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Industrial Solid Wastes for Construction and Building Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Construction and Building Materials".

Deadline for manuscript submissions: closed (20 July 2023) | Viewed by 41182

Special Issue Editors

Prof. Dr. Xiaoming Liu

E-Mail Website
Guest Editor
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Interests: solid wastes; reuse; recycle; ecological building material
Dr. Zengqi Zhang

E-Mail Website
Guest Editor
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Interests: solid waste; recycling; sustainable building materials

Special Issue Information

Dear Colleagues,

The Special Issue "Industrial Solid Wastes for Construction and Building Materials" covers the fields of environmental and materials science and engineering. It pays attention to the resource utilization of industrial solid waste in construction and building materials, reduces its impact on the environment, and helps society become more sustainable. It includes the preparation of building materials with industrial solid waste as the main raw materials and its green production processes, which are used in the fields of construction, environmental protection, energy storage, etc.

Topics of interest include (but are not limited to):

  • Cement, concrete, ceramics, bituminous materials, wall materials, road materials, bricks, mortars, additives, recycled materials, composite materials, and new building materials;
  • Porous materials (light weight, sound insulation, and heat insulation);
  • Energy storage materials;
  • Application of intellectualization in solid waste-based building materials;
  • New ways and application cases of industrial solid waste utilization in building materials;
  • Application of advanced methods and techniques in solid waste based building materials;
  • Life cycle assessment of building materials.

Prof. Dr. Xiaoming Liu
Dr. Zengqi Zhang
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • solid waste
  • resource utilization
  • building materials
  • porous materials
  • energy storage materials
  • intellectualization
  • life cycle assessment

Published Papers (24 papers)

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25 pages, 15802 KiB  
Article
Investigating on the Pavement Performance of Multi-Source Solid Wastes by Cement and Fly Ash
by Long Shan, Hongbo Li, Jing Zhao, Xuanshuo Zhang, Xinrui Kang, Xing Gao and Zhiyao Zhou
Materials 2023, 16(19), 6556; https://doi.org/10.3390/ma16196556 - 04 Oct 2023
Viewed by 767
Abstract
In order to advance the utilization rate of multi-source solid wastes in the Ningxia region of China, 16 groups of pavement base mixtures were designed with cement and fly ash (FA) as binders, steel slag (SS), silicon manganese slag (SMS), and recycled crushed [...] Read more.
In order to advance the utilization rate of multi-source solid wastes in the Ningxia region of China, 16 groups of pavement base mixtures were designed with cement and fly ash (FA) as binders, steel slag (SS), silicon manganese slag (SMS), and recycled crushed stone (RCS) as composite aggregates. The evolution laws of mechanical and frost resistance properties of the mixture were investigated by unconfined compressive strength (UCS), indirect tensile strength (ITS), freeze–thaw (FT), and ultrasonic detection tests. Then, the strength formation mechanisms were revealed by microscopic characterization technology. The mathematical models between UCS-ITS, UCS-ultrasonic amplitude, FT cycles-UCS damage, and frost resistance coefficient-relative dynamic elastic modulus Er were established. The results show that cement content and curing age exhibited a positive effect on the mechanical strength and frost resistance of the mixture. When the replacement rate of SS was 60%, the mechanical strength and frost resistance were preferable. The R2 of the strength relationship models constructed was greater than 0.9, indicating high fitting accuracy. With the extension of the curing age, the cementitious products such as C-S-H (hydrated calcium silicate) and AFt (ettringite) developed entirely, and they were interlocked and cemented with each other, resulting in the micro-morphology developed from the three-dimensional network structure to the dense system. The macroscopic behavior incarnated that the mechanical strength and frost resistance of the mixture were significantly enhanced. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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14 pages, 5703 KiB  
Article
Comparative Study of Iron-Tailings-Based Cementitious Mortars with Incorporated Graphite Ore and Graphite Tailings: Strength Properties and Microstructure
by Jiale Zhang, Qi Wei, Na Zhang, Shuai Zhang and Yihe Zhang
Materials 2023, 16(10), 3743; https://0-doi-org.brum.beds.ac.uk/10.3390/ma16103743 - 15 May 2023
Cited by 1 | Viewed by 1087
Abstract
Graphite ore and graphite tailings were blended into iron-tailings-based cementitious mortars, and their mechanical properties and microstructure were experimentally investigated. The flexural and compressive strengths of the resulting material were tested to compare the effects of graphite ore and graphite tailings as supplementary [...] Read more.
