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Article

Thermo-Optical Properties of Thin-Film TiO2–Al2O3 Bilayers Fabricated by Atomic Layer Deposition

1
Institute of Photonics, University of Eastern Finland, P.O. Box 111, FI-80101 Joensuu, Finland
2
Center for Advance Studies in Energy (CAS-EN), National University of Sciences and Technology (NUST), Sector H-12, 44000 Islamabad, Pakistan
*
Authors to whom correspondence should be addressed.
Nanomaterials 2015, 5(2), 792-803; https://0-doi-org.brum.beds.ac.uk/10.3390/nano5020792
Submission received: 28 February 2015 / Revised: 10 May 2015 / Accepted: 13 May 2015 / Published: 18 May 2015
(This article belongs to the Special Issue Nanophotonic Materials)

Abstract

:
We investigate the optical and thermo-optical properties of amorphous TiO2–Al2O3 thin-film bilayers fabricated by atomic layer deposition (ALD). Seven samples of TiO2–Al2O3 bilayers are fabricated by growing Al2O3 films of different thicknesses on the surface of TiO2 films of constant thickness (100 nm). Temperature-induced changes in the optical refractive indices of these thin-film bilayers are measured by a variable angle spectroscopic ellipsometer VASE®. The optical data and the thermo-optic coefficients of the films are retrieved and calculated by applying the Cauchy model and the linear fitting regression algorithm, in order to evaluate the surface porosity model of TiO2 films. The effects of TiO2 surface defects on the films’ thermo-optic properties are reduced and modified by depositing ultra-thin ALD-Al2O3 diffusion barrier layers. Increasing the ALD-Al2O3 thickness from 20 nm to 30 nm results in a sign change of the thermo-optic coefficient of the ALD-TiO2. The thermo-optic coefficients of the 100 nm-thick ALD-TiO2 film and 30 nm-thick ALD-Al2O3 film in a bilayer are (0.048 ± 0.134) × 10−4 °C−1 and (0.680 ± 0.313) × 10−4 °C−1, respectively, at a temperature T = 62 °C.

