Materials

FRP bars and steel strands are widely used in civil engineering. In this study, three different types of high-strength reinforcement materials, carbon fiber reinforced polymer (CFRP) bar, glass fiber reinforced polymer (GFRP) bar, and steel strand, were investigated for their interfacial bond performance with concrete. A total of 90 sets of specimens were conducted to analyze the effects of various parameters such as the diameter of reinforcement, bond length, the grade of concrete and stirrup on the bond strength and residual bond strength. The results show that CFRP bars possess a higher bond strength retention rate than steel bars in the residual section. in addition, with the increase in bond length and diameter of the CFRP bar, the residual bond strength decreases, and the bond strength retention rate decreases. Furthermore, the bond strength retention rate of GFRP bars was found to be higher than that of CFRP bars. With the increase in grade of concrete, the bond strength and residual bond strength between GFRP bars and concrete increases, but the bond strength retention rate decreases. With an increase in bond length and diameter of the GFRP bar, the bond strength starts to decrease. Further, stirrup can also increase the bond strength and reduce the slip at the free end of GFRP bars. Moreover, the bond strength retention rate of the steel strand was found to be lower than CFRP and GFRP bar. Full article

Large amounts of coal combustion products (as solid products of thermal power plants) with different chemical and physical properties cause serious environmental problems. Even though coal fly ash is a coal combustion product, it has a wide range of applications (e.g., in construction, metallurgy, chemical production, reclamation etc.). One of its potential uses is in zeolitization to obtain a higher added value of the product. The aim of this paper is to produce a material with sufficient textural properties used, for example, for environmental purposes (an adsorbent) and/or storage material. In practice, the coal fly ash (No. 1 and No. 2) from Czech power plants was firstly characterized in detail (X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), particle size measurement, and textural analysis), and then it was hydrothermally treated to synthetize zeolites. Different concentrations of NaOH, LiCl, Al₂O₃, and aqueous glass; different temperature effects (90–120 °C); and different process lengths (6–48 h) were studied. Furthermore, most of the experiments were supplemented with a crystallization phase that was run for 16 h at 50 °C. After qualitative product analysis (SEM-EDX, XRD, and textural analytics), quantitative XRD evaluation with an internal standard was used for zeolitization process evaluation. Sodalite (SOD), phillipsite (PHI), chabazite (CHA), faujasite-Na (FAU-Na), and faujasite-Ca (FAU-Ca) were obtained as the zeolite phases. The content of these zeolite phases ranged from 2.09 to 43.79%. The best conditions for the zeolite phase formation were as follows: 4 M NaOH, 4 mL 10% LiCl, liquid/solid ratio of 30:1, silica/alumina ratio change from 2:1 to 1:1, temperature of 120 °C, process time of 24 h, and a crystallization phase for 16 h at 50 °C. Full article

The construction of sponge city is a major green innovation to implement the concept of sustainable development. In this study, the road performance of permeable asphalt concrete (PAC), which displays pronounced water permeability and noise reduction that are favorable for sponge cities, has been improved with a two-fold modification using styrene–butadiene–styrene (SBS) and crumb rubber (CR). Four percent SBS and three different ratios (10%, 15%, and 20%) of CR have been used to modify the virgin asphalt binder. The Marshall design has been followed to produce PAC samples. To evaluate the asphalt binder performance, multiple-stress creep-recovery (MSCR) test, linear amplitude sweep (LAS) test, and engineering property test programs including softening point test, penetration test, and rotational viscosity test have been conducted. Freeze–thaw splitting test, Hamburg wheel-tracking test, resilient modulus test, and permeability coefficient test have been performed to evaluate the asphalt mixture performance. The test results show that the addition of SBS and CR reduces the permeability coefficient, but significantly improves the high temperature performance, fatigue performance, and rutting resistance as well as the resilient modulus. However, the optimum rubber content should not exceed 15%. Meanwhile, after adding CR and SBS modifier, the indirect tensile strength (ITS) and tensile strength ratio (TSR) increase. It indicates that the moisture stability and crack resistance have been improved by the composite modification effect. Full article

