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Editorial

Organic Inorganic Hybrid Perovskite Solar Cells

Department of Materials Science and Engineering, McMaster University, 1280 Main St W, Hamilton, ON L8S 4L8, Canada
*
Author to whom correspondence should be addressed.
Submission received: 14 September 2021 / Accepted: 17 September 2021 / Published: 27 September 2021
(This article belongs to the Special Issue Organic Inorganic Hybrid Perovskite Solar Cells)
Much progress has been achieved in the commercialization of solar devices, especially perovskite solar cells, which have shown excellent transport properties and low fabrication costs [1]. The organic perovskite solar cells based on MAPbI3 and FAPbI3 showed a surprising power conversion efficiency (PCE) of more than 25%, as opposed to their initial PCE of 3.8% a decade ago, inspiring a new era for green energy development [2].
Despite the great PCE, the stability of such devices remains a major challenge. The organic perovskite would decompose in the air within several hours due to moisture attack and/or phase transition. Even with the encapsulation, the lifetime could only be extended to several thousand hours, far from enough for the commercialization. As a result, a great deal of effort has since been devoted to trying to enhance the perovskite stability [3], such as strain engineering method, interface engineering, or doping in the A/B/X sites in the ABX3 structure of perovskite [1,2,3]. Unfortunately, these quick trials did not extend the perovskite lifetime to any appreciable level, due not least to the debatable degradation mechanism, in particular, the influence of water molecules on the perovskite structure, in addition to the possible structural variations vis-a-vis the kinetics and thermodynamics. Therefore, such efforts were destined to be less than successful. This is what the Special Issue is all about, to fill the critical gap and propose fresh strategies accordingly, and even to extend the development to other systems and devices, such as the one involving glucose sensing [4].
Several contributions have worked from the root of the instability problem, providing inspiring fresh alternatives as potential solutions for this question. For example, Seunghyun Rhee et al. [1] provided the fundamental properties of perovskite materials and categorized the usages in various optoelectronic applications. In particular, they introduced the fundamental structure and characteristics of a halide-based perovskite layer and next highlighted the key factors for achieving high performance in each application: solar cells, light-emitting diodes, lasers, and photodetectors, which is followed by a description of the remaining challenges. Their review confirmed the high potential of perovskite as a universal material solution for a wide range of optoelectronic applications and enhanced the understanding of key properties in each application for their practical commercialization. In addition, they reviewed the prerequisite factors for those applications, which assisted the understanding of the recent progress of perovskite-based optoelectronic devices and the challenges that need to be solved for the commercialization.
Moreover, Alex F. Xu et al. [2] proposed a brand-new organic perovskite structure of suitable bandgap and stability. They discovered a stable hybrid perovskite, pyrrolidinium lead iodide (PyPbI3), via a simple drop casting method. The formed PyPbI3 exhibited a hexagonal structure, presenting not only excellent phase stability, but also high transport properties, which indicated that PyPbI3 is an environmentally stable OIHP material of great potential to be employed in perovskite PV applications. Thus, the proposed five-membered ring-based perovskite PyPbI3 provided essential steps towards resolving the long-term instability problems of PSCs. Based on this proposal, Xu et al. offered multi-dimensional perovskite as a potential solution by incorporating one-dimensional (1D) perovskitoid PyPbI3 [3]. The stability measurements indicated that 1D perovskitoid is much more stable than the commonly employed FA-based perovskite, whose device lifetime can be enhanced to more than one month after adding PyPbI3 as an absorbing layer, achieving huge progress towards the commercialization of PSCs. Based on the results of XRD, X-ray photoelectron spectroscopy (XPS), and FTIR, it was discovered that the hexagonal structure of PyPbI3, as well as the interatomic force between Py cation and PbI2 lattice, played an important role in the structural stability. Due to the strong interatomic forces between Py+ cations and inorganic cages, the low dimensional perovskite exhibited excellent environmental stability compared to the 3D perovskite, providing new inspiration to the advancement of perovskite solar cells design.
The present Special Issue on “Organic Inorganic Hybrid Perovskite Solar Cells” is of huge significance for the wide PSCs research community, as it provides a fresh structural maneuvering engineering method under the current materials framework by structural physics negotiation. A novel structure of enhanced lifespan and comparable bandgap of the favorite α-FAPbI3 has thus been synthesized, which provides not only thermodynamic but also kinetical warrant, extending the perovskite lifetime by more than 10-fold. Hopefully, these discoveries will be of help to the advance of PSC design and materials research in general.

Author Contributions

Writing—original draft preparation, R.T.W.; writing—review and editing, G.X. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Rhee, K.S.; An, K.; Kang, K.T. Recent advances and challenges in halide perovskite crystals in optoelectronic devices from solar cells to other applications. Crystals 2021, 11, 39. [Google Scholar] [CrossRef]
  2. Xu, A.F.; Wang, R.T.; Yang, L.W.; Liu, E.E.; Xu, G. An environmentally stable organic—Inorganic hybrid perovskite containing py cation with low trap-state density. Crystals 2020, 10, 272. [Google Scholar] [CrossRef] [Green Version]
  3. Xu, F.; Li, Y.; Liu, N.; Han, Y.; Zou, M.; Song, T. 1D perovskitoid as absorbing material for stable solar cells. Crystals 2021, 11, 241. [Google Scholar] [CrossRef]
  4. Yang, L.W.; Liu, E.E.; Xu, A.F.; Chen, J.Y.; Wang, R.T.; Xu, G. Improving linear range limitation of non-enzymatic glucose sensor by OH− concentration. Crystals 2020, 10, 186. [Google Scholar] [CrossRef] [Green Version]
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MDPI and ACS Style

Wang, R.T.; Xu, G. Organic Inorganic Hybrid Perovskite Solar Cells. Crystals 2021, 11, 1171. https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11101171

AMA Style

Wang RT, Xu G. Organic Inorganic Hybrid Perovskite Solar Cells. Crystals. 2021; 11(10):1171. https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11101171

Chicago/Turabian Style

Wang, Ryan T., and Gu Xu. 2021. "Organic Inorganic Hybrid Perovskite Solar Cells" Crystals 11, no. 10: 1171. https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11101171

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