Natural Fibre Biocomposites

A special issue of Fibers (ISSN 2079-6439).

Deadline for manuscript submissions: closed (31 August 2018) | Viewed by 44531

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Guest Editor
Department of Mechanical and Energy Engineering, University of North Texas, Denton, TX 76203, USA
Interests: functional natural fiber composites; biomass to carbon conversion; engineered wood products
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Special Issue Information

Dear Colleagues,

This Special Issue is designed to update state-of-the-art technologies of biodegradable natural fibercomposite products. This Special Issue will consist of (but is not limit to) the following aspects:

  1. Fiber retting: The technologies for the conversion of wood and bast into fibers, including mechanical retting, bacterial retting, chemical retting, and other techniques;
  2. Fiber property characterizations: The physical and mechanical properties of different natural fibers, including wood, kenaf, hemp, cotton, wheat straw, bamboo, sisal, flex, and others;
  3. Fiber treatments: 1) treatment of natural fibers to enhance the interfacial bonding of fibers and the performance of the resulting composites; 2) treatment of natural fiber for the functionalization of fiber and the resulting composites;
  4. Bioresins and bioadhesives: This is to focus on the technology development of biodegradable adhesives and resins, such as soy based resin, glycosyl resin, and other plant based adhesives.Composites fabrication: Processing techniques for both structural and nonstructural natural fiber composites;
  5. Physical and mechanical properties, including decay resistant, biodegradability, mechanical performance, physical performance (thermal, sound, and others) of natural fiber composites
  6. Applications, including building, transportation, automobile and aerospace, military, and others

Prof. Sheldon Shi
Guest Editor

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Keywords

  • Natural fiber treatment
  • Bioresin and bioadhesive
  • Natural fiber composites fabrication
  • Functional composites
  • Nanoparticle

Published Papers (7 papers)

