Modern Materials and Methods of Mitigating Metal Corrosion

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Materials Science and Engineering".

Deadline for manuscript submissions: closed (31 August 2021) | Viewed by 6652

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Department of Chemistry, Dongguk University, Seoul 04620, Republic of Korea
Interests: material science; corrosion science; electrochemistry; spectroscopy; analytical chemistry; green chemistry; natural product chemistry; bio science; food chemistry; nanotechnology
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Dear Colleagues,

Metals are found in a combined form called ore. Ore is in a low-energy state. By applying a large amount of energy, metals are extracted from ores, which possess high energy in an unstable state. These metals have a tendency to attain a low-energy state (combined form) by reacting with the elements existing in the surrounding environment leading to corrosion. Corrosion is nothing but metal destruction due to its exposure to electrolytes, such as soil, and moisture through chemical or electrochemical reactions. It is a slow, steady, and irreversible process affecting the physical as well as the chemical properties of the metal. Corrosion is induced by chemical and electrochemical processes. There are two types of corrosion, namely, dry and wet; dry corrosion takes place in dry gases and non-conductive liquids where there is no current/electron flow, whereas wet corrosion takes place in metal in the presence of electrolytes. Corrosion is a natural process that occurs at the metal–electrolyte interface and significantly reduces the lifetime of metals. Metals are broadly utilized in modern society because of their excellent mechanical properties and their ability to withstand different conditions. Various acids have been utilized for descaling, derusting, pickling, and cleaning a variety of metal surfaces and equipment in industries. A recognizable strategy to combat corrosion is by employing corrosion inhibitors (natural or synthetic). The incredible mitigating effect of an inhibitor is strengthened by the existence of heteroatoms, aromatic rings, and π-electrons, which assist its adsorption on the surface of metal. These inhibitors have a tendency to mitigate corrosion by forming various kinds of protective films via adsorption, forming precipitates, or forming an inactive layer on a metal surface. Most inhibitors inhibit the corrosion process by developing an invisible protective film on the surface of metal. Electron pair and negatively charged ions from the inhibitors are transferred to the d orbital of the metal, forming coordination complexes and acting as a barrier to block the exposure of the metal to the aggressive environment. Metal corrosion is a major issue due to its negative impact on economics, society, and the health and safety of people. Hence, there is an alarming need to address this issue, and modern materials and methods to mitigate corrosion need to be discussed.

This Special Issue on the mentioned theme will represent a common forum for research findings from around the world addressing solutions for challenges and issues relating to metal corrosion. We kindly invite you to submit your research contributions, including full papers, communications, and reviews, to this Special Issue.

Dr. Mayakrishnan Prabakaran
Guest Editor

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Keywords

  • Corrosion inhibition
  • Metals
  • Coatings
  • Marine corrosion and microbial corrosion
  • Coatings for reinforcement in concrete
  • Corrosion inhibitors in concrete
  • Surface engineering
  • Surface chemistry
  • Electrochemistry
  • Spectroscopy

Published Papers (2 papers)

