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Article

Hydrosilylation of Aldehydes by a Manganese α-Diimine Complex

1
Science Department, Texas A&M University at Qatar, PO Box 23874 Doha, Qatar
2
Department of Chemistry, 3 Science Drive, National University of Singapore, Singapore 117543, Singapore
*
Authors to whom correspondence should be addressed.
Received: 21 October 2020 / Revised: 5 November 2020 / Accepted: 6 November 2020 / Published: 10 November 2020
(This article belongs to the Special Issue Organomanganese Chemistry)
This paper describes the catalytic activity of air stable and easy to handle manganese complexes towards the hydrosilylation of aldehydes. These catalysts incorporate a bulky diazabutadiene ligand and exhibit good functional group tolerance and chemoselectivity in the hydrosilylation of aldehydes, utilizing primary silanes as the reducing agent. The reactions proceed with turnover frequencies approaching 150 h−1 in some instances, similar to those observed for other manganese-based catalysts. The conversion of aromatic aldehydes to the corresponding alcohols was found to be more efficient than that for the analogous aliphatic systems. View Full-Text
Keywords: catalysis; manganese; hydrosilylation catalysis; manganese; hydrosilylation
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MDPI and ACS Style

Yempally, V.; Shahbaz, A.; Fan, W.Y.; Madrahimov, S.T.; Bengali, A.A. Hydrosilylation of Aldehydes by a Manganese α-Diimine Complex. Inorganics 2020, 8, 61. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics8110061

AMA Style

Yempally V, Shahbaz A, Fan WY, Madrahimov ST, Bengali AA. Hydrosilylation of Aldehydes by a Manganese α-Diimine Complex. Inorganics. 2020; 8(11):61. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics8110061

Chicago/Turabian Style

Yempally, Veeranna, Azal Shahbaz, Wai Y. Fan, Sherzod T. Madrahimov, and Ashfaq A. Bengali 2020. "Hydrosilylation of Aldehydes by a Manganese α-Diimine Complex" Inorganics 8, no. 11: 61. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics8110061

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