1. Introduction

The continuous miniaturization of optical and photonic components with the growing inquisitiveness to explore atomic-scale phenomena has led researchers to develop innovative techniques to fulfill the requirements for atomic-level control. Atomic layer deposition (ALD), initially developed for the deposition of uniform thin-films over wide areas of electroluminescent display devices [1], is a unique method enabling an atomic-level control of film thickness and reproducible growth of defect-free films. It is cost effective and, thus, suitable for low-cost mass production. Research and development in ALD during recent years has led to a wide range of processes for new materials. In addition, the availability of ALD reactors has paved the way for further improving the precise atomic-level thickness control, achieving self-controlled alternating surface reactions, improving the wide area uniformity and obtaining continuous pinhole or defect-free films [2]. With ALD, high quality thin-films can be deposited even at room temperature [3], but also at high temperatures (up to 500 °C) [4]. One important feature of ALD is the excellent conformality of the deposited films over corrugated and/or zigzag surface profiles [5].
The ALD process is based on sequential self-limiting chemical reactions of alternating precursor molecules on the substrate surface at a given deposition temperature, which results in saturative surface reactions. A typical ALD process proceeds in cycles composed of four steps. During the first step, precursor “A” molecules are pulsed into the ALD chamber to chemisorb on the substrate surface followed by purging with an inert gas to remove excessive precursor molecules or any other reaction by-products (the second step). In the third step, the ALD chamber is pulsed with precursor “B” molecules, which react with precursor “A” molecules chemisorbed on the substrate surface and form the desired binary compound. This step is followed again by purging with an inert gas to remove non-reactive precursor “B” molecules and/or any reaction by-products (the fourth step). This one complete AB ALD cycle results in the deposition of a partial monolayer, typically with a thickness of around 0.1 nm/cycle. Several ABAB ALD cycles are needed to form a uniform and high-quality film [6,7].
Titanium dioxide (TiO2) is a widely-studied metal oxide material due to having a high relative dielectric constant, high melting point, stability at higher temperatures, low absorption in the visible and infrared wavelength regions and temperature-induced reflectivity [8,9]. ALD-deposited TiO2 has significant potential in nanophotonics applications [6]. An important aspect of ALD-deposited TiO2 films is the adsorption of water molecules during the growth process, which leads to a change in the refractive index of the films due to environmental effects, such as temperature, pressure and humidity. Such index changes can also be accompanied by a bandgap change of the dielectric films due to the adsorption of water or other hydrogenated species at interstitial positions [10].
In this paper, we propose to modify the thermo-optic coefficient of TiO2 thin-films by employing a TiO2–Al2O3 bilayer film (see Figure 1). This may be useful in various nanophotonic devices, e.g., if athermal optical properties are desired. Due to the excellent film uniformity and low surface roughness obtained by ALD, it is an ideal deposition method for the fabrication of TiO2–Al2O3 bilayers [11]. We study the thermo-optic coefficients of ALD-TiO2 films of a 100-nm thickness and the influence of the ALD-Al2O3 thin-films of different thicknesses (10–70 nm) as barrier layers, in order to validate the surface porosity model introduced earlier [10,12]. The proposed model explains the reduction of surface defects on TiO2 films due to the ALD-Al2O3 diffusion barrier layer and the reduction of the evaporation rate of water molecules from TiO2 films through the ALD-Al2O3 diffusion barrier layers. The concept is based on the assumption that the TiO2 surface maintains the same energy levels (bandgaps) after coating by ultra-thin ALD-Al2O3 diffusion barrier layers. This is because the interfacial energy levels may change significantly due to the evaporation rate of water molecules from the TiO2 surface and/or chemical reactions or environmental interactions.
The paper is organized as follows: Section 2 describes the fabrication, thermal measurements and the formulated optical model viable for the evaluation of ellipsometric parameters and stacked layer thicknesses through a polynomial fitting. Section 3 presents the experimental results and analysis of TiO2 films of 100-nm thickness coated by ALD-Al2O3 diffusion barrier layers with different thicknesses. Finally, conclusions are presented in Section 4.

2. Experiments and Data Analysis

2.1. Sample Fabrication

In this study, seven bilayer samples containing a 100 nm-thick amorphous TiO2 film and amorphous Al2O3 diffusion barrier layers with different thicknesses (from 10 nm to 70 nm) were fabricated by ALD on 2-inch silicon wafers with crystal orientation <100> by using a Beneq TFS 200-152 ALD reactor. The samples were not exposed to ambient environment between the depositions of the two layers. The employed wafers were doped with phosphorus (n-type), have a thickness of 380 ± 25 μm and a native oxide layer with a thickness of 2 nm. The thickness of each ALD-grown layer was measured by the Dektak-150 stylus surface profilometer from Veeco technology, and the values were confirmed by ellipsometry measurements. The precursor species for the deposition of TiO2 and Al2O3 thin-films were titanium tetrachloride (TiCl4) and trimethylaluminum (Al(CH3)3), respectively, as well as H2O. Nitrogen (N2) was used as a purging gas. During the processes, the ALD chamber and the reactor were maintained at pressures of 5 mbar and 2 mbar, respectively. The ALD chamber N2 flow was 200 sccm (standard cubic centimeters per minute), and the process N2 flow was 600 sccm. During the TiO2 film deposition, the TiCl4 pulse time was 150 ms, and the N2 purge time was 750 ms; whereas the H2O pulse time was 150 ms, and the N2 purge time was 1 s. After the deposition process, the temperature was set to 20 °C, and the gas ballast time was 5 min to stabilize the end of the deposition process. At the end of the deposition process, the TiCl4 gas line was purged with N2 gas for 2 min. TiO2 thin-film deposition was carried out at a temperature of 120 °C. Except for the Al precursor, the same deposition cycle parameters were used to deposit the Al2O3 thin-films. The growth rates of TiO2 and Al2O3 thin-films were 0.065 nm and 0.12 nm per cycle, respectively.