A prestressed concrete (PSC) structure is subject to prestress losses in the long and short terms, and the structure ages over time. The structure is susceptible to corrosion from exposure to environmental factors such as moisture, chloride, and carbonation, thus causing prestress loss. Therefore, strengthening the structure is needed to address this problem. Here, the near surface mounted (NSM) method and the external prestressing (EP) method were selected because they are capable of applying additional prestressing. Further, we used fiber-reinforced plastics or polymers, or carbon fiber-reinforced plastics or polymers because of their high tensile strength and noncorrosive properties. For EP tests, prestressed strands were used. Accordingly, this study performs four-point flexural tests and evaluations for 12 types of specimens fabricated with different PSC methods. All specimens fabricated with the NSM (prestressing, no prestressing) and EP methods achieved stiffness that was 50–60% higher than that of the control PSC specimen. It was observed that the EP method in conjunction with prestressing yielded the best strengthening effect. It is expected that the results of this study will be applied to real structures for strengthening them and improving their performances. Full article

In this research, polyester-based polymers/Fe₃O₄ nanocomposite foams were prepared in order to study their performance; namely shape recovery speed and actuation load. A foamed structure was obtained through a solid-state foaming process, which was studied and optimized in previous research. The optimum foaming parameters were applied in an attempt to achieve the highest foaming ratio possible. A Taguchi Map was then designed to determine the number of experiments to be conducted. The experimental results showed that the maximum actuation load obtained was 3.35 N, while optimal (fastest) recovery speed was 6.36 mm/min. Furthermore, temperature had no impact on the actuation load as long as a temperature above the T_g was applied. Moreover, the addition of nanoparticles reduced shape recovery speed due to discontinuity within the polymer matrix. Full article

In this study, we report a novel high-throughput and instant-mixing droplet microfluidic system that can prepare uniformly mixed monodisperse droplets at a flow rate of mL/min designed for rapid mixing between multiple solutions and the preparation of micro-/nanoparticles. The system is composed of a magneton micromixer and a T-junction microfluidic device. The magneton micromixer rapidly mixes multiple solutions uniformly through the rotation of the magneton, and the mixed solution is sheared into monodisperse droplets by the silicone oil in the T-junction microfluidic device. The optimal conditions of the preparation of monodisperse droplets for the system have been found and factors affecting droplet size are analyzed for correlation; for example, the structure of the T-junction microfluidic device, the rotation speed of the magneton, etc. At the same time, through the uniformity of the color of the mixed solution, the mixing performance of the system is quantitatively evaluated. Compared with mainstream micromixers on the market, the system has the best mixing performance. Finally, we used the system to simulate the internal gelation broth preparation of zirconium broth and uranium broth. The results show that the system is expected to realize the preparation of ceramic microspheres at room temperature without cooling by the internal gelation process. Full article

The study performs a comparative analysis of the wear of tools made of two wear-resistant materials: steel Hardox 600 and NC11LV, used in the process of forming a band for roofing tiles. The analyses were to allow the assessment of the possibility of replacing the standard material for tools in this process with a much less expensive tool steel for cold work after heat treatment (with a large number of carbides), as an alternative material dedicated to tools resistant to intense abrasive wear. The performed investigations included a macroscopic and geometrical analysis with the use of 3D scanning, microstructural analyses conducted by means of a light microscope, as well as an analysis of the topography of the working areas of the tools with the use of SEM, and microhardness tests. The obtained results demonstrate that the tools made of both materials were characterized with a similar level of wear, which, in the most critical area, reached over 4 mm, while the tools made of steel NC11LV worked over a much longer period of time without regeneration, equaling 912 h, and an insert made of steel Hardox 600 operated for 384 h. A higher tool life in the case of NC11LV steel may be the result of higher hardness and the presence of hard carbides. Full article

