materials-logo

Journal Browser

Journal Browser

Advances in Energy Storage and Conversion Composites

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Energy Materials".

Deadline for manuscript submissions: closed (15 December 2021) | Viewed by 1870

Special Issue Editors


E-Mail Website
Guest Editor
State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Interests: energy storage and transform; microwave absorption

E-Mail Website
Guest Editor Assistant
State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Interests: microwave absorption material

Special Issue Information

Dear Colleagues,

The last two decades have witnessed a significant improvement in energy storage devices, enabling the utilization of various types of energy. Today, the storage and conversion of energy regarding portable electronic devices need improvements in components and microstructures of materials. The development of nanotechnology with the latest characterization facilities has led to the revolution of these materials. The emergence of electrochemical energy storage and conversion is regarded as one of the most promising methods of storing and transforming energy, which needs systematic strategies to reach maximum efficiencies.

This Special Issue will compile recent developments in the field of energy storage and conversion devices. The articles presented in this Special Issue will cover various topics including, but not limited to, the optimization of the preparations, and the functionalization and the characterization of various electrochemical devices, including batteries, electrolyte, supercapacitors, fuel cells, renewable energy, and portable electronic devices. Topics are open to carbon-based materials, MOFs, MXene, and other kinds of materials for the development of applications.

Prof. Hua Li
Dr. Wang Kaifeng
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • batteries
  • supercapacitors
  • electrolyte
  • fuel cells
  • renewable energy
  • portable electronic devices

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Research

20 pages, 5548 KiB  
Article
Structurally Dependent Electrochemical Properties of Ultrafine Superparamagnetic ‘Core/Shell’ γ-Fe2O3/Defective α-Fe2O3 Composites in Hybrid Supercapacitors
by Oleg Bazaluk, Andrii Hrubiak, Volodymyr Moklyak, Maria Moklyak, Lina Kieush, Bogdan Rachiy, Ivan Gasyuk, Yurii Yavorskyi, Andrii Koveria, Vasyl Lozynskyi and Serhii Fedorov
Materials 2021, 14(22), 6977; https://0-doi-org.brum.beds.ac.uk/10.3390/ma14226977 - 18 Nov 2021
Cited by 7 | Viewed by 1574
Abstract
The paper presents a method for obtaining electrochemically active ultrafine composites of iron oxides, superparamagnetic ‘core/shell’ γ-Fe2O3/defective α-Fe2O3, which involved modifying sol-gel citrate synthesis, hydrothermal treatment of the formed sol, and subsequent annealing of materials [...] Read more.
The paper presents a method for obtaining electrochemically active ultrafine composites of iron oxides, superparamagnetic ‘core/shell’ γ-Fe2O3/defective α-Fe2O3, which involved modifying sol-gel citrate synthesis, hydrothermal treatment of the formed sol, and subsequent annealing of materials in the air. The synthesized materials’ phase composition, magnetic microstructure, and structural, morphological characteristics have been determined via X-ray analysis, Mossbauer spectroscopy, scanning electron microscopy (SEM), and adsorption porometry. The mechanisms of phase stability were analyzed, and the model was suggested as FeOOH → γ-Fe2O3 → α-Fe2O3. It was found that the presence of chelating agents in hydrothermal synthesis encapsulated the nucleus of the new phase in the reactor and interfered with the direct processes of recrystallization of the structure with the subsequent formation of the α-Fe2O3 crystalline phase. Additionally, the conductive properties of the synthesized materials were determined by impedance spectroscopy. The electrochemical activity of the synthesized materials was evaluated by the method of cyclic voltammetry using a three-electrode cell in a 3.5 M aqueous solution of KOH. For the ultrafine superparamagnetic ‘core/shell’ γ-Fe2O3/defective α-Fe2O composite with defective hematite structure and the presence of ultra-dispersed maghemite with particles in the superparamagnetic state was fixed increased electrochemical activity, and specific discharge capacity of the material is 177 F/g with a Coulomb efficiency of 85%. The prototypes of hybrid supercapacitor with work electrodes based on ultrafine composites superparamagnetic ‘core/shell’ γ-Fe2O3/defective α-Fe2O3 have a specific discharge capacity of 124 F/g with a Coulomb efficiency of 93% for current 10 mA. Full article
(This article belongs to the Special Issue Advances in Energy Storage and Conversion Composites)
Show Figures

Figure 1

Back to TopTop