2.2. Thermal Measurement Setup

The thickness-, wavelength- and temperature-dependent refractive indices nn(tT,A, λ, T) of the bilayer TiO2 and Al2O3 thin-films were characterized by a variable angle spectroscopic ellipsometer VASE® with a High-Speed Monochromator System HS-190TM (manufactured by J.A. Woollam Co., Lincoln, NE, USA). It contains a continuously-rotating and adjustable wave plate analyzer, and a maximum beam spot size of 3 mm was used. The temperature-dependent refractive index of each bilayer sample was measured by a customized temperature-controlled heating device fabricated in-house. The heating device consists of an aluminum plate with adjustable mechanical clampers to hold the sample, thermocouples, a thermometer (manufactured by Fluke Corporation, Everett, WA, USA) and an adjustable power supply. The measurements were carried out for a temperature range from T = 22 °C to T = 102 °C with temperature steps of 10 °C and with a reading accuracy of ±0.1 °C. The temperature was precisely controlled by the adjustable power supply, and it was also measured by a Handheld Infrared Thermometer (Model Convir ST8811, manufactured by Calex Electronics Limited Co., Bedfordshire, UK). The measurements were done for a spectral range from 380 nm to 1800 nm with 5 nm wavelength steps. Three angles of incidence (59°, 67° and 75°) around the pseudo-Brewster angle were used in measurements for each temperature.

2.3. Structural Measurements

For structural characterization of the TiO2 and Al2O3 thin-film bilayers, the samples were sputter coated with a thin (less than 8 nm thick) conductive copper (Cu) by a K675X Turbo Large Chromium Coater 8. The sputter-coated samples were characterized by a scanning electron microscope (SEM), LEO 1550 Gemini. The surface morphology measurements of the ALD-TiO2–Al2O3 thin-film bilayers were carried out by an atomic force microscope (AFM, MultiMode® with High-Speed ScanAsyst-Air Mode, Bruker Co., Billerica, MA, USA). The tapping mode in air was employed, and the software Nanoscope Analysis Version 1.50 was utilized in the AFM image analysis. The surface roughness of each sample was measured by scanning a surface area of 1 μm × 1 μm of the sample.

2.4. Ellipsometry and Optical Model for Bilayer

As mentioned above, a variable angle spectroscopic ellipsometer was used to characterize and determine the optical properties of the fabricated samples. The analysis was carried out with WVASE32 ellipsometric data analysis software from J.A. Woollam Co., in terms of ellipsometric parameters Ψ and Δ to express the polarization state of a reflected light beam [12,13]. Figure 1 illustrates schematically the interaction of polarized light with a sample and also the porosity at the surface of the TiO2 layer. The varying angles of incidence in spectroscopic ellipsometry were set near the pseudo-Brewster angle to get the best sensitivity for the measured values of Δ [14].
In our optical model (see Figure 1), a polarized light (plane wave) illuminates a bilayer at an angle of incidence Φ. In this model, a 100 nm-thick (tT) TiO2 film is considered on a native oxide (SiO2) layer of ~2 nm in thickness (confirmed also with ellipsometry measurements). This, in turn, is on top of a 0.5 mm-thick Si substrate. On top of the TiO2 film, a thin layer of Al2O3 is added. Its thickness tA is varied from 10 nm to 70 nm. The model usesWVASE32 ellipsometry software in fitting the ellipsometric parameters Ψ and Δ to retrieve the experimentally-measured data at each wavelength within the defined spectral range. We did not add the layer of surface roughness and voids to the model (see Figure 1), since it would have been very difficult to properly add this non-uniform layer to the model. In addition, this layer would have a negligible effect, since the average surface roughness values of the TiO2 and Al2O3 nanoscale layers are only ≈1 nm. To assure the validity of this optical model, the errors were computed by a regressive algorithm and identified within a 90% confidence limit.