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Research

19 pages, 3834 KiB  
Article
Physico-Mechanical, Thermal and Biodegradation Performance of Random Flax/Polylactic Acid and Unidirectional Flax/Polylactic Acid Biocomposites
by Mahmudul Akonda, S. Alimuzzaman, D. U. Shah and A.N.M. Masudur Rahman
Fibers 2018, 6(4), 98; https://0-doi-org.brum.beds.ac.uk/10.3390/fib6040098 - 10 Dec 2018
Cited by 27 | Viewed by 6142
Abstract
Fully biodegradable flax/polylactic acid (PLA) thermoplastic composites were fabricated by using random (nonwoven mat) and aligned (unidirectional yarn) flax fiber as reinforcements (39% flax by volume) and Polylactic acid (PLA) as matrix. Results revealed that the aligned flax fibers have a greater reinforcing [...] Read more.
Fully biodegradable flax/polylactic acid (PLA) thermoplastic composites were fabricated by using random (nonwoven mat) and aligned (unidirectional yarn) flax fiber as reinforcements (39% flax by volume) and Polylactic acid (PLA) as matrix. Results revealed that the aligned flax fibers have a greater reinforcing effect due to the uniform distribution of load axially along the fiber length in the composite. The aligned flax/PLA and random flax/PLA showed the tensile strength of (83.0 ± 5.0) and (151.0 ± 7.0) MPa respectively and flexural strength of (130.0 ± 5.0) and (215.0 ± 7.2) MPa respectively. Young’s modulus of (9.3 ± 1.5) and (18.5 ± 2.0) GPa and flexural modulus of (9.9 ± 1.0) and (18.8 ± 1.0) GPa was attained for the random and unidirectional fiber composites, respectively. It was also found that both composite constituents, fiber and matrix, were degradable if buried in compost soil (ready soil after composting process), which is a distinctive advantage of the new composite structures. Remarkably, the biodegradation property of aligned flax fiber composites was significantly lower than random mat composites, possibly due to the less water swelling behavior of the aligned fiber composites. After 120 days burial test, the aligned flax/PLA composite displayed the reduction of 19% mass, residual flexural strength and modulus decreased by 57 and 50% respectively, while the random mat composites exhibited the loss of 27% mass, residual flexural strength and modulus declined by 80% at the same period. Full article
(This article belongs to the Special Issue Natural Fibre Biocomposites)
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17 pages, 4665 KiB  
Article
Effect of Density and Fiber Size on Porosity and Thermal Conductivity of Fiberboard Mats
by Pamela Rebolledo, Alain Cloutier and Martin-Claude Yemele
Fibers 2018, 6(4), 81; https://0-doi-org.brum.beds.ac.uk/10.3390/fib6040081 - 19 Oct 2018
Cited by 22 | Viewed by 7917
Abstract
The thermal conductivity and porosity of fiberboard mats are crucial parameters for efficient energy consumption of the hot-pressing process and for final panel quality. In this work, the effect of fiber size and mat density on porosity and thermal conductivity of the mat [...] Read more.
The thermal conductivity and porosity of fiberboard mats are crucial parameters for efficient energy consumption of the hot-pressing process and for final panel quality. In this work, the effect of fiber size and mat density on porosity and thermal conductivity of the mat were investigated. The fiber size was characterized as fine, medium and coarse. The mat porosity was measured by image analysis using the black and white contrast method. The thermal conductivity was determined at different density levels with a temperature gradient of 1.6 °C mm−1 and 7.6% (s = 0.3) moisture content. The results showed that fiber size was a dominant variable governing heat conduction and mat porosity. The mats made with medium size fibers showed a higher resistance to compression. The thermal conductivity of coarse fiber mats decreased drastically between 700 kg m−3 and 810 kg m−3. This was likely due to a higher fracture frequency observed for coarse fibers in comparison to the other fiber sizes studied. Hence, the fine and medium fibers conducted heat more efficiently. Moreover, fiber bundles and fractured fibers were observed during the mat porosity measurements, principally in mats made with fine fiber size. Full article
(This article belongs to the Special Issue Natural Fibre Biocomposites)
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11 pages, 3530 KiB  
Article
Moisture Absorption and Opacity of Starch-Based Biocomposites Reinforced with Cellulose Fiber from Bengkoang
by Fadli Hafizulhaq, Hairul Abral, Anwar Kasim, Syukri Arief and Jon Affi
Fibers 2018, 6(3), 62; https://0-doi-org.brum.beds.ac.uk/10.3390/fib6030062 - 29 Aug 2018
Cited by 23 | Viewed by 5944
Abstract
Cellulose fiber was isolated from bengkoang (Pachyrhizus erosus) tuber peel. A suspension consisting of distilled water, starch, and glycerol was mixed with various cellulose loadings (0, 2, 6, and 10 g) then gelatinized using a hot plate with a magnetic stirrer. [...] Read more.
Cellulose fiber was isolated from bengkoang (Pachyrhizus erosus) tuber peel. A suspension consisting of distilled water, starch, and glycerol was mixed with various cellulose loadings (0, 2, 6, and 10 g) then gelatinized using a hot plate with a magnetic stirrer. The biocomposite gel was sonicated using an ultrasonication probe (47.78 W/cm2 for 4 min). Scanning electron microscopy (SEM) micrographs for the fracture surface of resulting biocomposite films displayed a rougher surface than starch film, indicating fiber dispersion in the matrix. The opacity and moisture resistance of biocomposite films increased with the addition of cellulose. The opacity was at a maximum value (243.05 AUnm) with 10 g fiber, which was 11.27% higher than the starch film without cellulose. Moisture absorption of this biocomposite was 16.79% lower than the starch film. Fourier transform infrared (FTIR) confirmed this more hydrophobic nature with lower transmittance at –OH stretching in the composite than the starch film. The addition of cellulose fiber into the matrix also increased the crystallinity index. Full article
(This article belongs to the Special Issue Natural Fibre Biocomposites)
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14 pages, 5837 KiB  
Article
Influence of Furfuryl Alcohol Fiber Pre-Treatment on the Moisture Absorption and Mechanical Properties of Flax Fiber Composites
by Yunlong Jia and Bodo Fiedler
Fibers 2018, 6(3), 59; https://0-doi-org.brum.beds.ac.uk/10.3390/fib6030059 - 19 Aug 2018
Cited by 13 | Viewed by 5743
Abstract
Poor moisture resistance of natural fiber reinforced bio-composites is a major concern in structural applications. Many efforts have been devoted to alleviate degradation of bio-composites caused by moisture absorption. Among them, fiber pre-treatment has been proven to be effective. This paper proposes an [...] Read more.
