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Article

Wet Oxidation of Fine Soil Contaminated with Petroleum Hydrocarbons: A Way towards a Remediation Cycle

1
Department of Civil and Architectural Engineering, University of Pavia, via Ferrata 1, 27100 Pavia, Italy
2
Department of Civil, Environmental, Architectural Engineering and Mathematics, University of Brescia, via Branze 43, 25123 Brescia, Italy
*
Author to whom correspondence should be addressed.
Submission received: 16 May 2018 / Revised: 4 June 2018 / Accepted: 6 June 2018 / Published: 8 June 2018

Abstract

:
The aim of this experimental study was to assess the feasibility of using a wet oxidation (WO) process for treating fine soil with a high level of total petroleum hydrocarbons (TPHs). Two samples of soil were spiked with two different contaminants (motor oil, and motor oil + diesel). The samples were subjected to a WO bench plant test, where the effect of the main process parameters (i.e., temperature and reaction time) on the removal of TPHs was investigated. Results show that the WO process is effective for the decontamination of hydrocarbons, and a strong reduction (>85%) can be obtained with the typical working conditions of a full-scale plant (temperature = 250 °C, reaction time = 30 min). The solid residue resulting from the WO process was characterized in order to evaluate the recovery options. In terms of chemical characterization, the contents of the pollutants comply with the Italian regulations for commercial and industrial site use. Moreover, the results of the leaching test suggested that these residues could be reused for ceramic and brick manufacturing processes.

1. Introduction

The rapid and effective removal of total petroleum hydrocarbons (TPHs) from soil can be theoretically obtained through chemical–physical treatments, such as solvent extraction, low temperature thermal desorption, or chemical oxidation. The application of these technologies enables the attainment of high TPHs removal efficiency, even if some drawbacks must be taken into account. For instance, when solvent extraction is applied, the toxicity of the solvent is an important factor, as traces of solvent may remain within the treated soil [1], thereby compromising its quality. On the other hand, for chemical oxidation, reagent costs have to be carefully evaluated during the design phase [2]; for instance, in Fenton’s process, high carbonate and bicarbonate concentrations in the soil (as well as the organic matter) can lead to a high dosage of reagents [3], with respect to the stoichiometric amount. Furthermore, the composition of the soil (in terms of granulometry) can also affect the decontamination process; to give an example, soils characterized by a high content of silt and clay cannot be treated effectively with cheaper biological processes, or by soil vapor extraction, because of their low air permeability. Moreover, due to the tendency of the fine fraction of soil to form aggregates, pre-treatments such as shredding could be necessary prior to the decontamination process, increasing the treatment costs.
In addition, it must be taken into account that due to the tendency of contaminants to accumulate in the fine fraction of soil [4], in many cases, that fraction is not treated, but instead directly landfilled, and the remediation cycle is not completed; something that occurs, as reported by Dermont et al. [5], in soil washing treatment. Another aspect to be taken into account is the change in the partition of the contaminant amongst the different fractions of the soils due to the washing process [6].
In recent times, the European Commission has adopted an ambitious Circular Economy Package [7], aiming to stimulate Europe’s transition towards a circular economy. The proposed actions will contribute to “closing the loop” of product life cycles through greater recycling and reuse, and will bring benefits for both the environment and the economy. Therefore, the technicians are motivated to improve or find alternative remediation technologies finalized to close the remediation cycle, and give a new life to waste.
A technology that can be useful in reaching the aforementioned targets is the wet oxidation (WO) process, which is reliable and effective in the treatment of a wide spectrum of organic aqueous waste, even toxic waste, produced by various branches of industrial activity [8,9], and sewage sludge [10].
Typical treatment conditions for sludge and hazardous wastes reported in the literature are as follows: 200–325 °C for temperature; 5000–17,500 kPa for pressure; and 15–120 min for the reaction time. The preferred COD load ranges from 10–80 kg·m−3.
One of the biggest advantages related to the WO process is that decontamination is obtained with low polluting output gases, composed mainly of CO2, water steam, and oxygen, without hazardous by-products and low organic content in the final residue [8,11,12]. In addition, the WO effluent can be conveniently treated in a conventional wastewater treatment plant because of its high biodegradability, and, in some cases, it could also be used as a carbon source for the denitrification process, and as a substrate for the production of biopolymers [12]. Moreover, other researchers have also demonstrated that WO effluent represents an interesting energy vector; in fact, if it is treated by anaerobic digestion, biogas can be produced, and electric and thermal energy could be recovered [13].
Today, about 200 plants are in operation around the world (two of them in Italy), mostly to treat waste streams from petrochemical, chemical, and pharmaceutical industries, as well as residual sludge from urban wastewater treatment [12]. Detailed reviews about the WO process and its application are reported in Debellefontaine and Foussard [8], and Bhargava et al. [14].
According to Italian regulations [15], the soil and stones not containing dangerous substances (classified using the European Waste Code 17 05 04 [16]) can be recovered, in simplified procedure, for the following uses: ceramic and brick manufacturing processes, environmental recovery, road embankments, and foundations. With the exception of the first recovery route, the release of pollutants (by means of a leaching test provided for UNI EN 1247-2 [17]) must be lower than the limit values reported in the regulations. According to Italian regulations, the simplified procedure (where no actual permission is necessary, only the notification of competent local authorities) is provided for a limited class of recovery operations that are completely defined by the law, both in terms of qualitative description, and the threshold quantities to be handled.
These residues could also be recovered by an ordinary procedure for further applications. The conventional use of fine particles falls mainly in the civil construction field, employed for the following uses: in the production of bitumen-based binder [18]; as unbound aggregate (usually mixed with lime) in road bases and subbases [19,20,21]; in the production of cement and concrete [22,23,24,25] and bricks [26,27]. These kinds of recovery could be limited due to the uncertainty regarding the physical properties of residues, and the effects on the products obtained.
The objective of this work was to carry out a detailed investigation of the WO technology as a treatment option for the decontamination of fine-grained soil, and to demonstrate that the remediation of the soil is achievable. To this end, two samples of fine soil, spiked with contaminants based on petroleum hydrocarbons, were subjected to the WO treatment. The first sample was contaminated with motor oil, while the second one was contaminated with a mix of motor oil and diesel only.
This work is original. In fact, few studies have been reported that deal with the chemical oxidation process for the treatment of wastewater originating from the soil washing process [28,29,30], or with hot water extraction combined with in situ wet oxidation for the removal of polycyclic aromatic hydrocarbons (PAHs) from soil [31,32]. To our knowledge, no research dealing solely with the direct application of the WO process for the remediation of contaminated soils has been published.

