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Article

Synthesis and Characterization of Molecularly Imprinted Polymers for Phenoxyacetic Acids

1
Department of Applied Chemistry, College of Science, P.R. China Agricultural University, Beijing 100094, P.R. China
2
College of Chemistry, Beijing Normal University, Beijing 100085, P.R.China
3
Institute for the Control of Agrochemicals, Ministry of Agriculture, P.R. China
*
Author to whom correspondence should be addressed.
Int. J. Mol. Sci. 2008, 9(1), 98-106; https://0-doi-org.brum.beds.ac.uk/10.3390/ijms9010098
Received: 13 February 2007 / Revised: 15 November 2007 / Accepted: 29 November 2007 / Published: 25 January 2008
(This article belongs to the Section Molecular Recognition)
2-methylphenoxyacetic acid (2-MPA), 2-methyl-4-chlorophenxyacetic acid (MCPA) and 4-chlorophenoxyacetic acid (4-CPA) were imprinted to investigate the cross-selectivities of molecularly imprinted polymers (MIPs). The result indicates that 2-MPA, which is similar in shape, size and functionality with phenoxyacetic herbicides, are suitable to be used as a suitable template to prepare the MIPs for retaining phenoxyacetic herbicides. To study the ion-pair interactions between template molecules and functional monomer 4-vinylpiridine (4-VP), computational molecular modeling was employed. The data indicate that the cross-selectivities of MIPs for phenoxyacetic acid herbicides depend on the binding energies of complexes. View Full-Text
Keywords: molecularly imprinted polymers; 2-methylphenoxyacetic acid (2-MPA); phenoxyacetic herbicides; molecular modeling molecularly imprinted polymers; 2-methylphenoxyacetic acid (2-MPA); phenoxyacetic herbicides; molecular modeling
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MDPI and ACS Style

Zhang, H.; Song, T.; Zong, F.; Chen, T.; Pan, C. Synthesis and Characterization of Molecularly Imprinted Polymers for Phenoxyacetic Acids. Int. J. Mol. Sci. 2008, 9, 98-106. https://0-doi-org.brum.beds.ac.uk/10.3390/ijms9010098

AMA Style

Zhang H, Song T, Zong F, Chen T, Pan C. Synthesis and Characterization of Molecularly Imprinted Polymers for Phenoxyacetic Acids. International Journal of Molecular Sciences. 2008; 9(1):98-106. https://0-doi-org.brum.beds.ac.uk/10.3390/ijms9010098

Chicago/Turabian Style

Zhang, Huiting, Tao Song, Fulin Zong, Tiechun Chen, and Canping Pan. 2008. "Synthesis and Characterization of Molecularly Imprinted Polymers for Phenoxyacetic Acids" International Journal of Molecular Sciences 9, no. 1: 98-106. https://0-doi-org.brum.beds.ac.uk/10.3390/ijms9010098

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