2.4.1. Retrieval of the Film Thickness and Optical Constants by Optical Models

The thicknesses and optical constants of TiO2 and Al2O3 in the fabricated thin bilayer films were extracted by a Cauchy model. The optical constants of the films in these bilayers, with a corresponding uncertainty (statistical deviation values), were calculated at a wavelength of 640 nm. The Cauchy dispersion formula and the corresponding uncertainty equations used are given below, respectively, in Equations (1) and (2) [15]:
n ( λ ) = A + B λ 2 + C λ 4
σ [ n ( λ ) ] = [ ( σ A ) 2 + ( σ B λ 2 ) 2 + ( σ C λ 4 ) 2 ]
Here, A, B and C are Cauchy parameters and the unit of wavelength is μm. The final values of Cauchy model parameters were determined by fitting the model-generated data to the experimental data.
Thermal measurements for the bare Si substrate, with a thin native oxide layer, were first carried out for the temperature range from T = 22 °C to T = 102 °C, as described in Section 2.2. The thermal results for the Si substrate were added as the default for each temperature point in the beginning of the modeling scheme. The thermal data for the SiO2 layer embedded in the WVASE32 software was used. The appropriate minimum and maximum thickness values of each layer in the bilayer, together with the initial values of Cauchy parameters, were assigned using the edit fitting parameters. Upon optimum fitting between the experimental and the model data, the thickness and optical constants of each layer in the bilayer were determined, at a wavelength of 640 nm. Figure 2 shows room temperature spectroscopic ellipsometric measurements, in terms of ellipsometric parameters Ψ and Δ fitted by the Cauchy model at three angles (59°, 67° and 75°), for a bilayer consisting of a 100 nm-thick TiO2 layer and a 30 nm-thick Al2O3 layer.

2.4.2. Polynomial Fitting by Regression Algorithm

Finally, the thermo-optic coefficients for each layer in the bilayer along with their uncertainties were calculated using the refractive index data calculated at a 640 nm wavelength and employing a polynomial fitting algorithm. The procedure of this polynomial fitting is explained in detail in [16,17]. In our case, the thermo-optic coefficients and the associated standard uncertainties are at the 90% level of confidence.

