Synthesis, Crystal Structure, and Luminescent Properties of a New Holmium(III) Coordination Polymer Involving 2,5-Dihydroxy-1,4-terephthalic Acid Dianion as Ligand
Abstract
:1. Introduction
2. Experimental
2.1. Materials and Method
2.2. Characterization
2.3. Synthesis of DHTA
2.4. Synthesis of {[Ho2(DHTA)3(H2O)5]·H2O}n (1)
2.5. X-Ray Crystallography
3. Results and Discussions
3.1. Structure Description
3.2. IR Analysis
3.3. Thermogravimetric Analysis
3.4. PXRD Analysis
3.5. Luminescent Properties
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Complex | 1 |
---|---|
Empirical formula | C24H24O24Ho2 |
Formula weight | 1026.29 |
Crystal system | Triclinic |
Space group | P |
Unit cell dimensions | a = 9.6617(17) Å, α = 100.617(3)° |
b = 11.902(2) Å, β = 92.765(2)° | |
c = 13.284(2) Å, γ = 106.715(2)° | |
Volume | 1429.6(4) Å3 |
Z | 2 |
Density (calculated) | 2.384 g/cm3 |
F(000) | 982 |
Theta range for data collection | 1.569 to 26.04° |
Independent reflections | 6362 [Rint = 0.0232] |
Goodness-of-fit on F2 | 1.078 |
Final R indices [I > 2 sigma(I)] | R1 = 0.0321, wR2 = 0.0819 |
R indices (all data) | R1 = 0.0360, wR2 = 0.0835 |
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Li, J.; Dun, L.; Zeng, F.; Li, C.; Su, Z. Synthesis, Crystal Structure, and Luminescent Properties of a New Holmium(III) Coordination Polymer Involving 2,5-Dihydroxy-1,4-terephthalic Acid Dianion as Ligand. Crystals 2021, 11, 1294. https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11111294
Li J, Dun L, Zeng F, Li C, Su Z. Synthesis, Crystal Structure, and Luminescent Properties of a New Holmium(III) Coordination Polymer Involving 2,5-Dihydroxy-1,4-terephthalic Acid Dianion as Ligand. Crystals. 2021; 11(11):1294. https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11111294
Chicago/Turabian StyleLi, Jiaqi, Linan Dun, Fanming Zeng, Chun Li, and Zhongmin Su. 2021. "Synthesis, Crystal Structure, and Luminescent Properties of a New Holmium(III) Coordination Polymer Involving 2,5-Dihydroxy-1,4-terephthalic Acid Dianion as Ligand" Crystals 11, no. 11: 1294. https://0-doi-org.brum.beds.ac.uk/10.3390/cryst11111294