2. Materials and Methods

2.1. Soil Characteristics

For the tests, two samples of fine soil (about 90% of soil passes through an ASTM (American Society for Testing and Materials) 200 mesh sieve) were spiked with the following: motor oil (soil #1) and motor oil + diesel (soil #2).
The contamination with motor oil was carried out using a heavy-duty synthetic engine oil designed for the lubrication of diesel engines (15W-40 type), while the other contamination was achieved using a commercial diesel fuel.
The artificial contamination was carried out by spiking the contaminants on 5 kg of samples. Specifically, the soil samples were put into two different vessels, after which the contaminants were spread on the soils (by means of a spray equipment). The soils were also mixed with trowels. Two days of aging (in a covered basin) were also provided for.
The main characteristics of the soil samples (before and after the artificial contamination) are summarized in Table 1.
The soils, from the granulometric point of view, are similar to the fine fraction of residues derived from mining activities. About 90% of the soil tested is silt and clay.

2.2. WO Pilot Plant Characteristics

Lab-scale WO tests were carried out in a continuously stirred autoclave operated in batch mode. The reactor (volume = 1.95 L realized in Hastelloy C-276) is equipped with an electric heating jacket and a water-cooling system in order to control the reaction temperature (maximum tolerable temperature = 350 °C). The uniformity of the reaction is guaranteed by an internal mechanical stirrer. Pure oxygen is fed into the reactor by means of a supply system located on the top of the reactor’s cover, where a manometer is installed for pressure control (maximum tolerable pressure = 20,265 kPa). A programmable logic controller (PLC) allows the control of the temperature during the tests (Figure 1).

