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Effect on Cycloaddition Reactions of Aqueous Micellar Systems Formed by Amphiphilic Imidazolium Ionic Liquids

IQAL (UNL-CONICET), Laboratorio Fisicoquímica Orgánica, Facultad de Ingeniería Química, Universidad Nacional del Litoral, Santa Fe 3000, Argentina
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Presented at the 24th International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2020; Available online: https://ecsoc-24.sciforum.net/.
Published: 14 November 2020
The micellar effect on Diels–Alder (DA) reaction was analyzed taking advantage of the property presented by ionic liquids (ILs) based on 1-alkyl-3-methylimidazolium cations by having amphiphilic character when the alkyl group is a long hydrocarbon chain-12 carbon atoms [C12mim]. These ILs can act as surfactants forming micelles in aqueous solution. The reactive system studied consists of nitrofuran and isoprene which allows obtaining benzofuran through green synthetic strategies. These “new microheterogeneous systems” would allow a better solubilization of non-polar substrates and to adopt reaction conditions softer than the traditional thermal.
Keywords: ionic liquids; imidazolium cation; Diels–Alder; micelles ionic liquids; imidazolium cation; Diels–Alder; micelles
MDPI and ACS Style

Soffietti, J.B.; Adam, C.G.; Rosa, C.D.D. Effect on Cycloaddition Reactions of Aqueous Micellar Systems Formed by Amphiphilic Imidazolium Ionic Liquids. Chem. Proc. 2021, 3, 142. https://0-doi-org.brum.beds.ac.uk/10.3390/ecsoc-24-08338

AMA Style

Soffietti JB, Adam CG, Rosa CDD. Effect on Cycloaddition Reactions of Aqueous Micellar Systems Formed by Amphiphilic Imidazolium Ionic Liquids. Chemistry Proceedings. 2021; 3(1):142. https://0-doi-org.brum.beds.ac.uk/10.3390/ecsoc-24-08338

Chicago/Turabian Style

Soffietti, Jésica B., Claudia G. Adam, and Claudia D. Della Rosa. 2021. "Effect on Cycloaddition Reactions of Aqueous Micellar Systems Formed by Amphiphilic Imidazolium Ionic Liquids" Chemistry Proceedings 3, no. 1: 142. https://0-doi-org.brum.beds.ac.uk/10.3390/ecsoc-24-08338

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