Rapid Determination and Quality Control of Pharmacological Volatiles of Turmeric (Curcuma longa L.) by Fast Gas Chromatography–Surface Acoustic Wave Sensor
Abstract
:1. Introduction
2. Results
2.1. Retention Index Calibration
2.2. Turmeric Ample GC-SAW Test
2.3. Turmeric Sample GC-MS Test
2.4. Principal Component Analysis and Cluster Analysis of the Turmeric Samples
3. Materials and Methods
3.1. Materials
3.2. GC-SAW Analytical Conditions
3.3. GC-SAW Retention Index Calibration Method and Sample Analysis
3.4. Headspace Solid-Phase Micro-Extraction Method
3.5. GC-MS Analytical Conditions
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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No. | Time(s) | Retention Index | Pea Area |
---|---|---|---|
A | 0.56 | 600 | 1800 |
B | 0.94 | 700 | 2603 |
C | 1.62 | 800 | 3789 |
D | 2.56 | 900 | 2311 |
E | 3.90 | 1000 | 1563 |
F | 5.76 | 1100 | 3151 |
G | 7.84 | 1200 | 1746 |
H | 10.20 | 1300 | 842 |
I | 12.60 | 1400 | 1640 |
J | 14.86 | 1500 | 2273 |
K | 16.84 | 1600 | 2740 |
L | 18.58 | 1700 | 3051 |
M | 20.08 | 1800 | 1314 |
No. | Name | Molecular Formula | GC-MS Retention Time (min) | GC-MS Relative Content (%) | GC-SAW Relative Content (%) | Retention Index | MS Similarity (%) |
---|---|---|---|---|---|---|---|
1 | Ethanone, 1-(3-ethylcyclobutyl) | C8H14O | 7.326 | 3.15 | - | - | 84.58 |
2 | 2-Propyltetrahydropyran | C8H16O | 9.711 | 0.72 | - | 911 | 88.02 |
3 | Furan, 2-butyltetrahydro- | C8H16O | 10.333 | 0.25 | - | 981 | 88.38 |
4 | α-Phellandrene | C10H16 | 10.996 | 1.05 | - | 1011 | 92.82 |
5 | Eucalyptol | C10H18O | 11.514 | 1.04 | - | 1053 | 80.84 |
a | α-Terpineol | C10H18O | - | - | 0.12 | 1186 | - |
6 | Caryophyllene | C15H24 | 17.598 | 3.24 | 0.26 | 1414 | 98.26 |
7 | Trans-α-Bergamotene | C15H24 | 17.703 | 1.51 | 0.54 | 1457 | 89.67 |
8 | Humulene | C15H24 | 18.033 | 1.76 | - | 1450 | 90.76 |
9 | Curcumene | C15H22 | 18.276 | 22.78 | 9.10 | 1484 | 97.36 |
10 | (-)-Zingiberene | C15H24 | 18.422 | 7.5 | - | 1484 | 92 |
11 | β-Bisabolene | C15H24 | 18.595 | 5.86 | - | 1509 | 95.32 |
12 | β-sesquiphellandrene | C15H24 | 18.797 | 15.89 | 5.10 | 1525 | 96.94 |
b | Curcumol | C15H24O2 | - | - | 1.03 | 1572 | - |
13 | Turmerone | C15H22O | 19.663 | 0.44 | 69.63 | 1632 | 72.77 |
14 | ar-turmerone | C15H20O | 20.443 | 18.83 | 1667 | 90.99 | |
15 | Curlone | C15H22O | 20.87 | 4.61 | 1660 | 91.6 |
Category | Code | Origin of the Collected Turmeric Parts |
---|---|---|
First category | 20,19 | Lateral rhizome turmeric in Lotus Pond Market 3 Top rhizome turmeric in Lotus Pond Market 3 |
Second category | 7,14,18, | Lateral rhizome turmeric in Yin-an Village, Jianban Town Lateral rhizome turmeric in Yin-an Village, Jianban Town Lateral rhizome turmeric in Lotus Pond Market 1 |
Third category | 17,16,15,11,12, 13,9,10,8, | Lateral rhizome turmeric in Lotus Pond Market 2 Top rhizome turmeric in Lotus Pond Market 2 Top rhizome turmeric in Lotus Pond Market 1 Lateral rhizome turmeric in Yunnan Top rhizome turmeric in Yunnan Top rhizome turmeric in Tielu Town New Countryside Top rhizome turmeric in Zhagu Town, Muchuan County Top rhizome turmeric in Zhagu Town, Muchuan County Ungrouped turmeric in Zhagu Town, Muchuan County |
Fourth category | 5,6,4,2,3,1 | Ungrouped turmeric in Tielu Town, Muchuan county Ungrouped turmeric in Myanmar Ungrouped turmeric in Xintang village, Xinmin Town Ungrouped turmeric in Guangxi Yulin Ungrouped turmeric in Yunnan Ungrouped turmeric in Shilong Village, Longchi Town Ungrouped turmeric in Baijiawan Village, Longchi Town |
No. | Origins | Parts |
---|---|---|
1 | Turmeric in Tielu Town, Muchuan county | Ungrouped |
2 | Turmeric in Myanmar | Ungrouped |
3 | Turmeric in Xintang village, Xinmin Town | Ungrouped |
4 | Turmeric in Guangxi Yulin | Ungrouped |
5 | Turmeric in Yunnan | Ungrouped |
6 | Turmeric in Shilong Village, Longchi Town | Ungrouped |
7 | Turmeric in Yin-an Village, Jianban Town | Lateral rhizome |
8 | Turmeric in Zhagu Town, Muchuan County | Ungrouped |
9 | Turmeric in Zhagu Town, Muchuan County | Top rhizome |
10 | Turmeric in Zhagu Town, Muchuan County | Top rhizome |
11 | Turmeric in Yunnan | Lateral rhizome |
12 | Turmeric in Yunnan | Top rhizome |
13 | Turmeric in Tielu Town New Countryside | Top rhizome |
14 | Turmeric in Yin-an Village, Jianban Town | Lateral rhizome |
15 | Turmeric in Lotus Pond Market 1 | Top rhizome |
16 | Turmeric in Lotus Pond Market 2 | Top rhizome |
17 | Turmeric in Lotus Pond Market 2 | Lateral rhizome |
18 | Turmeric in Lotus Pond Market 1 | Lateral rhizome |
19 | Turmeric in Lotus Pond Market 3 | Top rhizome |
20 | Turmeric in Lotus Pond Market 3 | Lateral rhizome |
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Lu, Y.; Wang, J.; Shen, G.; Liu, J.; Zhu, H.; Zhao, J.; He, S. Rapid Determination and Quality Control of Pharmacological Volatiles of Turmeric (Curcuma longa L.) by Fast Gas Chromatography–Surface Acoustic Wave Sensor. Molecules 2021, 26, 5797. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules26195797
Lu Y, Wang J, Shen G, Liu J, Zhu H, Zhao J, He S. Rapid Determination and Quality Control of Pharmacological Volatiles of Turmeric (Curcuma longa L.) by Fast Gas Chromatography–Surface Acoustic Wave Sensor. Molecules. 2021; 26(19):5797. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules26195797
Chicago/Turabian StyleLu, Yanyan, Jianbo Wang, Gang Shen, Jiuling Liu, Hongwei Zhu, Junning Zhao, and Shitang He. 2021. "Rapid Determination and Quality Control of Pharmacological Volatiles of Turmeric (Curcuma longa L.) by Fast Gas Chromatography–Surface Acoustic Wave Sensor" Molecules 26, no. 19: 5797. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules26195797