2.3. Experimental Procedure

The wet oxidation process can only be conducted on liquid matrices, so soil samples (soil #1 and soil #2) were diluted with tap water in order to obtain a suspension with a dry content of about 8%. Before beginning the WO tests, total suspended solids (TSS) and COD were detected in the suspensions (this parameter is important because the stoichiometric amount of oxygen to be fed into the reactor is calculated in accordance with the ideal gas law, and COD’s suspension value). In order to prevent any corrosion phenomena of the reactor (pH drops during the tests), the solution’s pH was adjusted to 13 by means of a concentrated solution of sodium hydroxide (0.1 M, Sigma-Aldrich, Milano, Italy).
For each test, 500 mL of the suspension was poured into the autoclave, and a pre-fixed amount of oxygen was fed into the reactor. Since oxygen can be a limiting factor for the kinetics of the WO process, all of the tests were conducted in over-stoichiometric conditions (1520 kPa and 2027 kPa for soil #1 and soil #2, respectively). By means of the PLC, the temperature was held constant during the experiment. At the end of the tests, oxidized samples were cooled down to the ambient temperature, and a gaseous phase was extracted from the reactor. Samples of oxidized suspensions were collected and analyzed. pH, TSS and heavy metals analyses were performed according to APHA, AWWA, and WEF standard methods [33], TPHs according to the USEPA 8015D2003 method [34], and polycyclic aromatic hydrocarbons (PAHs) according to the APAT-IRSA-CNR 25Q64 method [35].
For both of the soil solutions, seven oxidation tests were performed one by one at varying temperatures (200, 250, and 300 °C) and reaction times (30–120 min, with steps of 30 min); the experimental program is reported in Table 2. For each set of operating conditions, one wet oxidation test was performed.
The choice of the experimental conditions was based on the operating conditions usually adopted by the manager of an Italian full scale wet oxidation plant.
In order to evaluate the recovery options, a chemical characterization was performed on the solid residues generated by the wet oxidation test that provides the best performance (for soil #1) in terms of the removal of TPHs. In addition, the single stage leaching test was carried out.
The single stage leaching test was performed in water for 24 h according to UNI 12457-2 [17]. The sample was kept in contact with demineralized water (liquid to solid ratio (L/S) equal to 10 L·kg−1) for 24 h under stirring conditions (by means of an overhead mixer).
The chemical analysis of the leachate was carried out according to APHA, AWWA and WEF standard methods [33].

3. Results and Discussion

3.1. Results of WO Tests

The results of the WO tests performed on soils #1 and #2 are reported in Figure 2 and Figure 3, respectively. Both figures show with a dashed line the threshold (750 mg(TPHs)·kgdw−1) set by Italian law [36] for reusing the treated soil in commercial and industrial sites. It is important to observe that, in regards to the soil protection, there are no complete and coherent rules within the European Union (E.U.); only a few E.U. member states have specific legislation. There are, for instance, directives aimed at agriculture, water, and waste management, however they have a different kind of purpose, and are not sufficient to ensure an adequate protection level for all soils in Europe. For example, the comparative analysis among various environmental legislations regarding the contamination of soil with oil products in some European countries (Latvia, Estonia, Lithuania, Finland, Denmark, Norway, Italy, The Netherlands) [37], highlighted that the most precautionary limit is adopted by Latvia (1 mg·kg−1), while the highest target values are adopted by Finland (100–600 mg·kg−1). A few countries use two limit values as a function of the use of the soil after remediation (Italy), while others countries even use three limits (Latvia and Estonia).

3.1.1. Effect of Temperature

As expected, by increasing the reaction temperature (while keeping the reaction time constant at 30 minutes) the amount of hydrocarbons in the soil decreases (the higher the temperature, the higher the removal of TPHs). In both soils, at the highest temperature (300 °C) the residual amount of TPHs is substantially negligible (23 and 90 mg·kgdw−1 for soil #1 and #2, respectively), with removal yields close to 100%.
In both cases, the higher increase in the TPHs removal yield was recorded as passing from 200–250 °C, especially for soil #2, where the removal yield increased by about 30%, reaching, substantially, a plateau (this is demonstrated by the fact that in the test conducted at 300 °C, the removal yield only increased by 4%). These results are in agreement with the findings of reference [38], where a similar matrix (fine grains derived from a soil washing pilot plant) was tested.
From the results, it can be seen that independent of the kind of contamination (motor oil or a mix of motor oil and diesel), 250 °C represents the temperature at which the normative constraint of 750 mg(TPHs)·kgdw−1 can be reached.
In addition, at temperatures equal to or higher than 250 °C, in both soils the PAHs content was lower than the detection threshold foreseen by the analytical method (<0.01 mg·kgdw−1), revealing that the WO process is also effective on this class of compounds. The reduction of the PAHs content in the soil is an important goal, as these compounds are dangerous for human health (cancer is a primary human health risk of exposure to PAHs, as reported by Bostrom et al. [39]).