Short fiber reinforced polymers are widely used in the construction of electronic housings, where they are often exposed to harsh environmental conditions. The main purpose of this work is the in-depth study and characterization of the water uptake behavior of PBT-GF30 (polybutylene terephthalate with 30% of short glass fiber)as well as its consequent effect on the mechanical properties of the material. Further analysis was conducted to determine at which temperature range PBT-GF30 starts experiencing chemical changes. The influence of testing procedures and conditions on the evaluation of these effects was analyzed, also drawing comparisons with previous studies. The water absorption behavior was studied through gravimetric tests at 35, 70, and 130 ${}^{\circ }$C. Fiber-free PBT was also studied at 35 ${}^{\circ }$C for comparison purposes. The effect of water and temperature on the mechanical properties was analyzed through bulk tensile tests. The material was tested for the three temperatures in the as-supplied state (without drying or aging). Afterwards, PBT-GF30 was tested at room temperature following water immersion at the three temperatures. Chemical changes in the material were also analyzed through Fourier-transform infrared spectroscopy (FTIR). It was concluded that the water diffusion behavior is Fickian and that PBT absorbs more water than PBT-GF30 but at a slightly higher rate. However, temperature was found to have a more significant influence on the rate of water diffusion of PBT-GF30 than fiber content did. Temperature has a significant influence on the mechanical properties of the material. Humidity contributes to a slight drop in stiffness and strength, not showing a clear dependence on water uptake. This decrease in mechanical properties occurs due to the relaxation of the polymeric chain promoted by water ingress. Between 80 and 85 ${}^{\circ }$C, after water immersion, the FTIR profile of the material changes, which suggests chemical changes in the PBT. The water absorption was simulated through heat transfer analogy with good results. From the developed numerical simulation, the minimum plate size to maintain the water ingress unidirectional was 30 mm, which was validated experimentally. Full article

In this study, the Generalized Softened Variable Angle Truss-Model (GSVATM) is used to predict the response of reinforced concrete (RC) beams under torsion at the early loading stages, namely the transition from the uncracked to the cracked stage. Being a 3-dimensional smeared truss model, the GSVATM must incorporate smeared constitutive laws for the materials, namely for the tensile concrete. Different smeared constitutive laws for tensile concrete can be found in the literature, which could lead to different predictions for the torsional response of RC beams at the earlier stages. Hence, the GSVATM is used to check several smeared constitutive laws for tensile concrete proposed in previous studies. The studied parameters are the cracking torque and the corresponding twist. The predictions of these parameters from the GSVATM are compared with the experimental results from several reported tests on RC beams under torsion. From the obtained results and the performed comparative analyses, one of the checked smeared constitutive laws for tensile concrete was found to lead to good predictions for the cracking torque of the RC beams regardless of the cross-section type (plain or hollow). Such a result could be useful to help with choosing the best constitutive laws to be incorporated into the smeared truss models to predict the response of RC beams under torsion. Full article

The article presents the results of studies on the influence of Mg on the formation of the periodic layered structure of the Zn-AlMg coatings. These coatings were produced by the double batch hot dip method in a Zn bath and then in a Zn-Al(Mg) bath with a content of 15, 23, 31 wt.% Al and 3, 6 wt.% Mg. The microstructure of the coatings (OM, SEM) was revealed and the phase composition (XRD) obtained in two-component Zn-Al baths and Zn-AlMg baths were determined. The periodic layered structure was found to consist of alternating FeAl₃ phase layers and a bath alloy (Zn + Al + Mg). Moreover, it was observed that the addition of 3 wt.% Mg reduces the thickness of the coating in baths containing 23 and 31 wt.% Al. However, the addition of 6 wt.% Mg causes complete disappearance of periodic layered structure in a bath with 23 wt.% Al. In a bath with a content of 31 wt.% Al the addition of 6 wt.% Mg creates a compact layer consisting of the FeAl₃ phase containing the precipitation of the MgZn₂ phase and Fe₂Al₅ phase. Such a structure of the coating transition layer limits the growth of the periodic layered structure in the coating. Full article

Calcium titanate-CaTiO₃ (perovskite) has been used in various industrial applications due to its dopant/doping mechanisms. Manipulation of defective grain boundaries in the structure of perovskite is essential to maximize mechanical properties and stability; therefore, the structure of perovskite has attracted attention, because without fully understanding the perovskite structure and diffracted planes, dopant/doping mechanisms cannot be understood. In this study, the areas and locations of atoms and diffracted planes were designed and investigated. In this research, the relationship between Young’s modulus and planar density of unit cell, super cells (2 × 2 × 2) and symmetry cells of nano CaTiO₃ is investigated. Elastic constant, elastic compliance and Young’s modulus value were recorded with the ultrasonic pulse-echo technique. The results were C₁₁ = 330.89 GPa, C₁₂ = 93.03 GPa, C₄₄ = 94.91 GPa and E = 153.87 GPa respectively. Young’s modulus values of CaTiO₃ extracted by planar density were calculated 162.62 GPa, 151.71 GPa and 152.21 GPa for unit cell, super cells (2 × 2 × 2) and symmetry cells, respectively. Young’s modulus value extracted by planar density of symmetry cells was in good agreement with Young’s modulus value measured via ultrasonic pulse-echo. Full article

