Recycling, Volume 5, Issue 2 (June 2020) – 8 articles

A large percentage of fruit mass is left as waste after the consumption or processing of citrus fruits. The inappropriate disposal of these wastes directly leads to environmental and economic concerns. However, scientific investigations have demonstrated that citrus wastes, due to their high concentration in soluble sugars, can be a source of cellulosic biomass for biogas recovery. d-Limonene, the major constituent of essential oils present in citrus wastes, is however, known to hamper the conversion process of citrus wastes to biogas. With the aim of improving biogas production, a study on the pre-treatment of lime fruit waste to reduce the effect of d-limonene was carried out. The pre-treatment process was done using hexane as the solvent in a solid–liquid extraction process to leach out essential oils from lime wastes. Solid–liquid extraction was carried out in a Soxhlet apparatus with pulverized lime waste at 68 °C for 180 min; then the residue was washed and aerated. From the pre-treatment procedure, 21.3 mL of essential oil was recovered, indicating an oil yield of 3.8%. Substrates of untreated and pre-treated lime waste were digested in batches under mesophilic conditions for a period of 28 days. The biogas yield of each substrate was evaluated and the results compared. Substrate of untreated lime waste yielded 66.9 mL/g VS. biogas after the digestion period. In comparison, pre-treated lime waste gave a better biogas yield of 93.2 mL/g VS. after 28 days, indicating an improvement in biogas yield by about 40%. The findings of this research show that there is a viable recovery option of biogas from lime waste, and recommendations of this research can be further explored to develop an economically viable biogas plant process that efficiently utilizes citrus wastes. This would boost the drive of government towards alternative sources of energy and also fulfil two of the sustainable development goals presented by the United Nations. Full article

In this study, waste cooking oil (WCO) was used to successfully manufacture catalyst cracking biodiesel in the laboratory. This study aims to evaluate and compare the influence of waste cooking oil synthetic diesel (WCOSD) with that of commercial diesel (CD) fuel on an engine’s operating characteristics. The second goal of this study is to compare the engine performance and temperature characteristics of cooling water and lubricant oil under various engine operating conditions of a test engine fueled by waste cooking oil and CD. The results indicated that the engine torque of the engine running with WCOSD dropped from 1.9 Nm to 5.4 Nm at all speeds, and its brake specific fuel consumption (BSFC) dropped at almost every speed. Thus, the thermal brake efficiency (BTE) of the engine fueled by WCOSD was higher at all engine speeds. Also, the engine torque of the WCOSD-fueled engine was lower than the engine torque of the CD-fueled engine at all engine speeds. The engine’s power dropped sequentially through 0.3 kW, 0.4 kW, 0.6 kW, 0.9 kW, 0.8 kW, 0.9 kW, 1.0 kW and 1.9 kW. Full article

The demand for new sources of energy is one of the main quests for humans. At the same time, there is a growing need to eliminate or recover a set of industrial or agroforestry waste sources. In this context, several options may be of interest, especially given the amounts produced and environmental impacts caused. Olive pomace can be considered one of these options. Portugal, as one of the most prominent producers of olive oil, therefore, also faces the problem of dealing with the waste of the olive oil industry. Olive pomace energy recovery is a subject referenced in many different studies and reports since long ago. However, traditional forms of recovery, such as direct combustion, did not prove to be the best solution, mainly due to its fuel properties and other characteristics, which cause difficulties in its storage and transportation as well. Torrefaction and pyrolysis can contribute to a volume reduction, optimizing storage and transportation. In this preliminary study, were carried out torrefaction and pyrolysis tests on olive pomace samples, processed at 300 °C, 400 °C, and 500 °C, followed by laboratory characterization of the materials. It was verified an improvement in the energy content of the materials, demonstrating that there is potential for the use of these thermochemical conversion technologies for the energy recovery of olive pomace. Full article