Graphite ore and graphite tailings were blended into iron-tailings-based cementitious mortars, and their mechanical properties and microstructure were experimentally investigated. The flexural and compressive strengths of the resulting material were tested to compare the effects of graphite ore and graphite tailings as supplementary cementitious materials and fine aggregates on the mechanical properties of iron-tailings-based cementitious mortars. Additionally, their microstructure and hydration products were mainly analyzed using scanning electronic microscope and X-ray powder diffraction techniques. The experimental results showed that the mechanical properties of the mortar material incorporating graphite ore were reduced due to the lubricating properties of graphite ore. As a result, the unhydrated particles and aggregates were not tightly bound to the gel phase, making the direct application of graphite ore in construction materials unfeasible. In the iron-tailings-based cementitious mortars prepared in this work, the optimal incorporation rate of graphite ore as a supplementary cementitious material was 4 wt%. The compressive strength of the optimal mortar test block after 28 days of hydration was 23.21 MPa, and the flexural strength was 7.76 MPa. The mechanical properties of the mortar block were found to be optimal with a graphite-tailings content of 40 wt% and an iron-tailings content of 10 wt%, resulting in a 28-day compressive strength of 48.8 MPa and a flexural strength of 11.7 MPa. By observing the microstructure and XRD pattern of the 28-day hydrated mortar block, it was determined that the hydration products of the mortar with graphite tailings as an aggregate included ettringite, Ca(OH)2, and C-A-S-H gel. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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24 pages, 12784 KiB  
Article
Analysis of Asphalt Mixtures Modified with Steel Slag Surface Texture Using 3D Scanning Technology
by Shuai Zhang, Rongxin Guo, Feng Yan, Ruzhu Dong, Chuiyuan Kong and Junjie Li
Materials 2023, 16(8), 3256; https://0-doi-org.brum.beds.ac.uk/10.3390/ma16083256 - 20 Apr 2023
Cited by 2 | Viewed by 1039
Abstract
This paper investigates the use of steel slag in the place of basalt coarse aggregate in Stone Mastic Asphalt-13 (SMA-13) gradings in the early forming of an experimental pavement and evaluates the test performance of the mixes, combined with 3D scanning techniques to [...] Read more.
This paper investigates the use of steel slag in the place of basalt coarse aggregate in Stone Mastic Asphalt-13 (SMA-13) gradings in the early forming of an experimental pavement and evaluates the test performance of the mixes, combined with 3D scanning techniques to analyse the initial textural structure of the pavement. Laboratory tests were carried out to design the gradation of the two asphalt mixtures and to assess the strength, chipping and cracking resistance of the asphalt mixtures using water immersion Marshall tests, freeze–thaw splitting tests, rutting tests and for comparison with laboratory tests, while surface texture collection and analysis of the height parameters (i.e., Sp, Sv, Sz, Sq, Ssk) and morphological parameters (i.e., Spc) of the pavement were performed to assess the skid resistance of the two asphalt mixtures. Firstly, the results show that a substitution of steel slag for basalt in pavements is a good alternative for efficient resource utilization. Secondly, when steel slag was used in place of basalt coarse aggregate, the water immersion Marshall residual stability improved by approximately 28.8% and the dynamic stability by approximately 15.8%; the friction values decayed at a significantly lower rate, and the MTD did not change significantly. Thirdly, in the early stages of pavement formation, Sp, Sv, Sz, Sq and Spc showed a good linear relationship with BPN values, and these texture parameters can be used as parameters to describe steel slag asphalt pavements. Finally, this study also found that the standard deviation of peak height was higher for steel slag–asphalt mixes than for basalt–asphalt mixes, with little difference in texture depth, while the former formed more peak tips than the latter. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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9 pages, 1607 KiB  
Article
Study on Crystal Growth of Tobermorite Synthesized by Calcium Silicate Slag and Silica Fume
by Zhijie Yang, Chengyang Fang, Yang Jiao, De Zhang, Dong Kang and Kaiyue Wang
Materials 2023, 16(3), 1288; https://0-doi-org.brum.beds.ac.uk/10.3390/ma16031288 - 02 Feb 2023
Cited by 3 | Viewed by 1486
Abstract
In order to high-value utilize the secondary solid waste calcium silicate slag (CSS) generated in the process of the extraction of alumina from fly ash, in this paper, tobermorite was synthesized using CSS and silica fume (SF) at different hydrothermal synthesis times. The [...] Read more.