3. Results and Discussion

Thermo-optic coefficients of the bilayers comprising a 100 nm-thick ALD-TiO2 film and ALD-Al2O3 films of different thicknesses, from 10 nm to 70 nm, were evaluated after fitting the experimentally-measured data. To illustrate the high quality of these bilayers, Figure 3 shows an SEM image of a cross-section of a bilayer with 20 nm-thick ALD-Al2O3 diffusion barrier layer to protect the TiO2 surface from water vapor evaporation.
It has been previously reported that TiO2 films possess negative thermo-optic coefficients due to the desorption of H2O and OH species at the OH–H2O surface-bound sites [12,18,19]. The adsorption of water molecules either undergoes dissociations at particular defect sites or they are adsorbed molecularly. Such evaporation of water molecules can be effectively minimized by an ALD-deposited Al2O3 diffusion barrier layer. This is due to the pinhole and defect-free nature of even very thin ALD-Al2O3 films, which cap the TiO2 surface and eliminate the desorption of water molecules at elevated temperatures. Figure 4a shows the temperature dependence of the refractive index dispersion curves of a 100 nm-thick ALD-TiO2 film coated by a 30 nm-thick ALD-Al2O3 diffusion barrier layer. Figure 4b shows the same for the 30 nm-thick Al2O3 barrier layer. Considering the calculation of thermo-optic coefficients at the wavelength of 640 nm, one can observe that the ALD-TiO2 index is nearly constant, and the Al2O3 index increases with temperature [20].
The temperature dependence of the refractive index of the 100 nm-thick ALD-TiO2 film as a function of the Al2O3 film thickness, nT(T, tA), at a wavelength of 640 nm, is shown in Figure 5. This TiO2 temperature dependence is shown in the case of the ALD-Al2O3 diffusion barrier layer thicknesses of 20 nm (Figure 5a) and 30 nm (Figure 5c). The corresponding temperature dependencies of the Al2O3 diffusion barrier layers are shown in Figure 5b,d. As mentioned above, with a 20 nm-thick ALD-Al2O3 diffusion barrier layer, the refractive index of the 100 nm-thick ALD-TiO2 film decreases slightly with temperature. This temperature dependence is very similar to that of a single 100 nm-thick TiO2 film, indicating a very small barrier effect [12]. However, by increasing the diffusion barrier layer thickness only by 10 nm, i.e., to 30 nm, the refractive index of the TiO2 is nearly constant with temperature. It can also be seen (Figure 5d) that the refractive index of the 30 nm-thick ALD-Al2O3 film increases with temperature rather than decreases, as is the case with the 20 nm-thick ALD-Al2O3 film (Figure 5b). This is expected when the Al2O3 film is thick enough. These results clearly indicate that a 20 nm-thick ALD-Al2O3 film is not yet pinhole free, while a 30 nm-thick film acts as an efficient, nearly pinhole-free, diffusion barrier layer. Consequently, a different behavior of the refractive indices with the temperature is observed for the ALD-Al2O3 films of 20-nm and 30-nm thicknesses in Figure 5b,d, respectively. In addition, the temperature dependence of the refractive index of a TiO2 thin-film does not depend only on its own properties, but also on the thickness of the diffusion barrier layer.
Figure 6a shows an atomic force microscopy (AFM) image of a 100 nm-thick ALD-TiO2 film with a surface roughness of Ra = 1.10 nm. The surface roughness of a similar 100 nm-thick ALD-TiO2 film with a 20 nm-thick ALD-Al2O3 film is less than 1 nm and is shown in Figure 6b. This means that the surface roughness of the TiO2 films is reduced after coating with an ALD-Al2O3 film.
The temperature dependence of the permeation through a diffusion barrier layer provides information about the dominating permeation mechanism for H2O and OH species, since the vapor permeation through solids is a thermally-driven process. The temperature-dependent permeation process can be described by the Arrhenius equation [21] as:
q = q 0 . e - E A k T
where q is the permeation coefficient, q0 is the system-dependent constant permeation coefficient, EA is the activation energy and k is the Boltzmann constant. The activation energies depend on the diffusion barrier layer, which is interpreted by a chemical interaction between water molecules and the coated diffusion barrier layer.
Figure 7 shows the thermo-optic coefficients of ALD-Al2O3 and ALD-TiO2 films as a function of the thickness tA. The thermo-optic coefficient of the Al2O3 film attains a positive value when the thickness tA is 30 nm or more (Figure 7a), i.e., when the film is nearly pinhole free and uniform. With thicker films, up to 70 nm in thickness, no rapid increase in the thermo-optic coefficient appears. On the other hand, the thermo-optic coefficient of the 100 nm-thick ALD-TiO2 film appears to increase linearly with thicknesses tA, as seen in Figure 7b. A linear fit gives an equation:
[ d n d T ] TiO 2 = 6.7 × 10 - 6 t A - 2.2 × 10 - 4
For its dependence on tA. Here, the slope of 6.7 × 10−6 has dimensions of °C−1 nm−1; −2.2 × 10−4 is a constant with a dimension of °C−1; and tA is the thickness of the barrier layer in nm. The slope of the straight line is described as per degree increase in temperature per nm, which determines the amount of activation energy required for water molecules to permeate through the ALD-Al2O3 diffusion barrier layer. If one increases the thickness tA of the barrier layer, the required activation energy will increase, and less water molecules are able to permeate through the barrier layers. This, in turn, will result in an increase in the thermo-optic coefficient of the TiO2 film and, consequently, in an increase in its density. Interestingly, the thermo-optic coefficient can attain a positive value, although the TiO2 films typically possess a negative thermo-optic coefficient. This may also be interpreted as acquiring low thermodynamic energies in order to fill surface defects of TiO2 films to minimize pinhole defects. As a potential application for these ALD-TiO2–Al2O3 bilayer films and nanostacks, we propose resonance waveguide gratings (RWG), which have important applications in sensing [22].
Typically, the RWG spectral characteristics encounter a spectral shift under varying thermal conditions and consequently make the resonance peak unstable for accurate sensing [23]. In order to mitigate the effect of temperature-dependent variations in the refractive index of TiO2, RWG surfaces can be coated with thin Al2O3 layers as diffusion barrier layers. To illustrate this approach, Figure 8 shows an RWG structure fabricated on fused silica substrate and employing an ALD-TiO2–Al2O3 nanostack as the waveguide. It is worth mentioning that the use of ALD results in highly conformal coating on the corrugated substrate.