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Research

18 pages, 8436 KiB  
Article
Evaluation of Antioxidant and Anticorrosive Activities of Ceriops tagal Plant Extract
by Md Shamsuzzaman, Kathirvel Kalaiselvi and Mayakrishnan Prabakaran
Appl. Sci. 2021, 11(21), 10150; https://0-doi-org.brum.beds.ac.uk/10.3390/app112110150 - 29 Oct 2021
Cited by 5 | Viewed by 2242
Abstract
Mangroves are plants known for their various medicinal and economical values, and therefore are widely investigated for their phytochemical, antioxidant, antidiarrheal, and antimicrobial activities. In the present study, we analyze the antioxidant and anticorrosive properties of Ceriops tagal (C. tagal), a [...] Read more.
Mangroves are plants known for their various medicinal and economical values, and therefore are widely investigated for their phytochemical, antioxidant, antidiarrheal, and antimicrobial activities. In the present study, we analyze the antioxidant and anticorrosive properties of Ceriops tagal (C. tagal), a tropical and subtropical mangrove plant of the Rhizophoraceae family. The total phenolic content (TPC) and total flavonoid content (TFC) were found to be 101.52 and 35.71 mg/g, respectively. The extract (100 µg/mL) exhibited 83.88, 85, and 87% antioxidant property against 1,1-diphenyl-2-picrylhydrazyl (DPPH), nitric oxide, and hydrogen peroxide free radicals. In addition, 600 ppm of C. tagal extract showed 95% corrosion inhibition against 1 M HCl attack on mild steel at 303 ± 1 K, which declined over other concentrations and temperatures, where AAS produced 82% inhibition at 600 ppm. UV-visible spectroscopy analysis revealed the formation of an inhibitor metal complex. The elemental analysis provided the presence of 84.21, 9.01, and 6.37% of Fe, O, and C, respectively, in inhibited mild steel, whereas the same were 71.54, 22.1, and 4.34%, respectively, in uninhibited specimen, stressing the presence of protective film on the metal surface. Scanning electron microscopy (SEM) also showed some noteworthy changes in both uninhibited and inhibited mild steel, making C. tagal plant a better alternative than any other synthetic inhibitors. Further, the atomic force microscopy (AFM) surface topography analysis showed that 600 ppm of C. tagal extract significantly diminished corrosion on the surface of mild steel. Full article
(This article belongs to the Special Issue Modern Materials and Methods of Mitigating Metal Corrosion)
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17 pages, 2292 KiB  
Article
Comparative Polyphenol Composition, Antioxidant and Anticorrosion Properties in Various Parts of Panax ginseng Extracted in Different Solvents
by Ramalingam Malathy, Mayakrishnan Prabakaran, Kathirvel Kalaiselvi, Ill-Min Chung and Seung-Hyun Kim
Appl. Sci. 2021, 11(1), 93; https://0-doi-org.brum.beds.ac.uk/10.3390/app11010093 - 24 Dec 2020
Cited by 25 | Viewed by 3110
Abstract
Panax ginseng C.A. (P. ginseng) Meyer has been in use since ancient times for its therapeutic activities. Although several studies have investigated the roles of phytoconstituents in human and animal health, no comparative studies have been conducted to test the efficacy [...] Read more.
Panax ginseng C.A. (P. ginseng) Meyer has been in use since ancient times for its therapeutic activities. Although several studies have investigated the roles of phytoconstituents in human and animal health, no comparative studies have been conducted to test the efficacy of P.ginseng leaf, fruit and root. Therefore, this study aimed to identify the antioxidant and anticorrosion activities of ginseng prepared using five different solvents. The methanolic fruit extract showed comparatively good activity in all assays. The total phenolic content (TPC) was higher in fruit (95.21 mg/g), followed by leaf (39.21 mg/g) extracted in methanol solvent compared other solvents. The total flavonoid content (TFC) of fruit methanolic extract was 50.21 mg/g, which was followed by fruit extracted in ethanol (41.33 mg/g). The same phenomenon was observed in all antioxidant studies. Through Ultrahigh Performance Liquid Chromatography (UHPLC), the presence of 23 phenolic components categorized as hydroxycinnamic acids, hydroxybenzoic acids and a few other groups that play a vital role in antioxidation was identified. Phenols such as chlorogenic acid (1002.2 μg/g), gentisic acid (854.21 μg/g) and rutin (165.32 μg/g) were found in higher amounts in fruit whereas leaf showed significant amounts of m-coumaric acid (185.32 μg/g) and p-coumaric acid (125.24 μg/g). The anti-corrosive property of the fruit extract of the ginseng with methanol as a solvent was analyzed for a copper specimen exposed to 1 M HCl medium and found to have 96% corrosion inhibition efficiency at a 1000-ppm concentration. The smooth surface of the specimen exposed to corrosive media shown in a field emission scanning electron microscope (FESEM) image confirms that the specimen was protected from corrosion, and energy-dispersive X-ray spectroscopy (EDX) spectra show that the loss of Cu is reduced in inhibited metal surface. Atomic force microscopy (AFM) images and surface roughness factor also validate the corrosion inhibition characteristic of ginseng plant extract. Full article
(This article belongs to the Special Issue Modern Materials and Methods of Mitigating Metal Corrosion)
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