In order to high-value utilize the secondary solid waste calcium silicate slag (CSS) generated in the process of the extraction of alumina from fly ash, in this paper, tobermorite was synthesized using CSS and silica fume (SF) at different hydrothermal synthesis times. The hydrothermal synthesis was evaluated by means of XRD, SEM, EDS, and micropore analysis, and the results discussed. The results indicate that β-dicalcium silicate, the primary phase in the CSS, partially hydrates at the beginning of hydrothermal synthesis conditions to form mesh-like crystal C-S-H (calcium-rich) and calcium hydroxide. It then reacts with SF to form yarn-like crystal C-S-H (silicon-rich) and then furtherly grows into large flake-like crystal C-S-H (silicon-rich) at 3 h. When the synthesis time is 4 h, β-dicalcium silicate completely hydrates, and crystal C-S-H (calcium-rich) and calcium hydroxide further reacts with large flake-like crystal C-S-H (silicon-rich) to generate medium flake-like tobermorite. With the increase in time, the crystal of hydrothermal synthesis grows in the order of medium flake-like tobermorite, small flake-like tobermorite, strip flake-like tobermorite, fibrous-like tobermorite, and spindle-like tobermorite, and the APV, APD, and SSA show a trend of decreasing first, then increasing, and then decreasing. Meanwhile, strip flake-like tobermorite with a higher average pore volume (APV), average pore diameter (APD), and specific surface area (SSA) can be synthesized at 6 h. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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17 pages, 4079 KiB  
Article
Graphene-Iron Ore Tailings–Based Cementitious Composites with High Early Flexural Strength
by Huiteng Xiao, Na Zhang, Gen Li, Youpeng Zhang, Yidi Wang, Yu Wang and Yihe Zhang
Materials 2023, 16(1), 327; https://0-doi-org.brum.beds.ac.uk/10.3390/ma16010327 - 29 Dec 2022
Cited by 3 | Viewed by 1408
Abstract
Graphene is a two-dimensional nanomaterial with excellent mechanical, electrical and thermal properties. The application of graphene in cement-based materials has good prospects. However, the mechanical properties of cement-based materials are difficult to be significantly enhanced by ordinary graphene nanoplates. In this paper, nitrogen-doped [...] Read more.