An improved hydraulic servo structure testing machine has been used to conduct biaxial dynamic compression tests on eight types of engineered cementitious composites (ECC) with lateral pressure levels of 0, 0.125, 0.25, 0.5, 0.7, 0.8, 0.9, 1.0 (the ratio of the compressive strength applied laterally to the static compressive strength of the specimen), and three strain rates of 10⁻⁴, 10⁻³ and 10⁻² s⁻¹. The failure mode, peak stress, peak strain, deformation modulus, stress-strain curve, and compressive toughness index of ECC under biaxial dynamic compressive stress state are obtained. The test results show that the lateral pressure affects the direction of ECC cracking, while the strain rate has little effect on the failure morphology of ECC. The growth of lateral pressure level and strain rate upgrades the limit failure strength and peak strain of ECC, and the small improvement is achieved in elastic modulus. A two-stage ECC biaxial failure strength standard was established, and the influence of the lateral pressure level and peak strain was quantitatively evaluated through the fitting curve of the peak stress, peak strain, and deformation modulus of ECC under various strain rates and lateral pressure levels. ECC’s compressive stress-strain curve can be divided into four stages, and a normalized biaxial dynamic ECC constitutive relationship is established. The toughness index of ECC can be increased with the increase of lateral pressure level, while the increase of strain rate can reduce the toughness index of ECC. Under the effect of biaxial dynamic load, the ultimate strength of ECC is increased higher than that of plain concrete. Full article

We present a unique dual laser beam processing approach based on excited state absorption by structuring 200 nm thin zinc oxide films sputtered on fused silica substrates. The combination of two pulsed nanosecond-laser beams with different photon energies—one below and one above the zinc oxide band gap energy—allows for a precise, efficient, and homogeneous ablation of the films without substrate damage. Based on structuring experiments in dependence on laser wavelength, pulse fluence, and pulse delay of both laser beams, a detailed concept of energy transfer and excitation processes during irradiation was developed. It provides a comprehensive understanding of the thermal and electronic processes during ablation. To quantify the efficiency improvements of the dual-beam process compared to single-beam ablation, a simple efficiency model was developed. Full article

This research investigated the application of epoxy resin polymer as a self-healing strategy for improving the mechanical and durability properties of cement-based mortar. The epoxy resin was added to the concrete mix at various levels (5, 10, 15, and 20% of cement weight), and the effectiveness of healing was evaluated by microstructural analysis, compressive strength, and non-destructive (ultrasonic pulse velocity) tests. Dry and wet-dry conditions were considered for curing, and for generating artificial cracks, specimens at different curing ages (1 and 6 months) were subjected to compressive testing (50 and 80% of specimen’s ultimate compressive strength). The results indicated that the mechanical properties in the specimen prepared by 10% epoxy resin and cured under wet-dry conditions was higher compared to other specimens. The degree of damage and healing efficiency index of this particular mix design were significantly affected by the healing duration and cracking age. An optimized artificial neural network (ANN) combined with a firefly algorithm was developed to estimate these indexes over the self-healing process. Overall, it was concluded that the epoxy resin polymer has high potential as a mechanical properties self-healing agent in cement-based mortar. Full article

Static dissolution experiments were carried out with the reference International Simple Glass under hyperalkaline pH at 70 °C and very high SA/V ratio. Three aspects of glass dissolution behavior were investigated, (1) the rate drop regime and the residual rate (stage II), (2) the formation of secondary phases including thermodynamic aspects, and (3) the microstructure of the interface of altered glass and secondary phases. A very low residual rate of 6 × 10⁻⁶ g/m²d was determined based on boron release, which was several orders of magnitude lower than the initial rate established between the start of the experiments and the first sampling on day 59. The presence of a porous layer with a thickness varying between 80 nm and 250 nm and a pore size between 10 nm and 50 nm was observed. CSH phases with a low Ca/Si ratio of 0.3–0.4 and zeolites were also visible at the surface of the altered glass grains, but no glass alteration resumption occurred, probably due to an important pH decrease already at day 59. Thermodynamic calculations assuming congruent glass dissolution and precipitation of the dissolved aqueous species confirmed the precipitation of CSH phases and zeolites. Full article

