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Gases, Volume 2, Issue 3 (September 2022) – 3 articles

Cover Story (view full-size image): Natural gas is the cleanest fossil energy source, and its exploration is crucial to ensuring a smooth transition from fossil energy to low-carbon energy. While the easy-to-produce onshore natural gas reserves are decreasing, production of offshore reserves, where weight and footprint constraints impose severe limitations, is increasing. In this scenario, a gas–liquid membrane contactor is a promising process intensification technology for offshore carbon dioxide removal from natural gas with aqueous-amine solvents. Thanks to its potential for substituting conventional packed/trayed columns for acid-gas absorption and acid-gas solvent regeneration, gas-liquid membrane contactors have been investigated experimentally and theoretically in the past two decades. These efforts are extensively and critically reviewed in the present work. View this paper
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36 pages, 1607 KiB  
Review
Carbon Capture from CO2-Rich Natural Gas via Gas-Liquid Membrane Contactors with Aqueous-Amine Solvents: A Review
by Guilherme Pereira da Cunha, José Luiz de Medeiros and Ofélia de Queiroz F. Araújo
Gases 2022, 2(3), 98-133; https://0-doi-org.brum.beds.ac.uk/10.3390/gases2030007 - 01 Sep 2022
Cited by 1 | Viewed by 6294
Abstract
Gas–liquid membrane contactor is a promising process intensification technology for offshore natural gas conditioning in which weight and footprint constraints impose severe limitations. Thanks to its potential for substituting conventional packed/trayed columns for acid-gas absorption and acid-gas solvent regeneration, gas-liquid membrane contactors have [...] Read more.
Gas–liquid membrane contactor is a promising process intensification technology for offshore natural gas conditioning in which weight and footprint constraints impose severe limitations. Thanks to its potential for substituting conventional packed/trayed columns for acid-gas absorption and acid-gas solvent regeneration, gas-liquid membrane contactors have been investigated experimentally and theoretically in the past two decades, wherein aqueous-amine solvents and their blends are the most employed solvents for carbon dioxide removal from natural gas in gas-liquid membrane contactors. These efforts are extensively and critically reviewed in the present work. Experimentally, there are a remarkable lack of literature data in the context of gas–liquid membrane contactors regarding the following topics: water mass transfer; outlet stream temperatures; head-loss; and light hydrocarbons (e.g., ethane, propane, and heavier) mass transfer. Theoretically, there is a lack of complete models to predict gas-liquid membrane contactor operation, considering multicomponent mass balances, energy balances, and momentum balances, with an adequate thermodynamic framework for correct reactive vapor–liquid equilibrium calculation and thermodynamic and transport property prediction. Among the few works covering modeling of gas-liquid membrane contactors and implementation in professional process simulators, none of them implemented all the above aspects in a completely successful way. Full article
(This article belongs to the Section Natural Gas)
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13 pages, 5057 KiB  
Article
Impact of Coal Orthotropic and Hydraulic Fracture on Pressure Distribution in Coalbed Methane Reservoirs
by Yaohui Li, Zheng Liu, Shuhui Yan, Yaoxin Yang, Yu Zhou and Zheng Sun
Gases 2022, 2(3), 85-97; https://0-doi-org.brum.beds.ac.uk/10.3390/gases2030006 - 18 Aug 2022
Viewed by 1685
Abstract
Coalbed methane (CBM) shows tremendous in situ reserves, attracting a great deal of research interests around the world. The efficient development of CBM is closely related to the dynamic pressure distribution characteristics in the coal seam. As the dominant component of the geological [...] Read more.
Coalbed methane (CBM) shows tremendous in situ reserves, attracting a great deal of research interests around the world. The efficient development of CBM is closely related to the dynamic pressure distribution characteristics in the coal seam. As the dominant component of the geological reserve for CBM, the adsorption-state gas will not be exploited until the local coal pressure becomes less than the critical desorption pressure. Therefore, although the CBM reserve is fairly large, the production performance is generally limited, with a poor understanding of the dynamic pressure field during the CBM production. In this work, in order to address this issue properly, the coal’s inherent properties, the coal’s orthotropic features, as well as artificial hydraulic fracturing are considered, all of which affect pressure propagation in the coal seam. Notably, to the current knowledge, the impact of coal’s orthotropic features has received little attention, while the coal’s orthotropic features are formed during a fairly long geological evolution, changing the dynamic pressure field a lot. Numerical simulation is performed to shed light on the pressure propagation behavior. The results show that (a) coal’s orthotropic features mitigate the depressurization process of CBM development; (b) the increasing length of a hydraulic fracture is helpful for efficient decline in the average formation pressure; and (c) there exists an optimal layout mode for multi-well locations to minimize the average pressure. This article provides an in-depth analysis upon pressure distribution in CBM reservoirs under impacts of coal orthotropic feature and hydraulic fractures. Full article
(This article belongs to the Section Natural Gas)
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11 pages, 4029 KiB  
Brief Report
Influence of an Extreme Saharan Dust Event on the Air Quality of the West Region of Portugal
by João Gomes, Helder Esteves and Luis Rente
Gases 2022, 2(3), 74-84; https://0-doi-org.brum.beds.ac.uk/10.3390/gases2030005 - 07 Jul 2022
Cited by 5 | Viewed by 2169
Abstract
This paper describes how an extreme Saharan dust event that took place in March 2022 affected the Iberian Peninsula and was noticed not only by the outdoor air quality monitoring stations measuring PM2.5 and PM10 but also by indoor air monitoring [...] Read more.
This paper describes how an extreme Saharan dust event that took place in March 2022 affected the Iberian Peninsula and was noticed not only by the outdoor air quality monitoring stations measuring PM2.5 and PM10 but also by indoor air monitoring systems in Fatima, central Portugal. The observed particulate matter concentrations clearly show the influence that such an event has on the indoor air quality inside buildings and that the magnitude of that influence is also dependent on the specific characteristics of the buildings, mainly the ventilation conditions, as should be expected. Therefore, this study alerts us to the necessity of integrating indoor and outdoor air quality monitoring systems to achieve automated air conditioning systems capable of efficiently controlling both temperature and air cleanliness. Full article
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