Graphene is a two-dimensional nanomaterial with excellent mechanical, electrical and thermal properties. The application of graphene in cement-based materials has good prospects. However, the mechanical properties of cement-based materials are difficult to be significantly enhanced by ordinary graphene nanoplates. In this paper, nitrogen-doped graphene is first reported as an additive with dosages of 0.01, 0.02, 0.03, 0.04 and 0.05 wt.%, respectively, to prepare iron ore tailings–based cementitious composites. The iron ore tailings–based cementitious composite with 0.02 wt.% graphene shows an extremely high flexural strength of 15.05 MPa at 3 days, which is 134.4% higher than that of the iron ore tailings–based cementitious composite without graphene. The effects of graphene content and curing age on the flexural strength and microstructure of iron ore tailings–based cementitious composites were studied. In particular, the scanning electron microscope was adopted to observe the micromorphology of the composites. It is helpful to understand the graphene reinforcement mechanism for the high early flexural strength of iron ore tailings–based cementitious composites. By altering the morphology of iron ore tailings–based cementitious composites, graphene plays two roles in the composites. One role is to connect C-(A)-S-H gels, ettringite and other hydrated crystals to construct a three-dimensional structure. The other is to attract iron ore tailings distributed on its platform to enhance its flexural strength properties. These findings provide favorable guidance for the performance enhancement and mechanism replenishment of graphene-reinforced cementitious composites. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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16 pages, 7713 KiB  
Article
Effect of Phosphorus Slag Admixture on the Properties and Hydration Mechanism of Circulating Fluidized Bed Fly Ash-Based Multi-Solid Waste Cementitious Material
by Wei Zhang, Chao Wei, Xiaoming Liu and Zengqi Zhang
Materials 2022, 15(19), 6774; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15196774 - 29 Sep 2022
Cited by 3 | Viewed by 1797
Abstract
This research aims to reveal the effect of phosphorus slag (PS) admixtures on the properties and hydration mechanism of circulating fluidized bed fly ash (CFA)-based multi-solid waste cementitious material (CWM). The results indicate that PS as an admixture is more helpful for improving [...] Read more.
This research aims to reveal the effect of phosphorus slag (PS) admixtures on the properties and hydration mechanism of circulating fluidized bed fly ash (CFA)-based multi-solid waste cementitious material (CWM). The results indicate that PS as an admixture is more helpful for improving the performance of CWM systems compared with blast furnace slag with a high specific surface area (HBFS) and gasification slag (GS). In this work, CWM2 is prepared with 30 wt.% CFA, 10 wt.% red mud (RM), 20 wt.% blast furnace slag (BFS), 10 wt.% PS, and 30 wt.% cement clinker (CC). The compressive strength and expansion value of CWM2 are the optimal (51.15 MPa and 0.70 mm) when the mass ratio of (Ca + Na)/(Si + Al) is 0.84, which can meet the requirements of 42.5 fly ash Portland cement. In addition, the polymerization degree of CWM2-28 days is the optimum (51.57%) because [PO4] and [SiO4] combine to improve its polymerization structure. The main hydration products are C-S-H gel, C/N-A-S-H gel, and ettringite in CWM, which are conducive to improve the compactness of the micromorphology. In addition, the consolidation of Na, As, Cd, and Hg is promoted in CWM2 by physical encapsulation and charge balance, which meet the drinking water requirements of the World Health Organization (WHO). Therefore, this work provides a new idea for the application of PS as an admixture in CFA-based multi-solid waste cementitious material. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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18 pages, 5925 KiB  
Article
Frost Resistance and Mechanism of Circulating Fluidized Bed Fly Ash-Blast Furnace Slag-Red Mud-Clinker Based Cementitious Materials
by Wei Zhang, Chao Wei, Xiaoming Liu and Zengqi Zhang
Materials 2022, 15(18), 6311; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15186311 - 12 Sep 2022
Cited by 1 | Viewed by 1296
Abstract
The motivation of this work is to enhance the long-term frost resistance of circulating fluidized bed fly ash (CFA)-based multisolid waste cementitious material (CSM). In this research, CSM2 is prepared by 30 wt.% CFA, 20 wt.% blast furnace slag (BFS), 10 wt.% red [...] Read more.
