Metal-Catalyzed C−H Functionalization

A special issue of Inorganics (ISSN 2304-6740). This special issue belongs to the section "Organometallic Chemistry".

Deadline for manuscript submissions: closed (20 January 2024) | Viewed by 5745

Special Issue Editors


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Guest Editor
Department of Chemistry, Christ University, Bengaluru, India
Interests: homogeneous and heterogeneous catalysis; organic synthesis; organometallics; coordination chemistry; transition metal catalysis

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Guest Editor
Department of Chemistry, Technische Universität Berlin, Straße des 17. Juni 115, 10623 Berlin, Germany
Interests: organometallics; homogeneous catalysis; biomass; green chemistry; transition metal chemistry; hydrogenation; dehydrogenation; amination; hydrogen borrowing

Special Issue Information

Dear Colleagues,

Transition metal catalyzed C‒H bond functionalization is currently one of the most widely investigated fields, which have, currently, a broad diversion in terms of ligand engineering, catalyst design, elucidation of reaction mechanism, controlling of regio-selectivity, short-step synthesis of various important structural motifs of natural products and biological compounds. One of the major reasons for such wide progress in C‒H bond functionalization chemistry is the omnipresence of C‒H bonds in organic molecules. Conversely, this ubiquitous nature of C‒H bonds can cause a thoughtful drawback in terms of a selectivity issue. Therefore, various tactics are being discovered worldwide by various research groups to do the functionalization in a selective way. Considering the applicability and efficacy of C‒H bond activation chemistry, the inorganic and organic research community indeed thinks that this field has wide advantages for laboratory and industrial research, and it has the potential to deliver more exciting and new strategies in respect of new catalyst designing and selective functionalization.

In this Special Issue, we wish to cover the recent advancement of C‒H bond functionalization chemistry using homogeneous or heterogeneous systems. Regardless, we would be happy to consider short critical reviews along with the significant original discoveries in this area of research.

Dr. Supriya Rej
Dr. Saravanakumar Elangovan
Guest Editors

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Keywords

  • C‒H bond functionalization
  • homogeneous and heterogeneous catalysts
  • organometallics & C‒H activation
  • transition metal catalysis
  • directing group
  • reaction mechanism

Published Papers (1 paper)

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Review

15 pages, 6494 KiB  
Review
Functionalization of Porphyrins Using Metal-Catalyzed C–H Activation
by Aleksey N. Kiselev, Sergey A. Syrbu, Natalia Sh. Lebedeva and Yury A. Gubarev
Inorganics 2022, 10(5), 63; https://0-doi-org.brum.beds.ac.uk/10.3390/inorganics10050063 - 13 May 2022
Cited by 5 | Viewed by 4865
Abstract
The review is devoted to the C–H functionalization of porphyrins. Porphyrins exhibit the properties of organic semiconductors, light energy converters, chemical and electrochemical catalysts, and photocatalysts. The review describes the iridium- and palladium-catalyzed direct functionalization of porphyrins, with more attention given to the [...] Read more.
The review is devoted to the C–H functionalization of porphyrins. Porphyrins exhibit the properties of organic semiconductors, light energy converters, chemical and electrochemical catalysts, and photocatalysts. The review describes the iridium- and palladium-catalyzed direct functionalization of porphyrins, with more attention given to the results obtained in our laboratory. The development and improvement of synthetic methods that do not require preliminary modification of the substrate with various functional groups are extremely important for the preparation of new organic materials based on porphyrins. This makes it possible to simplify the synthetic procedure, to make the synthesis more economical, environmentally safe, and simple to perform. Full article
(This article belongs to the Special Issue Metal-Catalyzed C−H Functionalization)
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Scheme 1

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