3.1.2. Effect of Reaction Time

These tests were performed at two different temperatures (250 and 200 °C for soil #1 and #2, respectively) in order to better investigate the effect of reaction time.
Operating with a severe temperature (tests performed on soil #1 at 250 °C), the increase in the reaction time definitely allows the reduction of the content of TPHs, even if the removal yield (η) only increases by 6% passing from 30 (η = 85%) to 120 min (η = 91%). This shows that, under those conditions, the oxidation process, substantially, reaches a plateau. Therefore, it is not convenient to use reaction times greater than 30 minutes, as the legislative constraints are already complied using this reaction time, and the additional environmental benefits obtained with higher reaction times are almost negligible.
By contrast, at a temperature of 200 °C (tests on soil #2), the removal of TPHs is more influenced by the reaction time. In fact, passing from 30–90 min, the amount of TPHs in the soil decreases by a further 27%, complying with the legislative limit of 750 mg(TPHs)·kgdw−1. No significant improvements in the TPHs reduction were obtained by extending the reaction time to 120 min.
These results also show that for hydrocarbons, up to a given point, the conversion of organic substances does not increase (reaching a plateau) even if reaction time and temperature are increased. In the scientific literature, similar results are reported for sewage sludge [12,40], or wastes from chemical industries [8].
From an operating point of view, it is also important to evaluate the value of pH obtained after the treatment, mainly because (1) effluent with low/high pH cannot be treated directly in a biological process, and (2) corrosion effects can reduce the service life of the plant (at low values of pH). The pH at the end of the reaction depends substantially on the kind of substance subjected to WO; therefore, the pH control is an important issue.
Figure 4 shows the relation between the pH of the solution and the reaction time. It can be observed that (1) the higher the content of contaminant in the soil (soil #2) the lower the final value of pH (6.8), and (2) by increasing the reaction time, the pH slightly decreases. This occurs due to the fact that during the WO process, the organic substance is converted into volatile fatty acids (VFAs), therefore the higher the amount of TPHs removed, the higher the amount of VFAs produced (and, consequently, the lower the pH of the solution); more details can be found in Debellefontaine and Foussard [8].
Finally, it seems that the final value of pH is affected by the amount of TPHs removed, rather than by the kind of contaminant.

3.1.3. COD Mass Balance

As concerns soil # 1, the COD removal yields varied from 38–78%. The results obtained by the mass balance (Figure 5) show that, despite the increase of temperature allows the attainment of high COD reduction (at 300 °C, the COD removal yield is 78%), only the increase in contact time lead to a lower content of COD in the solid fraction (at a temperature of 250 °C, a contact time of 120 minutes involves COD in solid equal to 2% of the initial total COD).
Therefore, the extraction of pollutants from the solid fraction could be the limiting factor for the entire remediation rate. Some authors [31,32] have investigated the extraction of PAHs (i.e., with hot water) and the subsequent wet oxidation. Moreover, Thomsen and Laturnus [41] showed that the application of an alkaline extraction prior to the wet oxidation could increase the degradation efficiency of organic pollutants.

3.2. Evaluation of WO Solid Residue Recovery Options

The contents of pollutants measured in soil #1 before and after the WO process (under the best oxidation conditions in terms of the highest removal of TPHs) are reported in Table 3. It can be noted that the solid residue resulting from WO treatment can be recovered in sites for commercial and industrial use (as reported in Legislative Decree n. 152/2006, and further modification).
As concerns nickel, although additional investigations were not carried out, the increase in concentration of the solid residue after WO could be due to the possible release of nickel from the reactor during the WO tests. In fact, nickel is the main component of the reactor alloy (i.e., Hastelloy C-276).
The results of the leaching test (according to UNI EN 12457-2) on the solid fraction obtained by the WO on soil #1 (under the oxidation conditions that enable the highest removal of TPHs) are reported in Table 4.
The release of nickel, total chromium, arsenic, and COD is higher than limit values for waste recovery in simplified procedure (according to Ministerial Decree n. 186/2006 [15]); this behavior is due to the high pH measured in the leachate (10.1). In fact, as reported by Jang et al. [42], the arsenic and the total chromium showed strong pH dependence of leaching. The releases are higher in acidic and alkaline conditions with respect to the values obtained for neutral pH. Similar behavior is observed for nickel [43]. Moreover, as concerns the COD, as reported by Andersson et al. [44], the increase of pH involves an enhancement in dissolved organic carbon release.
Although some pollutants are higher than the limit values set out by Ministerial Decree n. 186/2006, these residues could be recovered, in simplified procedure, for ceramic and brick manufacturing processes.