An evaluation method is proposed for determining the full fatigue life of aluminum alloy cruciform joint, including the crack initiation and propagation with welding residual stress. The results of simulations have shown that the boundary between the initiation and propagation stage is not constant, but a variable value. The residual stress leads to a significant reduction in both stages, which is more severe on initiation. With considering residual stress, the ratio of crack initiation to total life is below 7%. The effect of residual stress varies with external loading; when external load is lower, the residual stress has a greater effect. Full article

To avoid disadvantages caused by rotational degrees of freedom in the original Discontinuous Deformation Analysis (DDA), a new block displacement mode is defined within a time step, where displacements of all the block vertices are taken as the degrees of freedom. An individual virtual element space V₁(Ω) is defined for a block to illustrate displacement of the block using the Virtual Element Method (VEM). Based on VEM theory, the total potential energy of the block system in DDA is formulated and minimized to obtain the global equilibrium equations. At the end of a time step, the vertex coordinates are updated by adding their incremental displacement to their previous coordinates. In the new method, no explicit expression for the displacement u is required, and all numerical integrations can be easily computed. Four numerical examples originally designed by Shi are analyzed, verifying the effectiveness and precision of the proposed method. Full article

The quality and characteristics of a powder in powder bed fusion processes play a vital role in the quality of additively manufactured components. Its characteristics may influence the process in various ways. This paper presents an investigation highlighting the influence of powder deterioration on the stability of a molten pool in a laser beam powder bed fusion (LB-PBF, selective laser melting) process and its consequences to the physical properties of the alloy, porosity of 3D-printed components and their mechanical properties. The intention in this was to understand powder reuse as a factor playing a role in the formation of porosity in 3D-printed components. Ti6Al4V (15 μm–45 μm) was used as a base material in the form of a fresh powder and a degraded one (reused 12 times). Alloy degradation is described by possible changes in the shape of particles, particle size distribution, chemical composition, surface tension, density and viscosity of the melt. An approach of 3D printing singular lines was applied in order to study the behavior of a molten pool at varying powder bed depths. Single-track cross-sections (STCSs) were described with shape parameters and compared. Furthermore, the influence of the molten pool stability on the final density and mechanical properties of a material was discussed. Electromagnetic levitation (EML) was used to measure surface tension and the density of the melt using pieces of printed samples. It was found that the powder degradation influences the mechanical properties of a printed material by destabilizing the pool of molten metal during printing operation by facilitating the axial flow on the melt along the melt track axis. Additionally, the observed axial flow was found to facilitate a localized lack of fusion between concurrent layers. It was also found that the surface tension and density of the melt are only impacted marginally or not at all by increased oxygen content, yet a difference in the temperature dependence of the surface tension was observed. Full article

Reducing greenhouse gas emissions and dependence on fossil fuels is the cornerstone of all European climate and energy strategies. Consequently, renewable energy sources are becoming more competitive with fossil fuels. The largest source of bioenergy in the European Union is biomass-fired power plants. Therefore, the European coal phase-out strategy led to an increased use of wood biomass as a sustainable fuel, generating large amounts of wood biomass ash (WBA). In the research studies reported so far, WBA has been mainly used in cementitious composites. However, given the similarities between the chemical composition of WBA and hydraulic lime (HL), this research focused on its potential classification as a building lime. Overall, three different sources of fly WBA were considered for the preparation of binders as mixtures of WBA and coal fly ash (CFA) in different ratios. The contribution of each binder mixture on the paste and mortar properties was analyzed based on the chemical composition, setting time, volume stability, and contribution to the mortar strength (compressive and flexural). In general, it can be concluded that the studied binders can meet the criteria of EN 459-1. However, special attention should be paid to the volume deformations and the setting time. Full article