New Research Trends in Rare Earth Oxide-Based Catalysts

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 6636

Special Issue Editors


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Guest Editor
Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, Puerto Real (Cádiz), Spain
Interests: heterogeneous catalysis, lanthanoid oxides, carbon materials, surface science, nanoparticles

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Guest Editor
Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, 11510 Puerto Real (Cádiz), Spain
Interests: heterogeneous catalysis; lanthanoid oxides; X-ray photoelectron spectroscopy; nanoparticles
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Special Issue Information

Dear Colleagues,

According to the recent IUPAC recommendations, rare earth elements refer to a family of 17 chemical elements encompassing the 15 lanthanoids (i.e., from lanthanum to lutetium) along with scandium and yttrium. Over the past few decades, especially from the establishment and development of the three-way catalyst (TWC) technology, rare earth oxides have become ubiquitous materials in heterogeneous catalysis. In this application field, they are extensively used either as catalysts or, much more frequently, as supports of a variety of metal-containing catalytic active phases and as structural and electronic promoters. Such an extensive use chiefly arises from the unique and excellent solid-state properties of rare earth oxides, which can be easily tailored to the specific requirements of catalytic processes. Among these features, the surface basic character, significantly decreasing from lanthana (La2O3) to lutetia (Lu2O3), and redox properties, associated with some reversible redox couples (mainly Ce4+/Ce3+, but also Pr4+/Pr3+ and Tb4+/Tb3+), have been traditionally considered as the most relevant with regard to the catalytic applications of these materials. Nevertheless, the increasingly growing technological applications of rare earth oxides, together with the relative scarcity and limited geographical distribution of their economically viable ores, have led to a steady rise in prices during the last decade. Therefore, making a more efficient use of these oxides by reducing and optimizing their contents in catalysts formulations has currently become not only a mandatory practice but also a great challenge for the catalysis science community. This situation is pushing forward the development of new research lines aimed at designing novel rare earth oxide-based catalysts with improved activity and stability as well as lower economic cost. The present Special Issue of Catalysts is intended to provide a broad overview of recent progress and research trends in the field of rare earth oxide-based catalysts, covering from their design, preparation, and characterization to their testing in catalytic processes with environmental, energy or industrial interest. Furthermore, both experimental and theoretical studies aimed at understanding the fundamentals of these materials for heterogeneous catalytic applications are also welcome. We strongly encourage researchers to submit their original works as full papers, communications or reviews.

Dr. Adrian Barroso-Bogeat
Prof. Dr. Ginesa Blanco
Guest Editors

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Keywords

  • Rare earth oxides Lanthanoids Heterogeneous catalysis Photocatalysis
  • Catalyst preparation
  • Catalyst characterization
  • Catalyst testing, deactivation and regeneration
  • Environmental catalysis
  • Fine chemical synthesis
  • Energy

Published Papers (2 papers)

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17 pages, 8754 KiB  
Article
Approach to the Characterization of Monolithic Catalysts Based on La Perovskite-like Oxides and Their Application for VOC Oxidation under Simulated Indoor Environment Conditions
by Ornel Padilla, Jessica Munera, Jaime Gallego and Alexander Santamaria
Catalysts 2022, 12(2), 168; https://0-doi-org.brum.beds.ac.uk/10.3390/catal12020168 - 28 Jan 2022
Cited by 8 | Viewed by 2397
Abstract
Catalysts are very important in controlling the pollutant emissions and are used for hundreds of chemical processes. Currently, noble metal-based catalysts are being replaced for other kinds of materials. In this study, three lanthanum-based perovskite-like oxides were synthesized (LaCo, LaCoMn, and LaMn) by [...] Read more.
Catalysts are very important in controlling the pollutant emissions and are used for hundreds of chemical processes. Currently, noble metal-based catalysts are being replaced for other kinds of materials. In this study, three lanthanum-based perovskite-like oxides were synthesized (LaCo, LaCoMn, and LaMn) by the glycine-combustion method. The powder catalysts obtained were supported onto cordierite ceramic monoliths using an optimized washcoating methodology to obtain the subsequent monolithic catalysts (LaCo-S, LaCoMn-S, and LaMn-S). Sample characterization confirmed the formation of the perovskite-like phase in the powder materials as well as the presence of the perovskite phase after supporting it onto the monolithic structure. The XPS analysis showed a general decrease in lattice oxygen species for monolithic catalysts, mainly caused by the colloidal silica used as a binder agent during the washcoating process. Additionally, some variations in the oxidation state distribution for elements in Co-containing systems suggest a stronger interaction between cordierite and such catalysts. The catalytic activity results indicated that powder and monolithic catalysts were active for single-component VOC oxidation in the following order: 2-propanol > n-hexane ≅ mixture > toluene, and there was no evidence of loss of catalytic activity after supporting the catalysts. However, LaMn-S had a better catalytic performance for all VOC tested under dry conditions, achieving oxidation temperatures between 230–420 °C. The oxidation efficiency for the VOC mixture was strongly affected by the presence of moisture linking the oxidation efficiency at wet conditions to the VOC chemical nature. Additionally, for higher VOC concentrations, the catalyst efficiency decreased due to the limited number of active sites. Full article
(This article belongs to the Special Issue New Research Trends in Rare Earth Oxide-Based Catalysts)
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17 pages, 2524 KiB  
Article
Transition Metal B-Site Substitutions in LaAlO3 Perovskites Reorient Bio-Ethanol Conversion Reactions
by Quang Nguyen Tran, Olinda Gimello, Nathalie Tanchoux, Monica Ceretti, Stefania Albonetti, Werner Paulus, Barbara Bonelli and Francesco Di Renzo
Catalysts 2021, 11(3), 344; https://0-doi-org.brum.beds.ac.uk/10.3390/catal11030344 - 07 Mar 2021
Cited by 11 | Viewed by 3238
Abstract
LaAlO3 perovskites, as such and with 25% molar Al substitution by Cu, Co, or Ga, have been prepared by sol-gel methods and tested as heterogeneous catalysts in the gas-phase conversion of ethanol. LaAlO3 presented a significant acidic character, with high formation [...] Read more.
LaAlO3 perovskites, as such and with 25% molar Al substitution by Cu, Co, or Ga, have been prepared by sol-gel methods and tested as heterogeneous catalysts in the gas-phase conversion of ethanol. LaAlO3 presented a significant acidic character, with high formation of ethylene by ethanol dehydration. B-site substitutions increased the basicity of the catalysts, favoring the dehydrogenation of ethanol to acetaldehyde. The most reducible Cu- and Co-substituted materials, characterized by easier formation of surface oxygen vacancies, promoted the self-condensation of acetaldehyde by the Tishchenko mechanism, with formation of acetone and odd-carbon number products. Aldol coupling of acetaldehyde, favored on pure and Ga-substituted LaAlO3, led to the formation of butadiene and hexadiene. The role of Ga insertion, favoring both dehydrogenation of ethylene and dehydration of higher alcohols, corresponds to an amphoteric character. The formation of olefins and diolefins on all catalysts suggests that LaAl-based materials present the most acidic character among La-perovskites. Full article
(This article belongs to the Special Issue New Research Trends in Rare Earth Oxide-Based Catalysts)
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