The motivation of this work is to enhance the long-term frost resistance of circulating fluidized bed fly ash (CFA)-based multisolid waste cementitious material (CSM). In this research, CSM2 is prepared by 30 wt.% CFA, 20 wt.% blast furnace slag (BFS), 10 wt.% red mud (RM), 10 wt.% phosphorus slag (PS), and 30 wt.% cement clinker (CC). The strength and mass of CSM are detected by a press and electronic balance. The hydration products, polymerization degree, thermogravimetric, micromorphology, pore structure, and harmful element leaching are detected by XRD, MAS NMR, TG-DTG, SEM-EDX, MIP, and ICP-MS. The major findings indicate that the strength loss, mass loss, and strength of CSM2 after 25 freeze–thaw cycles (CSM2-25) are 2.35%, 0.36%, and 49.95 MPa, respectively, which is superior to other CSMs and still meets the performance requirements of fly ash Portland cement 42.5#. The main hydration products are C-S-H gel, C/N-A-S-H gel, and ettringite during the freeze–thaw cycle. The polymerization degree and thermogravimetric loss of hydration products in CSM2-25 are 50.65% and 12.82 wt.%, respectively, which are higher than those of other CSMs under the synergy of CFA, BFS, RM, and PS. In addition, the microscopic results show that the interface between the paste and aggregate, micromorphology, and pore structure of CSM2-25 are the densest when the mass ratio of Ca/(Si + Al) is 0.81. These characteristics are beneficial to the improvement of long-term frost resistance in CSM2. Finally, the leaching results of harmful elements in CSM2 after 25 freeze–thaw cycles still meet the WHO standard of drinking water. Therefore, this work provides a reliable reference for the preparation of green cementitious materials with great frost resistance by using CFA, BFS, RM, and PS. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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17 pages, 4056 KiB  
Article
Influence of Mechanical Grinding on Particle Characteristics of Coal Gasification Slag
by Mengbo Zhu, Geng Xie, Lang Liu, Pan Yang, Huisheng Qu and Caixin Zhang
Materials 2022, 15(17), 6033; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15176033 - 01 Sep 2022
Cited by 12 | Viewed by 1712
Abstract
Based on the test results of laser particle size analyzer, specific surface area analyzer and infrared spectrometer, the grinding kinetics of coal gasification slag (CGS) was systematically described by using Divas–Aliavden grinding kinetics, Rosin–Rammler–Bennet (RRB) distribution model and particle size fractal theory. The [...] Read more.
Based on the test results of laser particle size analyzer, specific surface area analyzer and infrared spectrometer, the grinding kinetics of coal gasification slag (CGS) was systematically described by using Divas–Aliavden grinding kinetics, Rosin–Rammler–Bennet (RRB) distribution model and particle size fractal theory. The influence of grinding time and particle group of CGS on the strength activity index of mortar was studied by using the strength activity index of mortar and grey correlation analysis. The results show that the particles are gradually refined before mechanical grinding of CGS for 75 min. When the mechanical grinding time is greater than 75 min, the “agglomeration phenomenon” of fine CGS particles led to the decrease in various properties. Divas–Aliavden grinding kinetics, the RRB model and fractal dimension can characterize the change of CGS particle size in the grinding process quantitatively. The strength activity index of CGS at different curing ages is positively correlated with grinding time, and the influence on the later strength activity index is the most obvious. The relationship between CGS particle size distribution and strength activity index were probed using grey correlation analysis. The CGS particle groups with the particle size of 20~30 μm and 10~20 μm have the greatest impact on the early and late strength activity index, respectively. Therefore, the optimal grinding time of CGS as auxiliary cementing material is 75 min, considering factors, such as economy and performance, and the specific surface area (SSA) is 4.4874 m2·g−1. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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20 pages, 7264 KiB  
Article
Properties of Slurry Shield Tunnel Sand and Its Application in Large Flow Concrete
by Ba Hezhuoli Ke Zierkailedi, Libo Bian, Xiufang Wang, Xingbo Hu, Xuelei Liu and Zhi Zhang
Materials 2022, 15(15), 5131; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15155131 - 23 Jul 2022
Cited by 3 | Viewed by 1505
Abstract
The amount of Slurry shield tunnel slag (SSTS) from the Beijing East Sixth Ring Road renovation project is about 3 million m3, and it is mainly fine and silt sand. In order to realize its resource utilization, the properties of SSTS [...] Read more.
