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A PAlP Pincer Ligand Bearing a 2-Diphenylphosphinophenoxy Backbone

Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
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Received: 15 August 2019 / Revised: 19 November 2019 / Accepted: 20 November 2019 / Published: 28 November 2019
(This article belongs to the Special Issue Organoaluminum Compounds)
A PAlP pincer ligand derived from 2-diphenylphosphino-6-isopropylphenol was synthesized. The Lewis acidity of the Al center of the ligand was evaluated with coordination of (O)PEt3. A zwitterionic rhodium-aluminum heterobimetallic complex bearing the PAlP ligand was synthesized through its complexation with [RhCl(nbd)]2. Moreover, reduction of the zwitterionic rhodium-aluminum complex with KC8 afforded heterobimetallic complexes bearing an X-type PAlP pincer ligand. View Full-Text
Keywords: pincer ligands; aluminum; heterobimetallic complexes pincer ligands; aluminum; heterobimetallic complexes
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MDPI and ACS Style

Semba, K.; Fujii, I.; Nakao, Y. A PAlP Pincer Ligand Bearing a 2-Diphenylphosphinophenoxy Backbone. Inorganics 2019, 7, 140. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics7120140

AMA Style

Semba K, Fujii I, Nakao Y. A PAlP Pincer Ligand Bearing a 2-Diphenylphosphinophenoxy Backbone. Inorganics. 2019; 7(12):140. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics7120140

Chicago/Turabian Style

Semba, Kazuhiko, Ikuya Fujii, and Yoshiaki Nakao. 2019. "A PAlP Pincer Ligand Bearing a 2-Diphenylphosphinophenoxy Backbone" Inorganics 7, no. 12: 140. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics7120140

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