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Review

Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids

Department of Chemical Engineering, Sami Shamoon College of Engineering, Basel/Bialik Sts., Beer-Sheva 8410001, Israel
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Received: 23 December 2019 / Revised: 9 January 2020 / Accepted: 15 January 2020 / Published: 18 January 2020
(This article belongs to the Special Issue Palladium-Catalyzed Reactions)
Polysaccharides derived from natural sources exhibit unique structures and functional groups, which have recently garnered them increased attention for their potential applicability as supports for metal catalysts. Renewable polysaccharide matrices were employed as supports for palladium complexes, with or without previous modification of the support, and were used in Suzuki cross-coupling of halobenzenes and phenylboronic acid derivatives. In this review, recent developments in the immobilization of palladium-based complexes are reported, including descriptions of the preparation procedures and catalytic activity of each system. In addition, the effects of the nature of the polymeric support and of the reaction conditions on catalytic performance are discussed. View Full-Text
Keywords: cross-coupling; heterogeneous catalysts; immobilization; palladium; polysaccharides Suzuki–Miyaura cross-coupling; heterogeneous catalysts; immobilization; palladium; polysaccharides Suzuki–Miyaura
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MDPI and ACS Style

Wolfson, A.; Levy-Ontman, O. Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids. Catalysts 2020, 10, 136. https://0-doi-org.brum.beds.ac.uk/10.3390/catal10010136

AMA Style

Wolfson A, Levy-Ontman O. Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids. Catalysts. 2020; 10(1):136. https://0-doi-org.brum.beds.ac.uk/10.3390/catal10010136

Chicago/Turabian Style

Wolfson, Adi, and Oshrat Levy-Ontman. 2020. "Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids" Catalysts 10, no. 1: 136. https://0-doi-org.brum.beds.ac.uk/10.3390/catal10010136

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