4. Conclusions

In this study, two samples of soil spiked with contaminants containing hydrocarbons were treated by the WO process. The soil was characterized by a high content of fine fraction, and different hydrocarbon contamination, both in terms of the kind of contaminants (motor oil and motor oil + diesel), and the concentrations.
The results obtained show that both the temperature and the reaction time influence the removal of TPHs. In fact, the lowest removal yields were obtained at the lowest temperature (200 °C) and reaction time (30 min). Generally, 30 min treatment at 250 °C is enough to respect the limit imposed by Italian law for the reuse of the treated soil; in those conditions, in fact, the TPHs removal rates are close to 95%. Moreover, at those conditions, negligible concentrations of PAHs are obtained after the treatment. Similar results can be reached at 200 °C, with 90 min of treatment.
As concerns the characterization of the solid residue obtained from WO treatment, with the aim of assessing recovery options, the results of chemical analysis and the leaching test suggest that these residues could be recovered for ceramic and brick manufacturing processes.
In conclusion, this study demonstrates that WO represents an effective process for the remediation of fine soils contaminated with TPHs and PAHs.

Author Contributions

M.C.C. and M. V. have designed the work and supervised the research activities. M.C. carried out data analysis and the manuscript drafting. A.A. and S.S. have edited the section concerning the evaluation of recovery options for the solid residues.

Acknowledgments

The authors are grateful to 3V Green Eagle, which supported the experimental activity within the official collaboration with the University of Pavia on the research “Advanced processes aimed to treat liquid waste and sludge”. The authors also wish to thank Eng. Sabrina Zanaboni, who performed the wet oxidation tests.

Conflicts of Interest

The authors declare no conflicts of interest.