Poor moisture resistance of natural fiber reinforced bio-composites is a major concern in structural applications. Many efforts have been devoted to alleviate degradation of bio-composites caused by moisture absorption. Among them, fiber pre-treatment has been proven to be effective. This paper proposes an alternative “green” fiber pretreatment with furfuryl alcohol. Pre-treatments with different parameters were performed and the influence on the mechanical properties of fiber bundles and composites was investigated. Moisture resistance of composites was evaluated by water absorption tests. Mechanical properties of composites with different water contents were analyzed in tensile tests. The results show that furfuryl alcohol pretreatment is a promising method to improve moisture resistance and mechanical properties (e.g., Young’s modulus increases up to 18%) of flax fiber composites. Full article
(This article belongs to the Special Issue Natural Fibre Biocomposites)
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12 pages, 2045 KiB  
Article
Heat and Mass Transfer Properties of Sugar Maple Wood Treated by the Thermo-Hygro-Mechanical Densification Process
by Qilan Fu, Alain Cloutier and Aziz Laghdir
Fibers 2018, 6(3), 51; https://0-doi-org.brum.beds.ac.uk/10.3390/fib6030051 - 24 Jul 2018
Cited by 3 | Viewed by 4745
Abstract
This study investigated the evolution of the density, gas permeability, and thermal conductivity of sugar maple wood during the thermo-hygro-mechanical densification process. The results suggested that the oven-dry average density of densified samples was significantly higher than that of the control samples. However, [...] Read more.
This study investigated the evolution of the density, gas permeability, and thermal conductivity of sugar maple wood during the thermo-hygro-mechanical densification process. The results suggested that the oven-dry average density of densified samples was significantly higher than that of the control samples. However, the oven-dry density did not show a linear increase with the decrease of wood samples thickness. The radial intrinsic gas permeability of the control samples was 5 to 40 times higher than that of densified samples, which indicated that the void volume of wood was reduced notably after the densification process. The thermal conductivity increased by 0.5–1.5 percent for an increase of one percent moisture content for densified samples. The thermal conductivity of densified wood was lower than that of the control samples. The densification time had significant effects on the oven-dry density and gas permeability. Both densification time and moisture content had significant effects on thermal conductivity but their interaction effect was not significant. Full article
(This article belongs to the Special Issue Natural Fibre Biocomposites)
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9 pages, 5567 KiB  
Article
Mechanical Properties of a Water Hyacinth Nanofiber Cellulose Reinforced Thermoplastic Starch Bionanocomposite: Effect of Ultrasonic Vibration during Processing
by Mochamad Asrofi, Hairul Abral, Anwar Kasim, Adjar Pratoto, Melbi Mahardika and Fadli Hafizulhaq
Fibers 2018, 6(2), 40; https://0-doi-org.brum.beds.ac.uk/10.3390/fib6020040 - 08 Jun 2018
Cited by 61 | Viewed by 8258
Abstract
Thermoplastic starch (TPS) reinforced by 1 wt % nanofiber cellulose (NFC) reinforcing from water hyacinth was produced. Ultrasonic vibration time (UVT) was applied to bionanocomposites during gelation for 0, 15, 30 and 60 min. Morphology of the NFC was investigated using Transmission Electron [...] Read more.
Thermoplastic starch (TPS) reinforced by 1 wt % nanofiber cellulose (NFC) reinforcing from water hyacinth was produced. Ultrasonic vibration time (UVT) was applied to bionanocomposites during gelation for 0, 15, 30 and 60 min. Morphology of the NFC was investigated using Transmission Electron Microscopy (TEM). Scanning Electron Microscopy (SEM) and tensile tests were performed to identify the fracture surface and determine the mechanical properties of the bionanocomposites, respectively. The Crystallinity index (CI) of untreated and treated bionanocomposites was measured using X-ray Diffraction (XRD). The average diameter of NFC water hyacinth was 10–20 nm. The maximum tensile strength (TS) and modulus elasticity (ME) of the bionanocomposite was 11.4 MPa and 443 MPa respectively, after 60 min UVT. This result was supported by SEM which indicated good dispersion and compact structure. Full article
(This article belongs to the Special Issue Natural Fibre Biocomposites)
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16 pages, 2061 KiB  
Article
Various Extraction Methods Influence the Adhesive Properties of Dried Distiller’s Grains and Solubles, and Press Cakes of Pennycress (Thlaspi arvense L.) and Lesquerella [Lesquerella fendleri (A. Gary) S. Watson], in the Fabrication of Lignocellulosic Composites
by Brent Tisserat, Fred Eller and Rogers Harry-O’kuru
Fibers 2018, 6(2), 26; https://0-doi-org.brum.beds.ac.uk/10.3390/fib6020026 - 24 Apr 2018
Cited by 7 | Viewed by 5079
Abstract
Lignocellulosic composite (LC) panels were fabricated using an adhesive matrix prepared from three different agricultural by-products: dried distillers grains with solubles (DDGS), pennycress (Thlaspi arvense L.) press cake (PPC), or lesquerella [Lesquerella fendleri (A. Gary) S. Watson] press cake (LPC) reinforced [...] Read more.
Lignocellulosic composite (LC) panels were fabricated using an adhesive matrix prepared from three different agricultural by-products: dried distillers grains with solubles (DDGS), pennycress (Thlaspi arvense L.) press cake (PPC), or lesquerella [Lesquerella fendleri (A. Gary) S. Watson] press cake (LPC) reinforced with Paulownia elongata L. wood (PW) particles. The goal in this study was to assess the mechanical properties of composites utilizing these low-cost matrix materials, which were subjected to various oil extraction methods. Three types of oil extraction methods were utilized: ethanol, supercritical CO2, and hexane, in order to generate matrix materials. These matrix materials were mixed with equal proportions of PW and hot pressed to generate panels. Overall, hexane extraction was the best method to enhance the mechanical properties of the matrices used to fabricate lignocellulosic composites. LPC’s produced a matrix that gave the resulting composite superior flexural properties compared to composites generated from DDGS and PPC matrices. The mechanical properties of composites generated from soy products (soybean meal flour or soy protein isolate) were similar to those derived from DDGS, PPC, or LPC. The dimensional stability properties of LCs were improved when the hexane extraction method was employed, unlike with the other extraction methods that were used to generate matrices. Full article
(This article belongs to the Special Issue Natural Fibre Biocomposites)
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