The amount of Slurry shield tunnel slag (SSTS) from the Beijing East Sixth Ring Road renovation project is about 3 million m3, and it is mainly fine and silt sand. In order to realize its resource utilization, the properties of SSTS and the performance of concrete with strength grades from C30-C60, which used the mixed sand compound with SSTS and Coarse Manufactured Sand (CMS) as a fine aggregate, were investigated. The results showed that SSTS’ fineness modulus is 1.2, its clay content is 17.0% but its composition is mainly Inert Silt (IS), and SSTS replaced with 40% of the mass of CMS can obtain a mixed sand with a fineness modulus of 2.7 and a clay content of 7.0%. The morphological and filling effects of SSTS and IS will improve the workability and durability properties of concrete with no adverse effects on the compressive strength. On the other hand, clay lumps in SSTS adversely affect the workability, early cracking properties, and freeze resistance of concrete, which can be alleviated by dewatering and crushing the clay lumps in SSTS. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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15 pages, 6867 KiB  
Article
Hydration and Compressive Strength of Activated Blast-Furnace Slag–Steel Slag with Na2CO3
by Yunfeng Wang, Bo Jiang, Ying Su, Xingyang He, Yingbin Wang and Sangkeun Oh
Materials 2022, 15(13), 4375; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15134375 - 21 Jun 2022
Cited by 4 | Viewed by 1428
Abstract
Alkali-activated materials (AAMs) are regarded as an alternative cementitious material for Portland cement with regards to sustainable development in construction. The purpose of this work is to investigate the properties of activated blast-furnace slag (BFS)–steel slag (SS) with sodium carbonate (NC), taking into [...] Read more.
Alkali-activated materials (AAMs) are regarded as an alternative cementitious material for Portland cement with regards to sustainable development in construction. The purpose of this work is to investigate the properties of activated blast-furnace slag (BFS)–steel slag (SS) with sodium carbonate (NC), taking into account BFS fineness and Na2O equivalent. The hydration was investigated by rheological behavior and pH development. The hydrates were characterized by TG-DTG and XRD, and the microstructure was analyzed by SEM and MIP. Results showed that the rheology of activated BFS-SS pastes was well-fitted with the H-B model and affected by BFS fineness and NC mixture ratio. It was found that BFS fineness and NC ratio played a crucial role in the initial alkalinity of SS-BFS-based pastes. As such, lower BFS fineness and higher NC ratio can dramatically accelerate the formation of reaction products to endow higher mechanical strength of BFS-SS pastes. However, the effect of NC ratio on the microstructure development of BFS-SS based AAMs was more obvious than BFS fineness. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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13 pages, 3605 KiB  
Article
Waste Polymer and Lubricating Oil Used as Asphalt Rheological Modifiers
by Khalid Ahmed Owaid, Ammar Ahmed Hamdoon, Rand Raad Matti, Mohanad Yakdhan Saleh and M. A. Abdelzaher
Materials 2022, 15(11), 3744; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15113744 - 24 May 2022
Cited by 21 | Viewed by 2159
Abstract
The hazards of plastic waste (PW) from polymers (e.g., polyethylene terephthalate (PET), high-density polyethylene (HDPE), low-density polyethylene (LDPE), polyvinyl chloride (PVC), nylon, polystyrene (PS), etc.), the mechanism of its spread in general, and its ubiquity in our daily lives as a continuously and/or [...] Read more.
The hazards of plastic waste (PW) from polymers (e.g., polyethylene terephthalate (PET), high-density polyethylene (HDPE), low-density polyethylene (LDPE), polyvinyl chloride (PVC), nylon, polystyrene (PS), etc.), the mechanism of its spread in general, and its ubiquity in our daily lives as a continuously and/or frequently expelled product are a crisis of the twenty-first century, as reported by the United Nations in 2019, especially after the outbreak of the COVID-19 pandemic. This research included the process of modifying the rheological properties of asphalt to obtain asphalt suitable for use in a high-humidity atmosphere. The Iraqi climate is characterized by heat that reaches the point of harshness in the summer and coldness that falls below zero on some winter days. From this point of view, our recent study focuses mainly on making rheological and chemical modifications to asphalt using spent polymeric materials and used lubricating oils (ULO), thus achieving two important goals, namely obtaining asphalt with rheological properties resistant to the Iraqi atmosphere as well as eliminating both solid and liquid environmental pollutants. The microstructure and morphology of the designed patches were characterized using scanning electron microscopy (SEM) to indicate phase composition. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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11 pages, 2894 KiB  
Article
Hydration Mechanisms of Alkali-Activated Cementitious Materials with Ternary Solid Waste Composition
by Zhijie Yang, De Zhang, Chengyang Fang, Yang Jiao, Dong Kang, Changwang Yan and Ju Zhang
Materials 2022, 15(10), 3616; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15103616 - 18 May 2022
Cited by 4 | Viewed by 1270
Abstract
Considering the recent eco-friendly and efficient utilization of three kinds of solid waste, including calcium silicate slag (CSS), fly ash (FA), and blast-furnace slag (BFS), alkali-activated cementitious composite materials using these three waste products were prepared with varying content of sodium silicate solution. [...] Read more.
