Recent Advancements in M-N-C Catalysts for Electrochemical Energy Conversion Devices

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Electrocatalysis".

Deadline for manuscript submissions: closed (20 February 2022) | Viewed by 4741

Special Issue Editors

National Renewable Energy Laboratory, Golden, CO 80401, USA
Interests: M-N-C catalysts; metal-organic frameworks; fuel cell; electrolysis; metal-air battery

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Guest Editor
Los Alamos National Laboratory, Los Alamos, NM 87545, USA
Interests: M-N-C catalysts; reaction kinetics; electrode structure; fuel cell; electrolysis
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Special Issue Information

Dear Colleagues,

The growing concerns of the energy crisis and environmental pollution are calling for a viable and sustainable solution. Case in point, to reduce and eventually eliminate our dependence on fossil fuels, efficient and affordable electrochemical energy conversion technologies should be largely implemented. This idea relies heavily on the development of fuel cells, electrolyzers, and batteries, of which the performance is limited by the electrode reactions due to their multiple charge- and proton-transfer steps, which occur typically at three-phase interfaces.

Electrocatalysts with the intention of accelerating the chemical–electricity conversion are currently suffering from unsatisfactory tradeoff between activity, durability, and cost. Boosting the intrinsic activity and the active site density is the key solution, and the use of metal- and nitrogen-codoped carbon (M-N-C) materials with single-atom sites exemplifies such an approach.

This Special Issue entitled “Recent Advancements in M-N-C Catalysts for Electrochemical Energy Conversion Devices” welcomes the submission of manuscripts in the form of original research articles, short communications, and reviews. The topics include M-N-C materials with single-atom sites for all types of energy conversion devices, such as fuel cells, water electrolyzers, CO2 reduction electrolyzers, N2 reduction electrolyzers, batteries, etc.

Experimental and theoretical insights on M-N-C electrocatalyst synthesis, characterization, structure-performance relationship, reaction intermediate pathways, and degradation mechanisms are particularly welcome. Furthermore, electrode structure studies to understand the catalyst aggregate size, catalyst pore size, ionomer distribution, ion transfer and mass transport in bulk electrode, etc., and their impacts on device performance are also kindly invited.

Dr. Hao Wang
Dr. Luigi Osmieri
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • M-N-C electrocatalysts
  • Single-atom electrocatalysts
  • Battery
  • Fuel cell
  • Electrolysis
  • Oxygen reduction/evolution reaction
  • Hydrogen evolution/oxidation reaction
  • CO2 reduction reaction
  • N2 reduction reaction
  • Electrode structure

Published Papers (1 paper)

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Review

22 pages, 3267 KiB  
Review
Multifunctional Electrocatalysis on Single-Site Metal Catalysts: A Computational Perspective
by Ritums Cepitis, Nadezda Kongi, Vitali Grozovski, Vladislav Ivaništšev and Enn Lust
Catalysts 2021, 11(10), 1165; https://0-doi-org.brum.beds.ac.uk/10.3390/catal11101165 - 27 Sep 2021
Cited by 12 | Viewed by 3811
Abstract
Multifunctional electrocatalysts are vastly sought for their applications in water splitting electrolyzers, metal-air batteries, and regenerative fuel cells because of their ability to catalyze multiple reactions such as hydrogen evolution, oxygen evolution, and oxygen reduction reactions. More specifically, the application of single-atom electrocatalyst [...] Read more.
Multifunctional electrocatalysts are vastly sought for their applications in water splitting electrolyzers, metal-air batteries, and regenerative fuel cells because of their ability to catalyze multiple reactions such as hydrogen evolution, oxygen evolution, and oxygen reduction reactions. More specifically, the application of single-atom electrocatalyst in multifunctional catalysis is a promising approach to ensure good atomic efficiency, tunability and additionally benefits simple theoretical treatment. In this review, we provide insights into the variety of single-site metal catalysts and their identification. We also summarize the recent advancements in computational modeling of multifunctional electrocatalysis on single-site catalysts. Furthermore, we explain each modeling step with open-source-based working examples of a standard computational approach. Full article
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