This research focused on using ground tire rubber (GTR) with different grain sizes as a replacement for the mineral aggregates used in a cement-based mixture suitable for extrusion-based Additive Manufacturing. The use of two types of GTR particles and the possibility to apply rubberized mixtures in advanced manufacturing technologies are the innovative aspects of this work. At the base of this strategy is the possibility of achieving cementitious aggregates, which would potentially be improved regarding some technological-engineering requirements (lightness, thermal-acoustic insulation, energy dissipation capacity, durability) and environmentally sustainable. The integration of waste tires into cement-based materials is a promising solution for the reuse and recycling of such industrial waste. In addition, this approach may involve a considerable reduction in the use of natural resources (sand, water, coarse mineral aggregates) needed for the building materials production. The purpose of the research was to investigate the effect of sand-GTR replacement on certain chemical-physical properties of mixtures (permeable porosity, surface wetness, and water sorptivity), closely related to material durability. Besides, the role of rubber on the printability properties of the fresh material was evaluated. GTR fillers do not alter the rheological properties of the cement material, which was properly extruded with better print quality than the reference mixture. Concerning chemical-physical characterization, the GTR powder-granules synergy promotes good compaction of the mixture, hinders the cracks propagation in the cement matrix, decreases the permeable porosity, improves the surface hydrophobicity and preserves optimal water permeability. Full article

This paper presents a brief description of some existing models of facility location problems (FLPs) in solid waste management. The study provides salient information on commonly used distance functions in location models along with their corresponding mathematical formulation. Some of the optimization techniques that have been applied to location problems are also presented along with an appropriate pseudocode algorithm for their implementation. Concerning the models and solution techniques, the survey concludes by summarizing some recent studies on the applications of FLPs to waste collection and disposal. It is expected that this paper will contribute in no small measure to an integrated solid waste management system with specific emphasis on issues associated with waste collection, thereby boosting the drive for effective and efficient waste collection systems. The content will also provide early career researchers with some necessary starting information required to formulate and solve problems relating to FLP. Full article

In this paper, we report a study on the use of a linear triblock copolymer based on styrene and ethylene/butylene (SEBS) and a polypropylene (PP)-based olefin block copolymer (OBC) for improving the impact strength of a recycled polypropylene (PP) from packaging waste. Talc was used as a reinforcing filler in order to prepare a material suitable for being used in the automotive sector. The composite mixtures were prepared by melt extrusion, and the samples were manufactured by injection molding. Impact strength was evaluated by Izod tests, and a morphological study of the produced fractures was performed. As a result, a composite with substantially improved impact properties was prepared, with a two-fold increase of the impact strength in the case of unnotched specimens, while only a limited positive effect was produced on notched specimens. Since talc-filled PP is a typical material used in the automotive sector, the obtained results demonstrate that post-consumer PP coming from the municipal waste collection of plastic packaging can be successfully used in car components with no compromise in terms of mechanical requirements. Full article

The effects of poor solid waste management practices in many developing countries have been identified in the literature. This study focuses on understanding the public perception and attitudes of people towards local waste management practices. Five Local Government Areas in Ogun State, Nigeria, were selected based on population, landmass, spatial location, and distribution. The study used a survey that looked into the socio-demographics, household characteristics, and standard solid waste disposal practices at the household and municipal levels. Factors such as frequency of waste collection, presence of environmental task force/protection agency, and level of effectiveness of such task force/agency were all investigated. The study verified the impact of people’s attitudes towards waste management, as well as the effects of monitoring and control on the management of waste. The results showed that significant factors such as age, income, and education levels affect the perceptions, practices, and attitudes of the people towards solid waste management. An average of 36.6% of the people in the selected local governments dispose of their solid wastes at open dumps, with the majority of the residents (54.4%) still with the opinion that sanitation services are too costly and should be the prerogative of the local and state governments to carry out. These outcomes resonate that more efforts by the government and relevant stakeholders should be put into proper enforcement of environmental laws, as well as creating awareness on proper solid waste management practices in schools and public places. Full article

Several theories and case studies have shown that information has little or no direct influence on waste sorting behavior. However, it is often suggested that information plays a vital role by indirectly influencing behavior. This contribution sheds light on how instructive information influences users of a recycling scheme in terms of perception, knowledge and waste sorting behavior. The study was performed as a case study on a student population in a medium-sized city in Sweden. An intervention in the form of modified information that was provided to the users was studied. This information was instructive in nature and adapted to the participants’ needs using the Recycling Behavior Transition procedure, where the users are involved in the development and modification of recycling schemes. New information was designed after investigating how the participants perceived the original information on correct waste sorting, as well as ascertaining their preferred channel for providing the information. Pick analyses and surveys were conducted before and after providing the user-adapted information. The results indicated a trend towards correct participation in the recycling scheme. These results are also discussed in the theoretical context of the Motivation-Opportunity-Ability-Behavior model. The study shows that user-adapted, instructive information can have a significant influence on people’s knowledge of correct waste separation and their overall perception of information. Full article