Considering the recent eco-friendly and efficient utilization of three kinds of solid waste, including calcium silicate slag (CSS), fly ash (FA), and blast-furnace slag (BFS), alkali-activated cementitious composite materials using these three waste products were prepared with varying content of sodium silicate solution. The hydration mechanisms of the cementitious materials were analyzed by X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. The results show that the composite is a binary cementitious system composed of C(N)-A-S-H and C-S-H. Si and Al minerals in FA and BFS are depolymerized to form the Q0 structure of SiO4 and AlO4. Meanwhile, β-dicalcium silicate in CSS hydrates to form C-S-H and Ca(OH)2. Part of Ca(OH)2 reacts with the Q0 structure of AlO4 and SiO4 to produce lawsonite and wairakite with a low polymerization degree of the Si-O and Al-O bonds. With the participation of Na+, part of Ca(OH)2 reacts with the Q0 structure of AlO4 and the Q3 structure of SiO4, which comes from the sodium silicate solution. When the sodium silicate content is 9.2%, the macro properties of the composites effectively reach saturation. The compressive strength for composites with 9.2% sodium silicate was 23.7 and 35.9 MPa after curing for 7 and 28 days, respectively. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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17 pages, 5164 KiB  
Article
Experimental Study and Mechanism Analysis of Preparation of α-Calcium Sulfate Hemihydrate from FGD Gypsum with Dynamic Method
by Ying Li, Wen Ni, Pengxuan Duan, Siqi Zhang and Jiajia Wang
Materials 2022, 15(9), 3382; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15093382 - 09 May 2022
Cited by 4 | Viewed by 2496
Abstract
Flue-gas desulphurization (FGD) gypsum is a highly prevalent industrial by-product worldwide, which can be an excellent alternative to natural gypsum due to its high content of CaSO4·2H2O. The preparation of α-calcium sulfate hemihydrate is a high-value pathway for the [...] Read more.
Flue-gas desulphurization (FGD) gypsum is a highly prevalent industrial by-product worldwide, which can be an excellent alternative to natural gypsum due to its high content of CaSO4·2H2O. The preparation of α-calcium sulfate hemihydrate is a high-value pathway for the efficient use of FGD gypsum. Here, a dynamic method, or an improved autoclaved process, was used to produce α-calcium sulfate hemihydrate from FGD gypsum. In this process, the attachment water of the mixture of FGD gypsum and crystal modifiers was approximately 18%, and the pH value was approximately 6.0. The mixture did not need to be pressed into bricks or made into slurry, and it was directly sent into the autoclave reactor for reaction. It was successfully applied to the practical production and application of FGD gypsum, citric acid gypsum and phosphogypsum. In this work, the compositions and morphology of the product at different stages of the reaction were examined and compared. In particular, single-crystal diffraction was used to produce the crystal structure of CaSO4·0.5H2O, and the results were as follows: a = 13.550(3); b = 13.855(3); c = 12.658(3); β = 117.79(3)°; space group C2. The preferential growth along the c-axis and the interaction mechanism between the carboxylate groups and the crystal were discussed throughout the analysis of the crystal structure. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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23 pages, 18162 KiB  
Article
Durability and Improvement of Cement-Based Revetment Materials Serving in Subtidal, Intertidal, and Supratidal Environments
by Rui Sun, Dongmin Wang, Yiren Wang, Lei Zhang and Yue Gu
Materials 2022, 15(9), 3210; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15093210 - 29 Apr 2022
Cited by 1 | Viewed by 1303
Abstract
To improve the durability of cement-based revetment materials serving in different positions relative to the water level, slag powder and polypropylene fibers were added into cement to prepare paste, mortar, and concrete. Based on three simulated experiments of high-humidity air, dry–wet cycles-coupled chloride [...] Read more.