4. Conclusions

Thin-film bilayers of TiO2 and Al2O3 were fabricated by ALD, and their temperature-dependent optical properties were spectrally characterized by ellipsometry. The experimental data were analyzed with the support of optical models and respective regression algorithms. The ellipsometry data measured for these bilayers were fitted by the Cauchy model, which provided optical constants both for TiO2 and Al2O3 thin-films. The determined optical constants were then used for the evaluation of thermo-optic constants of TiO2 and Al2O3 thin-films in this bilayer configuration. Thermo-optic properties of ALD-TiO2 films with a thickness of 100 nm, in the presence of diffusion barrier layers of ALD-Al2O3 with different thicknesses, were presented. The results were discussed in terms of the porosity model of thin TiO2 films. The study included the gradual increase of the thickness of the diffusion barrier layer, which resulted in a change in the refractive index and thermo-optic coefficients of the two thin-film materials. On increasing the thickness of the ALD-Al2O3 diffusion barrier layers from 20 nm to 30 nm, the initially negative thermo-optic coefficient of a 100 nm-thick TiO2 film turns positive. The increase in its thermo-optic coefficient with the thickness of the barrier layer exhibits a nearly linear relation, with a slope that determines the activation energies required for H2O and OH species to permeate through the barrier layer. The proposed ALD-grown bilayers and nanostacks may have potential in nanophotonics applications, in which temperature-dependent operation is a nuisance. For example, biosensors based on resonance waveguide gratings typically require accurate control of the ambient temperature, which may be alleviated with the proposed approach.

Acknowledgments

Financial support from the strategic funding of the University of Eastern Finland, Academy of Finland, Tekes, and the graduate school of Modern Optics and Photonics (Finland) is greatly appreciated.

Author Contributions

The first author has contributed to the fabrication, measurements and characterization of samples. Muhammad Rizwan Saleem is the original inventor of the presented research to observe the defects on the surface of optical materials by exploring the behavior of thermo-optic coefficients. The surface porosity model is further extended by a diffusion barrier layer. Pertti Pääkkönen has assisted during the measurements and in the calculations involved. Seppo Honkanen has supervised the research work. All authors have contributed in writing the manuscript.

Conflicts of Interest

The authors declare no conflict of interest.

