Structure, Thermodynamics and Applications of Ferrofluids

A special issue of Magnetochemistry (ISSN 2312-7481). This special issue belongs to the section "Magnetic Materials".

Deadline for manuscript submissions: closed (31 December 2022) | Viewed by 4970

Special Issue Editor


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Guest Editor
Institute of Physics and Mechatronics, University of Pannonia, Veszprém, Veszprém, Egyetem u. 10, 8200, Hungary
Interests: statistical physics of liquids; application of complex liquids; measurement techniques

Special Issue Information

Dear Colleagues,

The number of new materials with extreme physical properties is continuously increasing with the development of nanotechnology, such as supra- and paramagnetic ferrofluids, liquid crystals, magnetorheological (MR), and electrorheological (ER) liquids. Among them, a ferrofluid is a liquid that becomes highly magnetized in the presence of a magnetic field. A ferrofluid is a colloidal suspension of single-domain particles dispersed in a carrier liquid and stabilized by a suitable organic surfactant. The particles have radii ranging from approximately 2–10 nm. Single-domain particles are particles that are in a state of uniform magnetization. The magnetic properties of the dispersion, subjected to a constant magnetizing field, are adequately described by the Langevin theory of paramagnetism. Ferrofluids are characterized by a magnetization curve that displays no hysteresis. The measurement of the complex susceptibility of a colloidal suspension of magnetic particles involves the measurement of inductance and resistance of the suspension. The frequency range is determined by the size of the magnetic particles and their subsequent mechanism of relaxation. For magnetic fluids, two relaxation mechanisms can occur, one by rotational Brownian diffusion and the other by Neel relaxation. The dominant magnetization process of a particle will be that which has the shortest relaxation time. As ferrofluids contain a distribution of particle sizes, both mechanisms contribute to the magnetization with an effective relaxation. The conventional method of determining the frequency dependence of the complex susceptibility of a ferrofluid is to insert the fluid into the alternating magnetic field of a coil and observe the changes in its inductance and resistance.

Ferrofluids have many applications ranging from small electronic devices to space crafts to cancer treatments to art. Ferrofluids are found in many common household devices, including hard drives where they are used to seal the interior of the device. When magnetized they form a barrier to dust and dirt that could damage the delicate plates. Ferrofluids can be viewed as a particularly interesting class of dipolar fluids, which have a wide range of potential applications in biomedicine and technology. Separation, immunoassay, drug delivery, magnetic resonance imaging (MRI), and hyperthermia are enhanced by the use of magnetic nanoparticles and ferrofluids. Ferrofluids can have very high thermal conductivities and their heat transfer properties are exploited in devices such as loudspeakers.

This Special Issue will focus on the structural, transport, and thermodynamic properties of ferrofluids, practical usability of ferrofluid materials in industrial, environmental, and medical applications, as well as the dependence of the phase equilibrium properties of these complex fluids on external electric and magnetic fields.

Prof. Dr. Istvan Szalai
Guest Editor

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Keywords

  • Ferrofluids
  • Structure of ferrofluids 
  • Thermodynamics of ferrofluids 
  • Magnetic nanoparticles 
  • Nanomagnetism
  • Nuclear magnetic resonance 
  • Magnetic resonance imaging 
  • Superparamagnetic iron oxide nanoparticles 
  • Ultrastable colloidal suspensions
  • Dynamic magnetic susceptibility 
  • Brownian dynamics simulations 
  • Computer simulation 
  • Phase behavior
  • Dipolar fluids
  • Magnetic materials 
  • Magnetic properties
  • Biomedical applications

Published Papers (2 papers)

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Research

11 pages, 905 KiB  
Article
Magnetic Field-Induced Deformation of Isotropic Magnetorheological Elastomers
by Diána Balogh, Sándor Guba, Barnabás Horváth and István Szalai
Magnetochemistry 2022, 8(11), 146; https://0-doi-org.brum.beds.ac.uk/10.3390/magnetochemistry8110146 - 03 Nov 2022
Cited by 6 | Viewed by 1403
Abstract
In our research, the magnetic field-induced deformation of isotropic magnetorheological elastomer (MRE) discs loaded with two types of magnetite and an iron powder were examined. A measurement system using a microscope camera was assembled, and the magnitude of the deformation was determined from [...] Read more.
In our research, the magnetic field-induced deformation of isotropic magnetorheological elastomer (MRE) discs loaded with two types of magnetite and an iron powder were examined. A measurement system using a microscope camera was assembled, and the magnitude of the deformation was determined from the optical contour obtained with digital image processing. We found that the MRE discs with a height-to-width aspect ratio of 1:2 underwent expansion in the direction of the external field in all cases. The magnitude of the dilatation increased with the magnetic field strength in cases of all filler materials, but the exact trend depended on the type and concentration of the filler. An inhibition of the polymerization of the matrix was observed in the case of one of the magnetite fillers, which resulted in a decreased zero-field elastic modulus at higher particle loadings. A correlation was found between the reduced elastic modulus and the increased magnitude of the deformation. Full article
(This article belongs to the Special Issue Structure, Thermodynamics and Applications of Ferrofluids)
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20 pages, 8693 KiB  
Article
Dynamics of a Pair of Paramagnetic Janus Particles under a Uniform Magnetic Field and Simple Shear Flow
by Christopher Sobecki, Jie Zhang and Cheng Wang
Magnetochemistry 2021, 7(1), 16; https://0-doi-org.brum.beds.ac.uk/10.3390/magnetochemistry7010016 - 19 Jan 2021
Cited by 4 | Viewed by 2906
Abstract
We numerically investigate the dynamics of a pair of circular Janus microparticles immersed in a Newtonian fluid under a simple shear flow and a uniform magnetic field by direct numerical simulation. Using the COMSOL software, we applied the finite element method, based on [...] Read more.
We numerically investigate the dynamics of a pair of circular Janus microparticles immersed in a Newtonian fluid under a simple shear flow and a uniform magnetic field by direct numerical simulation. Using the COMSOL software, we applied the finite element method, based on an arbitrary Lagrangian-Eulerian approach, and analyzed the dynamics of two anisotropic particles (i.e., one-half is paramagnetic, and the other is non-magnetic) due to the center-to-center distance, magnetic field strength, initial particle orientation, and configuration. This article considers two configurations: the LR-configuration (magnetic material is on the left side of the first particle and on the right side of the second particle) and the RL-configuration (magnetic material is on the right side of the first particle and on the left side of the second particle). For both configurations, a critical orientation determines if the particles either attract (below the critical) or repel (above the critical) under a uniform magnetic field. How well the particles form a chain depends on the comparison between the viscous and magnetic forces. For long particle distances, the viscous force separates the particles, and the magnetic force causes them to repel as the particle orientation increases above the configuration’s critical value. As the initial distance decreases, a chain formation is possible at a steady orientation, but is more feasible for the RL-configuration than the LR-configuration under the same circumstances. Full article
(This article belongs to the Special Issue Structure, Thermodynamics and Applications of Ferrofluids)
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