Catalysis by Design: Advances and Challenges in Electrochemical CO2 Reduction

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (31 January 2022) | Viewed by 7210

Special Issue Editors


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Guest Editor
Laboratoire de Chimie Appliquée des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Rabat 1014, Morocco
Interests: materials science; environmental science; chemistry; chemical engineering
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Guest Editor
IM2NP, University of Toulon, LaGarde, France
Interests: development of nanomaterials for environmental applications: detection and transformation of pollutants into clean by-products; nanomaterials; nanostructuration; gas sensor; heterogeneous catalysis; organic dye decomposition; solar photocatalysis; CO2 reduction; methane oxidation; electrical and optical properties
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues, 

Since the industrial revolution in the 19th century, CO2 emission has experienced a remarkable increase in the atmosphere over the subsequent decades, which has led to serious greenhouse effect, abnormal climate change, ocean acidification and ice melting. To address these threats, substantial efforts have been deployed to develop a range of sustainable neutral or negative CO2 footprint technologies to capture and convert atmospheric CO2, including utilization and storage. Therefore, a number of thermochemical, biochemical, photocatalytic and electrocatalytic CO2 reduction technologies have been attempted during the last two decades to convert CO2 to industrially high-value-added chemicals. CO2 electrochemical reduction (CO2ER) in aqueous conditions is an appealing technology because of its room-temperature reaction conditions, the straightforward control of the reaction process and its potential for cell design and scaling up.

This Special Issue aims to attract high-quality short communications, original research papers and review articles that report the recent advances, developments and existing challenges in the field of electrochemical CO2 reduction for chemical products (adsorption and photocatalysis). Articles that highlight oxide materials, 2D materials, nanoparticles, carbon-based materials, Metal Organic Frameworks (MOFs) and linked properties (transport, optical, micro-structural, morphological, nanostructuring) are of particular interest. The relevant fundamentals for CO2ER, including reaction mechanisms and crucial parameters, are also interesting and will be taken into consideration.

Prof. Dr. Hassan AIT AHSAINE
Prof. Dr. Madjid ARAB
Guest Editors

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Keywords

  • CO2 conversion
  • Electrocatalysts
  • Electrochemical reduction
  • Catalytic conversion
  • Electrochemical CO2 reduction

Published Papers (1 paper)

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Review

26 pages, 6404 KiB  
Review
CO2 Electroreduction over Metallic Oxide, Carbon-Based, and Molecular Catalysts: A Mini-Review of the Current Advances
by Hassan Ait Ahsaine, Mohamed Zbair, Amal BaQais and Madjid Arab
Catalysts 2022, 12(5), 450; https://0-doi-org.brum.beds.ac.uk/10.3390/catal12050450 - 19 Apr 2022
Cited by 14 | Viewed by 6025
Abstract
Electrochemical CO2 reduction reaction (CO2RR) is one of the most challenging targets of current energy research. Multi-electron reduction with proton-coupled reactions is more thermodynamically favorable, leading to diverse product distribution. This requires the design of stable electroactive materials having selective [...] Read more.
Electrochemical CO2 reduction reaction (CO2RR) is one of the most challenging targets of current energy research. Multi-electron reduction with proton-coupled reactions is more thermodynamically favorable, leading to diverse product distribution. This requires the design of stable electroactive materials having selective product generation and low overpotentials. In this review, we have explored different CO2RR electrocatalysts in the gas phase and H-cell configurations. Five groups of electrocatalysts ranging from metals and metal oxide, single atom, carbon-based, porphyrins, covalent, metal–organic frameworks, and phthalocyanines-based electrocatalysts have been reviewed. Finally, conclusions and prospects have been elaborated. Full article
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