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Synthesis and X-ray Diffraction Study of thiosemicarbazone Palladacycles with dppm

Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiago de Compostela, Avda. das Ciencias s/n, 15782 Santiago de Compostela, Spain
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Presented at the 2nd International Electronic Conference on Crystals, 10–20 November 2020; Available online: https://iocc_2020.sciforum.net/.
Published: 22 January 2021
(This article belongs to the Proceedings of The 2nd International Online Conference on Crystals)
Cyclometallated compounds have been extensively studied, in particular those with palladium and platinum. This is because of their possible applications in medicinal chemistry, as anticancer or antimicrobial agents; in some cases, with similar results as cisplatin, carboplatin or oxaliplatin. What is also remarkable is their use as homogeneous catalysts, for example, in cross coupling reactions such as Suzuki–Miyaura or Mizoroki–Heck. Herein, we report the synthesis of different thiosemicarbazone ligands, which will be reacted with a palladium or platinum salt, to give the corresponding cyclometallated compounds; in addition, their reactivity with bis(diphenylphosphino)methane (dppm) will be studied. Characterization has been carried out by elemental analysis, IR spectroscopy, 1H and 31P NMR spectroscopy. Additionally, 1c has been studied by X-ray diffraction.
Keywords: cyclometallation; thiosemicarbazone; palladium; platinum; X-ray diffraction cyclometallation; thiosemicarbazone; palladium; platinum; X-ray diffraction
MDPI and ACS Style

Rúa-Sueiro, M.; Munin-Cruz, P.; Reigosa, F.; Vila, J.M.; Ortigueira, J.M. Synthesis and X-ray Diffraction Study of thiosemicarbazone Palladacycles with dppm. Proceedings 2020, 62, 13. https://0-doi-org.brum.beds.ac.uk/10.3390/proceedings2020062013

AMA Style

Rúa-Sueiro M, Munin-Cruz P, Reigosa F, Vila JM, Ortigueira JM. Synthesis and X-ray Diffraction Study of thiosemicarbazone Palladacycles with dppm. Proceedings. 2020; 62(1):13. https://0-doi-org.brum.beds.ac.uk/10.3390/proceedings2020062013

Chicago/Turabian Style

Rúa-Sueiro, Marcos; Munin-Cruz, Paula; Reigosa, Francisco; Vila, José M.; Ortigueira, Juan M. 2020. "Synthesis and X-ray Diffraction Study of thiosemicarbazone Palladacycles with dppm" Proceedings 62, no. 1: 13. https://0-doi-org.brum.beds.ac.uk/10.3390/proceedings2020062013

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