Removal of Arsenate and Arsenite in Equimolar Ferrous and Ferric Sulfate Solutions through Mineral Coprecipitation: Formation of Sulfate Green Rust, Goethite, and Lepidocrocite
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemicals
2.2. Formation of Coprecipitation Solids
2.3. X-Ray Diffraction (XRD) Analysis
2.4. X-ray Absorption Spectroscopy Analysis
2.5. Raman Spectroscopy Analysis
2.6. Aqueous Solution Analysis
2.7. Arsenic Concentration in Solid Phases
3. Results
3.1. Iron and Arsenic Removal
3.2. Mineralogy of Coprecipitated Solids
3.3. Raman Spectra of Coprecipitates
3.4. Extent and Nature of Coprecipitated As(V) and As(III)
4. Discussion
4.1. Stabilization of Sulfate Green Rust by As(III)
4.2. Was Dissolved O2 An Oxidant for As(III) Oxidation?
4.3. Implications of Iron-Based Remediation of Groundwater
5. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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[As(V)]0/mM | pH | Eh/mV | [Fe2+]/mM | [Fe]/mM | Fe Removal/% | [As(V)]/mM | [As(III)]/mM | As Removal/% | As conc. in solids/mg kg−1 | Mineralogy | Solids Color | Magnetic |
---|---|---|---|---|---|---|---|---|---|---|---|---|
100 | 6.59 | 30.8 | 21.9 | 27.8 | 89.55 | 0.053 | nd | 99.95 | 171,000 ± 6000 | amorphous HFO | gray | no |
50 | 6.23 | 53.7 | 69.6 | 62.3 | 76.58 | 0.018 | nd | 99.96 | 101,000 ± 500 | amorphous HFO | brown | no |
10 | 6.15 | 61.6 | 56 | 84 | 68.42 | nd | nd | 100 | 40,600 ± 6300 | amorphous HFO | brown | no |
5 | 5.78 | 86.3 | 69.8 | 91 | 65.79 | nd | nd | 100 | 17,400 ± 800 | lepido., goethite | brown | no |
1 | 5 | 187 | 96.2 | 95.5 | 64.1 | nd | nd | 100 | 3980 ± 230 | lepido., goethite | brown | no |
0.5 | 4.83 | 227 | 86.2 | 95.1 | 64.25 | nd | nd | 100 | 2070 ± 100 | goethite, lepido. | brown | no |
0 | 4.09 | 366 | 97.1 | 96.7 | 63.65 | nd | nd | nd | nd | goethite | brown | no |
[As(III)]0/mM | pH | Eh/mV | [Fe2+]/mM | [Fe]/mM | Fe Removal/% | [As(V)]/mM | [As(III)]/mM | As Removal/% | As conc. in solids/mg kg−1 | Mineralogy | Solids Color | Magnetic |
---|---|---|---|---|---|---|---|---|---|---|---|---|
100 | 6.62 | 18.1 | 55.1 | 56.8 | 78.65 | 1.06 | 0.29 | 98.65 | 207,000 ± 7000 | amorphous HFO | gray | no |
50 | 6.34 | 56.8 | 47.9 | 75.6 | 71.58 | 0.22 | 0.32 | 98.92 | 136,300 ± 26,100 | SGR | green | no |
10 | 5.51 | 194 | 95.3 | 93.7 | 64.77 | 0.0039 | 0.071 | 99.25 | 31,600 ± 1150 | lepidocrocite | brown | no |
5 | 4.37 | 342 | 88.3 | 96.9 | 63.57 | 0.0024 | 0.047 | 99.01 | 14,900 ± 1700 | goethite, lepido. | brown | no |
1 | 3.73 | 417 | 92.2 | 98.1 | 63.12 | 0.00051 | 0.0070 | 99.25 | 3280±520 | goethite, lepido. | brown | no |
0.5 | 4.96 | 214 | 89.2 | 94 | 64.66 | nd | 0.0016 | 99.68 | 1850 ± 70 | goethite | brown | no |
Coprecipitate Sample | Component | Fitted XANES Fraction |
---|---|---|
100 mM As(III) | As(V) | 0.110 |
As(III) | 0.890 | |
50 mM As(III) | As(V) | 0.131 |
As(III) | 0.869 | |
10 mM As(III) | As(V) | 0.294 |
As(III) | 0.706 | |
5.0 mM As(III) | As(V) | 0.509 |
As(III) | 0.491 | |
1.0 mM As(III) | As(V) | 0.722 |
As(III) | 0.278 | |
0.5 mM As(III) | As(V) | 0.722 |
As(III) | 0.278 |
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Su, C.; Wilkin, R.T. Removal of Arsenate and Arsenite in Equimolar Ferrous and Ferric Sulfate Solutions through Mineral Coprecipitation: Formation of Sulfate Green Rust, Goethite, and Lepidocrocite. Soil Syst. 2020, 4, 68. https://0-doi-org.brum.beds.ac.uk/10.3390/soilsystems4040068
Su C, Wilkin RT. Removal of Arsenate and Arsenite in Equimolar Ferrous and Ferric Sulfate Solutions through Mineral Coprecipitation: Formation of Sulfate Green Rust, Goethite, and Lepidocrocite. Soil Systems. 2020; 4(4):68. https://0-doi-org.brum.beds.ac.uk/10.3390/soilsystems4040068
Chicago/Turabian StyleSu, Chunming, and Richard T. Wilkin. 2020. "Removal of Arsenate and Arsenite in Equimolar Ferrous and Ferric Sulfate Solutions through Mineral Coprecipitation: Formation of Sulfate Green Rust, Goethite, and Lepidocrocite" Soil Systems 4, no. 4: 68. https://0-doi-org.brum.beds.ac.uk/10.3390/soilsystems4040068