 April 2018
(This article belongs to the Special Issue Indium in Organic Synthesis)
A combined Lewis acid system comprising of two or more Lewis acids occasionally exhibits augmented catalytic activity in organic transformations which are otherwise unrealizable by either of the components exclusively. On the other hand, the efficient construction of multiple new C-C bonds and polycyclic structures in minimal steps remains a subject of great interest in both academia and industry. Herein we report an efficient method to assemble aryldihydronaphthalene derivatives via a cascade reaction of diarylalkynes with acrylates under the catalysis of a combined Lewis acid derived from In(III) salt and TMSBr. View Full-Text
Keywords: indium; combined Lewis acid; catalysis; cascade reaction; aryldihydronaphthalene indium; combined Lewis acid; catalysis; cascade reaction; aryldihydronaphthalene
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MDPI and ACS Style

Zhang, Q.-C.; Zhang, W.-W.; Shen, L.; Shen, Z.-L.; Loh, T.-P. In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives. Molecules 2018, 23, 979. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules23040979

AMA Style

Zhang Q-C, Zhang W-W, Shen L, Shen Z-L, Loh T-P. In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives. Molecules. 2018; 23(4):979. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules23040979

Chicago/Turabian Style

Zhang, Qiu-Chi, Wen-Wei Zhang, Liang Shen, Zhi-Liang Shen, and Teck-Peng Loh. 2018. "In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives" Molecules 23, no. 4: 979. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules23040979

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