Nutrient Pollutants in Surface Water—Assessing Trends in Drinking Water Resource Quality for a Regional City in Central Europe
Abstract
:1. Introduction
2. Materials and Methods
2.1. Study Site
2.2. Scope and Methods of Research
3. Results and Discussion
3.1. Trend Analysis
3.2. Concentrations of Analysed Parameters in the Winter and Summer Half-Year
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References and Notes
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Indices | Range of Values | Arithmetic Mean (mg·dm−3) | 95% Confidence Interval | Median (mg·dm−3) | ||
---|---|---|---|---|---|---|
Minimum (mg·dm−3) | Maximum (mg·dm−3) | |||||
Ammonium nitrogen (NH4-N) | 0.02 | 1.60 | 0.35 | 0.30 | 0.41 | 0.24 |
Total Kjeldahl nitrogen (TKN) | 0.00 | 5.90 | 1.27 | 1.13 | 1.42 | 1.10 |
Nitrite nitrogen (NO2-N) | 0.00 | 0.13 | 0.03 | 0.03 | 0.04 | 0.03 |
Nitrate nitrogen (NO3-N) | 0.00 | 4.20 | 1.60 | 1.50 | 1.70 | 1.50 |
Total nitrogen (TN) | 0.80 | 7.40 | 2.89 | 2.71 | 3.08 | 2.80 |
Phosphates (PO4) | 0.02 | 0.43 | 0.15 | 0.14 | 0.17 | 0.13 |
Total phosphorus (TP) | 0.00 | 0.76 | 0.14 | 0.12 | 0.17 | 0.12 |
Indices | Range of Changes (mg·dm−3) | StandardDeviation (mg·dm−3) | Variation Coefficient (%) | Slope of the Trend (mg·dm−3·month−1) | Rank Statistics of the Trend (Kendall tau) | Test Statistic (Z) | Probability Test (p) |
---|---|---|---|---|---|---|---|
Ammonium nitrogen (NH4-N) | 1.58 | 0.32 | 89 | −0.0027 a | −0.197 a | −3.18 a | 0.001 |
Total Kjeldahl nitrogen (TKN) | 5.90 | 0.75 | 59 | −0.0053 a | −0.233 a | −3.57 a | <0.001 |
Nitrite nitrogen (NO2-N) | 0.13 | 0.02 | 68 | <0.0001 | 0.029 | 0.38 | 0.70 |
Nitrate nitrogen (NO3-N) | 4.20 | 0.56 | 35 | −0.0007 | −0.002 | −0.04 | 0.97 |
Total nitrogen (TN) | 6.60 | 0.98 | 34 | −0.0061 a | −0.145 a | −2.23 a | 0.03 |
Phosphates (PO4) | 0.41 | 0.09 | 57 | −0.0005 a | −0.147 a | −2.38 a | 0.02 |
Total phosphorus (TP) | 0.46 | 0.10 | 72 | −0.0007 | −0.121 | −1.59 | 0.11 |
Indices | Median | Quartile | The Values of Statistics (Z) | Probability Test (p) | ||||
---|---|---|---|---|---|---|---|---|
Q1 | Q3 | Q1 | Q3 | |||||
Winter | Summer | Winter | Summer | |||||
Ammonium nitrogen (NH4-N) | 0.31 a | 0.19 a | 0.19 | 0.63 | 0.11 | 0.30 | 3.68 a | <0.001 |
Total Kjeldahl nitrogen (TKN) | 1.1 | 1.1 | 0.8 | 1.5 | 0.8 | 1.6 | −0.45 | 0.65 |
Nitrite nitrogen (NO2-N) | 0.02 a | 0.04 a | 0.02 | 0.03 | 0.02 | 0.06 | −3.23 a | 0.001 |
Nitrate nitrogen (NO3-N) | 1.8 a | 1.4 a | 1.5 | 2.0 | 1.2 | 1.5 | 6.33 a | <0.001 |
Total nitrogen (TN) | 3.0 a | 2.6 a | 2.5 | 3.5 | 2.1 | 2.9 | 3.32 a | <0.001 |
Phosphates (PO4) | 0.11 | 0.15 | 0.09 | 0.16 | 0.09 | 0.23 | −1.75 | 0.08 |
Total phosphorus (TP) | 0.10 a | 0.14 a | 0.08 | 0.13 | 0.11 | 0.20 | −3.32 a | <0.001 |
Indices | Limit Values (mg·dm−3) for Class [10] | Frequency of Index Values (% of Samples) in the Class | Arithmetic Mean (mg·dm−3) (Water Class) | |||
---|---|---|---|---|---|---|
I | II | I | II | BGP | ||
Ammonium nitrogen (NH4-N) | ≤0.78 | ≤1.56 | 87.5 | 11.7 | 0.8 | 0.35 (I) |
Total Kjeldahl nitrogen (TKN) | ≤1 | ≤2 | 46.3 | 44.4 | 9.3 | 1.27 (II) |
Nitrate nitrogen (NO3-N) | ≤2.2 | ≤5 | 90.8 | 9.2 | 0 | 1.60 (I) |
Total nitrogen (TN) | ≤5 | ≤10 | 96.3 | 3.7 | 0 | 2.89 (I) |
Phosphates (PO4) | ≤0.2 | ≤0.31 | 81.7 | 10.8 | 7.5 | 0.15 (I) |
Total phosphorus (TP) | ≤0.2 | ≤0.4 | 87.7 | 9.8 | 2.5 | 0.14 (I) |
Indices | Permissible Values (mg·dm−3) for Water Treatment Category [58] | Frequency of Index Values (% of Samples) in Normative Rangefor a Given Water Treatment Category | ||||
---|---|---|---|---|---|---|
A1 | A2 | A3 | A1 | A2 | A3 | |
Ammonium (NH4) | 0.5 a | 1.5 b | 2.0 b | 73.3 c | 98.3 | 99.2 |
Total Kjeldahl nitrogen (TKN) | 1 a | 2 a | 3 a | 46.3 c | 90.7 c | 98.1 |
Nitrates (NO3) | 50 b | 50 b | 50 b | 100 | 100 | 100 |
Phosphates (PO4) | 0.4 a | 0.7 a | 0.7 a | 98.3 | 100 | 100 |
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Kanownik, W.; Policht-Latawiec, A.; Fudała, W. Nutrient Pollutants in Surface Water—Assessing Trends in Drinking Water Resource Quality for a Regional City in Central Europe. Sustainability 2019, 11, 1988. https://0-doi-org.brum.beds.ac.uk/10.3390/su11071988
Kanownik W, Policht-Latawiec A, Fudała W. Nutrient Pollutants in Surface Water—Assessing Trends in Drinking Water Resource Quality for a Regional City in Central Europe. Sustainability. 2019; 11(7):1988. https://0-doi-org.brum.beds.ac.uk/10.3390/su11071988
Chicago/Turabian StyleKanownik, Włodzimierz, Agnieszka Policht-Latawiec, and Wioletta Fudała. 2019. "Nutrient Pollutants in Surface Water—Assessing Trends in Drinking Water Resource Quality for a Regional City in Central Europe" Sustainability 11, no. 7: 1988. https://0-doi-org.brum.beds.ac.uk/10.3390/su11071988