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Article

Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants

NMR laboratory, Department of Chemistry, Moscow State University, Moscow, 119899, Russia
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Int. J. Mol. Sci. 2003, 4(3), 107-118; https://0-doi-org.brum.beds.ac.uk/10.3390/i4030107
Received: 5 August 2002 / Accepted: 5 November 2002 / Published: 25 February 2003
Complete analysis of 1H-NMR spectra of trans-1,2-dichlorocyclopentane and trans-1,2-dibromocyclopentane was performed with use of our total lineshape fitting algorithm VALISA. The resulting high precision spin-spin coupling constants were then applied to the problem of conformational analysis, yielding a continuos potential of pseudorotation for the studied compounds in CDCl3, CCl4, and CD3CN solutions. View Full-Text
Keywords: High resolution NMR; pseudorotation; NMR lineshape; cyclopentane conformations; VALISA High resolution NMR; pseudorotation; NMR lineshape; cyclopentane conformations; VALISA
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MDPI and ACS Style

Zubkov, S.V.; Chertkov, V.A. Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants. Int. J. Mol. Sci. 2003, 4, 107-118. https://0-doi-org.brum.beds.ac.uk/10.3390/i4030107

AMA Style

Zubkov SV, Chertkov VA. Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants. International Journal of Molecular Sciences. 2003; 4(3):107-118. https://0-doi-org.brum.beds.ac.uk/10.3390/i4030107

Chicago/Turabian Style

Zubkov, Sergei V., and Vyacheslav A. Chertkov 2003. "Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants" International Journal of Molecular Sciences 4, no. 3: 107-118. https://0-doi-org.brum.beds.ac.uk/10.3390/i4030107

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