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Figure 1. Wet oxidation reactor at lab-scale (a) and programmable logic controller (PLC) (b).
Figure 1. Wet oxidation reactor at lab-scale (a) and programmable logic controller (PLC) (b).
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Figure 2. Results obtained for soil #1. Initial pO2 = initial partial pressure of oxygen fed into the reactor. Dotted line represents the limit (750 mg(TPHs)·kgdw−1) imposed by Italian law for the reuse of the treated soil [36]. TPHs: total petroleum hydrocarbons.
Figure 2. Results obtained for soil #1. Initial pO2 = initial partial pressure of oxygen fed into the reactor. Dotted line represents the limit (750 mg(TPHs)·kgdw−1) imposed by Italian law for the reuse of the treated soil [36]. TPHs: total petroleum hydrocarbons.
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Figure 3. Results obtained for soil #2. Initial pO2 = initial partial pressure of oxygen fed into the reactor. Dotted line represents the limit (750 mg(TPHs)·kgdw−1) imposed by Italian law for the reuse of the treated soil [36].
Figure 3. Results obtained for soil #2. Initial pO2 = initial partial pressure of oxygen fed into the reactor. Dotted line represents the limit (750 mg(TPHs)·kgdw−1) imposed by Italian law for the reuse of the treated soil [36].
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Figure 4. Soils’ pH values after the wet oxidation (WO) treatment.
Figure 4. Soils’ pH values after the wet oxidation (WO) treatment.
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Figure 5. Results obtained for soil #1. COD balance after the WO treatment.
Figure 5. Results obtained for soil #1. COD balance after the WO treatment.
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Table 1. Characteristics of the soils treated by wet oxidation.
Table 1. Characteristics of the soils treated by wet oxidation.
ParameterMeasurement UnitSoil #1Soil #2
As RawMotor OilAs RawMotor Oil + Diesel
Contaminating medium
 Total Petroleum Hydrocarbons (TPHs)mg·kgdw−1<201455 ± 220<204736 ± 600
 Total Polycyclic Aromatic Hydrocarbons (PAHs)mg·kgdw−1<0.10.12 ± 0.10<0.10.20 ± 0.05
pH-n.a.8.0n.a.7.7
Granulometric fractions
 Sand%n.a.11n.a.10
 Silt%n.a.75n.a.76
 Clay%n.a.14n.a.14
dw: dry weight; n.a.: not available.
Table 2. Wet oxidation tests performed on the two samples of soils.
Table 2. Wet oxidation tests performed on the two samples of soils.
SoilTestTemperature
(°C)
Initial Partial Pressure of Pure Oxygen
(kPa)
Reaction Time
(min)
Soil #1A.1200152030
A.2250
A.3300
A.4250152030
A.560
A.690
A.7120
Soil #2B.1200202730
B.2250
B.3300
B.4250202730
B.560
B.690
B.7120
Table 3. Contents of pollutants in soil #1 before and after WO.
Table 3. Contents of pollutants in soil #1 before and after WO.
ParameterConcentration (mg·kgdw−1)Limit Value Legislative Decree n. 152 (2006) (mg·kgdw−1)
INOUT *Public, Private and Residential Use (A)Commercial and Industrial Use (B)
Cu54 ± 851 ± 8120600
Zn131 ± 16137 ± 161501500
Be2.8 ± 0.52.3 ± 0.4210
Co.37.6 ± 535.1 ± 520250
Ni198 ± 27239 ± 35120500
V78.5 ± 1056.2 ± 790250
As31.6 ± 518.0 ± 32050
Cd0.4 ± 0.060.3 ± 0.05215
CrTOT131 ± 18110 ± 15150800
Pb31 ± 429 ± 41001000
Se3.4 ± 0.53.3 ± 0.5315
Hg<0.1<0.115
Sb1 ± 0.14<11030
TPHs1455 ± 22023 ± 750750
PAHs0.12 ± 0.1<11100
* T: 300 °C, reaction time: 30 min, initial pO2: 1520 kPa. The bold values do not respect the limit values for public, private, and residential use (A), but are lower than limit values for commercial and industrial use (B).
Table 4. Results of leaching test (UNI EN 12457-2) on solid residue from WO (soil #1—T: 300 °C, reaction time: 30 min, initial pO2: 1520 kPa).
Table 4. Results of leaching test (UNI EN 12457-2) on solid residue from WO (soil #1—T: 300 °C, reaction time: 30 min, initial pO2: 1520 kPa).
ParameterConcentration
(mg·L−1)
Limit Values Ministerial Decree n. 186 (2006)
(mg·L−1)
NO3<150
F<0.21.5
SO42−7 ± 1250
Cl2 ± 0.4100
CN<0.0050.05
Ba<0.11
Cu<0.050.05
Zn<0.13
Be<0.0010.01
Co.0.014 ± 0.040.25
Ni0.105 ± 0.030.01
V0.16 ± 0.040.25
As0.1 ± 0.040.05
Cd<0.00050.005
CrTOT0.32 ± 0.080.05
Pb0.013 ± 0.0040.05
Se<0.0050.01
Hg<0.00050.001
COD111 ± 2030
pH10.15.5 ÷ 12
The bold values do not respect the normative limits for waste reuse in simplified procedure.

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Collivignarelli, M.C.; Vaccari, M.; Abbà, A.; Canato, M.; Sorlini, S. Wet Oxidation of Fine Soil Contaminated with Petroleum Hydrocarbons: A Way towards a Remediation Cycle. Environments 2018, 5, 69. https://0-doi-org.brum.beds.ac.uk/10.3390/environments5060069

AMA Style

Collivignarelli MC, Vaccari M, Abbà A, Canato M, Sorlini S. Wet Oxidation of Fine Soil Contaminated with Petroleum Hydrocarbons: A Way towards a Remediation Cycle. Environments. 2018; 5(6):69. https://0-doi-org.brum.beds.ac.uk/10.3390/environments5060069

Chicago/Turabian Style

Collivignarelli, Maria Cristina, Mentore Vaccari, Alessandro Abbà, Matteo Canato, and Sabrina Sorlini. 2018. "Wet Oxidation of Fine Soil Contaminated with Petroleum Hydrocarbons: A Way towards a Remediation Cycle" Environments 5, no. 6: 69. https://0-doi-org.brum.beds.ac.uk/10.3390/environments5060069

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