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Open AccessArticle

Influence of Substituents in Terephthalate Linker on the Structure of MOFs Obtained from Presynthesized Heterometallic Complex

1
Nikolaev Institute of Inorganic Chemistry, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia
2
Natural Sciences Department, Novosibirsk State University, 1, Pirogova str., 630090 Novosibirsk, Russia
*
Author to whom correspondence should be addressed.
Received: 25 November 2020 / Revised: 14 December 2020 / Accepted: 18 December 2020 / Published: 2 January 2021
(This article belongs to the Special Issue Heterometallic Complexes)
The synthesis of new porous materials with desired properties is a challenging task. It becomes especially difficult if you need to combine several metals in one framework to obtain a heterometallic node. The use of presynthesized complexes for obtaining of new heterometallic metal–organic frameworks could be essential to solve the problem of tailored synthesis. In our study we use presynthesized heterometallic pivalate complex [Li2Zn2(piv)6(py)2] to obtain new MOFs with heterometallic core as a node of the framework. We are managed to obtain four new heterometallic MOFs: [H2N(CH3)2]2[Li2Zn2(bdc)4]·CH3CN·DMF (1), [Li2Zn2(H2Br2-bdc)(Br2-bdc)3]·2DMF (2), [H2N(CH3)2][LiZn2(ndc)3]·CH3CN (3) and [{Li2Zn2(dmf)(py)2}{LiZn(dmf)2}2 (NO2-bdc)6]·5DMF (4). Moreover three of them contain starting tetranuclear core {Li2Zn2} and saves its geometry. We also demonstrate the influence of substituent in terephthalate ring on preservation of tetranuclear core. For compound 1 it was shown that luminescence of the framework could be quenched when nitrobenzene is included in the pores. View Full-Text
Keywords: metal–organic frameworks; heterometallic complexes; luminescence metal–organic frameworks; heterometallic complexes; luminescence
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MDPI and ACS Style

Barsukova, M.; Dudko, E.; Samsonenko, D.; Kovalenko, K.; Ryadun, A.; Sapianik, A.; Fedin, V. Influence of Substituents in Terephthalate Linker on the Structure of MOFs Obtained from Presynthesized Heterometallic Complex. Inorganics 2021, 9, 4. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics9010004

AMA Style

Barsukova M, Dudko E, Samsonenko D, Kovalenko K, Ryadun A, Sapianik A, Fedin V. Influence of Substituents in Terephthalate Linker on the Structure of MOFs Obtained from Presynthesized Heterometallic Complex. Inorganics. 2021; 9(1):4. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics9010004

Chicago/Turabian Style

Barsukova, Marina; Dudko, Evgeny; Samsonenko, Denis; Kovalenko, Konstantin; Ryadun, Alexey; Sapianik, Aleksandr; Fedin, Vladimir. 2021. "Influence of Substituents in Terephthalate Linker on the Structure of MOFs Obtained from Presynthesized Heterometallic Complex" Inorganics 9, no. 1: 4. https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics9010004

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