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Figure 1. Schematic diagram of a TiO2 and Al2O3 bilayer film grown by atomic layer deposition (ALD) on a Si substrate. The illumination geometry in ellipsometric measurements is also shown.
Figure 1. Schematic diagram of a TiO2 and Al2O3 bilayer film grown by atomic layer deposition (ALD) on a Si substrate. The illumination geometry in ellipsometric measurements is also shown.
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Figure 2. Spectral dependence of the measured ellipsometric data at room temperature: (a) Ψ and (b) Δ for a bilayer with a 100 nm-thick ALD-TiO2 and a 30 nm-thick ALD-Al2O3. The data are fitted by the Cauchy model at three different angles (59°, 67° and 75°).
Figure 2. Spectral dependence of the measured ellipsometric data at room temperature: (a) Ψ and (b) Δ for a bilayer with a 100 nm-thick ALD-TiO2 and a 30 nm-thick ALD-Al2O3. The data are fitted by the Cauchy model at three different angles (59°, 67° and 75°).
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Figure 3. Scanning electron microscope (SEM) image of a bilayer consisting of a 100 nm-thick ALD-TiO2 and a 20 nm-thick ALD-Al2O3 film, on a Si substrate.
Figure 3. Scanning electron microscope (SEM) image of a bilayer consisting of a 100 nm-thick ALD-TiO2 and a 20 nm-thick ALD-Al2O3 film, on a Si substrate.
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Figure 4. Dispersion relation of refractive indices of (a) a 100 nm-thick ALD-TiO2 film and (b) a 30 nm-thick ALD-Al2O3 film in a TiO2–Al2O3 bilayer at different temperatures.
Figure 4. Dispersion relation of refractive indices of (a) a 100 nm-thick ALD-TiO2 film and (b) a 30 nm-thick ALD-Al2O3 film in a TiO2–Al2O3 bilayer at different temperatures.
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Figure 5. Temperature dependence of the refractive index of ALD-TiO2 and ALD-Al2O3 films in bilayers: (a) for a 100 nm-thick TiO2 film with a 20 nm-thick Al2O3 diffusion barrier layer; (b) for a 20-nm Al2O3 diffusion barrier layer; (c) for a 100-nm TiO2 film with a 30-nm Al2O3 diffusion barrier layer; and (d) for a 30-nm Al2O3 diffusion barrier layer.
Figure 5. Temperature dependence of the refractive index of ALD-TiO2 and ALD-Al2O3 films in bilayers: (a) for a 100 nm-thick TiO2 film with a 20 nm-thick Al2O3 diffusion barrier layer; (b) for a 20-nm Al2O3 diffusion barrier layer; (c) for a 100-nm TiO2 film with a 30-nm Al2O3 diffusion barrier layer; and (d) for a 30-nm Al2O3 diffusion barrier layer.
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Figure 6. The atomic force microscopy (AFM) images of (a) a 100 nm-thick ALD-TiO2 film deposited on a Si substrate with a surface roughness value Ra = 1.10 nm; and (b) a 100 nm-thick ALD-TiO2 film with a 20 nm-thick ALD-Al2O3 film with a surface roughness value Ra < 1 nm.
Figure 6. The atomic force microscopy (AFM) images of (a) a 100 nm-thick ALD-TiO2 film deposited on a Si substrate with a surface roughness value Ra = 1.10 nm; and (b) a 100 nm-thick ALD-TiO2 film with a 20 nm-thick ALD-Al2O3 film with a surface roughness value Ra < 1 nm.
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Figure 7. Thermo-optic coefficients of (a) Al2O3 and (b) TiO2 films.
Figure 7. Thermo-optic coefficients of (a) Al2O3 and (b) TiO2 films.
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Figure 8. SEM image of a resonant waveguide grating structure with a TiO2–Al2O3 bilayer as the waveguide layer, on a fused silica substrate.
Figure 8. SEM image of a resonant waveguide grating structure with a TiO2–Al2O3 bilayer as the waveguide layer, on a fused silica substrate.
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Ali, R.; Saleem, M.R.; Pääkkönen, P.; Honkanen, S. Thermo-Optical Properties of Thin-Film TiO2–Al2O3 Bilayers Fabricated by Atomic Layer Deposition. Nanomaterials 2015, 5, 792-803. https://0-doi-org.brum.beds.ac.uk/10.3390/nano5020792

AMA Style

Ali R, Saleem MR, Pääkkönen P, Honkanen S. Thermo-Optical Properties of Thin-Film TiO2–Al2O3 Bilayers Fabricated by Atomic Layer Deposition. Nanomaterials. 2015; 5(2):792-803. https://0-doi-org.brum.beds.ac.uk/10.3390/nano5020792

Chicago/Turabian Style

Ali, Rizwan, Muhammad Rizwan Saleem, Pertti Pääkkönen, and Seppo Honkanen. 2015. "Thermo-Optical Properties of Thin-Film TiO2–Al2O3 Bilayers Fabricated by Atomic Layer Deposition" Nanomaterials 5, no. 2: 792-803. https://0-doi-org.brum.beds.ac.uk/10.3390/nano5020792

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