Recent Developments in Catalysts for Space Thrusters Using Green Monopropellants

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (31 March 2022) | Viewed by 3365

Special Issue Editors


E-Mail Website
Guest Editor
In-Space Propulsion Branch, Rocket Propulsion Division, Aerospace Systems Directorate, Air Force Research Laboratory, AFRL/RQRS, Edwards Air Force Base, CA 93524, USA
Interests: Dr. Vaghjiani studies and evaluates reaction pathways pertinent to the understanding of numerous rocket propellant decomposition and spacecraft-atmospheric processes. Experimental findings are rationalized using modern quantum chemical and molecular dynamics theories to construct reaction models, which enable one to understand the mechanisms and to extrapolate from the laboratory to the conditions of real world rocket combustion, propulsion, and in-space applications.

E-Mail Website
Co-Guest Editor
Department of Aerospace Engineering, Indian Institute of Science, Bangalore, India
Interests: propellants; combustion; catalysts; coal combustion

Special Issue Information

Dear Colleagues,

The power plant in most of the reaction control systems (RCS) in satellites use monopropellants. Monopropellants are chemicals that can be easily decomposed when sprayed over a catalytic bed. The exothermic decomposition and expansion of decomposed products through a nozzle provide the required thrust for orbit control or other maneuvers that need precise control. Anhydrous hydrazine has been in use for almost five decades as a reliable and high-performing monopropellant in space thrusters. However, with the realization of its high toxicity and escalating handling costs along with increasing environmental awareness, there has been a surge in the search for newer green propellants which are both environmentally friendly and high-performing. Some of the monopropellants that have gained prominence in recent times are hydroxylammonium nitrate (HAN), ammonium dinitramide (ADN), nitrous oxide, and hydrogen peroxide. Volumetric specific impulse and safety associated with these chemicals are impressive and satellites powered by prototypes using these chemicals have been successfully deployed recently. However, typical of any energetic materials, the evolution of a mature technology takes decades, and the development of a catalyst for the propellant decomposition is a critical and most crucial component in thruster development. The catalyst while ensuring a smooth decomposition with the shortest ignition delay should also remain active without any passivation or attrition through the length of the mission. Finding a suitable active metal, high-temperature tolerant support, bed configuration, and other crucial parameters are formidable challenges in the journey to a higher technology readiness level. While the research findings in this domain may remain more or less classified due to the strategic importance, there has been open-ended research both at academic laboratories and space centers focused on thruster development. Realizing the importance of consolidating the findings in this field and sensitize and initialize other catalyst researchers to this vital space technology that can wipe out the use of toxic hydrazine, “catalysts” has decided to bring out a special issue on “Recent development in catalysts for space thrusters using green monopropellants”. The articles can be both original research articles or comprehensive reviews that encompass a particular field. Some of the likely titles can be as follows

  1. Green propellant overview
  2. Ionic liquids as propellants 
  3. MP: mission scenario and thruster designs
  4. MP: decomposition catalyst development  
  5. MP: catalyst decomposition chemistry and kinetics
  6. MP: catalyst bed configuration and thruster design
  7. MP: numeric models for catalytic decomposition
  8. DFT or other quantum mechanical methods for exploring heterogeneous catalysis mechanisms in space thrusters

MP: monopropellant (MP) can be HAN, ADN, HP, nitrous oxide, or any other energetic ionic liquid that can be considered as a green monopropellant

Dr. Ghanshyam L. Vaghjiani
Prof. Dr. Charlie Oommen
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Green In-Space Propulsion
  • Hydroxylammonium Nitrate-based Fuels
  • Monopropellant Thrusters
  • Hydrazine Alternatives
  • monopropellants
  • catalyst
  • space thrusters
  • high-temperature catalyst
  • combustion

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Research

22 pages, 7587 KiB  
Article
Effect of Metal Sequestrants on the Decomposition of Hydroxylammonium Nitrate
by Emil J. Broemmelsiek, Joshua L. Rovey and Steven P. Berg
Catalysts 2021, 11(12), 1488; https://doi.org/10.3390/catal11121488 - 04 Dec 2021
Cited by 2 | Viewed by 2399
Abstract
Hydroxylammonium nitrate (HAN) is an energetic salt used in flight-proven green monopropellants such as ASCENT (formerly AF-M315E), flown in NASA’s 2019 Green Propellant Infusion Mission, and SHP163, flown in JAXA’s Rapid Innovative Satellite Technology Demonstration-1. The decomposition of HAN is catalyzed by metals [...] Read more.
Hydroxylammonium nitrate (HAN) is an energetic salt used in flight-proven green monopropellants such as ASCENT (formerly AF-M315E), flown in NASA’s 2019 Green Propellant Infusion Mission, and SHP163, flown in JAXA’s Rapid Innovative Satellite Technology Demonstration-1. The decomposition of HAN is catalyzed by metals commonly found in storage tanks, a factor limiting its use. This work investigates the ability of metal-sequestering chelating agents to inhibit the decomposition of HAN. Isothermal and dynamic thermogravimetric analysis (TGA) were used to find isothermal decomposition rates, decomposition onset temperatures, and first-order Arrhenius reaction rate parameters. In the present research, 2,2′-bipyridine (Bipy), triethanolamine (TEA), and ethylenediaminetetraacetic acid (EDTA) were studied as 0.05, 0.1, 0.5, 1, and 5% by weight additives in 90% aqueous HAN. An isothermal decomposition rate of 0.137%/h at 348 K was observed for HAN. The addition of 1% Bipy and 1% TEA reduced the isothermal decomposition rate by 20.4% to 0.109%/h, and by 3.65% to 0.132%/h, respectively, showing that Bipy can inhibit decomposition. The addition of 1% EDTA increased the isothermal decomposition rate by 12.4% to 0.154%/h. Bipy was found to increase the decomposition onset temperature from 454.8 K to 461.8 K, while the results for TEA and EDTA were inconclusive. First order reaction rates calculated by the Ozawa-Flynn-Wall method were found to be insufficient to capture the effects of the tested additives. Bipy was found to inhibit the decomposition of HAN, while TEA and EDTA produced little or negative effect, a result believed to be due to poor metal complex stability at low pH and high acidity, respectively. Spectrophotometry, used for colorimetric analysis of Bipy+iron complexes, showed that Bipy forms chelate complexes with trace iron impurities when added to HAN solutions. Full article
Show Figures

Figure 1

Back to TopTop