To improve the durability of cement-based revetment materials serving in different positions relative to the water level, slag powder and polypropylene fibers were added into cement to prepare paste, mortar, and concrete. Based on three simulated experiments of high-humidity air, dry–wet cycles-coupled chloride erosion, and complete immersion-coupled chloride erosion, the half-year durability of cement-based revetment materials was investigated. An abundant amount of Ettringite containing chloride was formed in the pores of the cement, and its formation was accelerated by dry–wet cycles. Replacing 30% of cement by slag powder and adding 0.1 vol.% of polypropylene fibers helped concrete in the intertidal zone to obtain a compressive strength of 47.58 MPa after erosion, equal to 159% of the reference. Slag powder was found to induce cement to form Friedel’s salt and C-S-H with a more amorphous structure, increasing its chemical binding ability and physical adsorption ability to chloride ions, and reduce the chloride ions’ penetration depth of concrete from 22.5 to 12.6 mm. Polypropylene fibers controlled the direction of surface cracks to be perpendicular to the specimen’s sides. These findings lay a foundation for the design of high-durability cement-based revetment materials serving in costal environments. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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14 pages, 13961 KiB  
Article
Experimental Study on Subgrade Material of Calcium Silicate Slag
by De Zhang, Zhijie Yang, Dong Kang, Chenyang Fang, Yang Jiao and Shizhong Mi
Materials 2022, 15(6), 2304; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15062304 - 20 Mar 2022
Cited by 1 | Viewed by 1479
Abstract
Calcium silicate slag (CSS) is used as a secondary solid waste produced by aluminum extraction technology from high alumina fly ash, and its resource utilization has always been a key issue to be solved. In this study, CSS was used to replace a [...] Read more.
Calcium silicate slag (CSS) is used as a secondary solid waste produced by aluminum extraction technology from high alumina fly ash, and its resource utilization has always been a key issue to be solved. In this study, CSS was used to replace a portion of fly ash (FA) to prepare a new inorganic binder stabilized material for road base. The unconfined compressive strength (UCS), phase composition, microstructure, durability and performance index of the base of the test section of the CSS pavement base material were studied. The results showed that with the increase in CSS content, the UCS of pavement base materials gradually increased. Under standard curing conditions, the UCS increased 6.90~17.24% after 7 days, and 7.90~28.95% after 28 days. The main reason was that as the hydration time increased from 7 d to 28 d, the hydration products C-A-S-H gel and C-S-H gel increased, the [SiO4] polymerization degree increased, the crystal type changed, and the structure denser, which supported the good development of mechanical strength of CSS pavement base material. In addition, the research has been successfully applied to a pilot test in Hohhot, China. The freeze–thaw resistance, water stability and UCS of the CSS pavement base material were tested to meet the requirements of Chinese road construction standards, indicating that the application of CSS in pavement base is feasible. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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11 pages, 2994 KiB  
Article
Effect of Phase Composition on Leaching Behavior and Mechanical Properties of Ceramics from Ferrochrome Slag and Tundish Slag
by Dejian Pei, Yu Li, Xiangjie Duan, Daqiang Cang, Yindong Yang, Alex McLean, Zhancheng Guo and Chuanhua Xu
Materials 2022, 15(6), 1993; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15061993 - 08 Mar 2022
Cited by 2 | Viewed by 1435
Abstract
Ferrochrome slag (FS) and tundish slag (TS) are two typical slags containing high contents of Cr2O3 (3.88 wt.%) and MnO (18.69 wt.%), respectively. In this study, batches of ceramics were prepared from FS and TS, and their Cr/Mn leaching behaviors, [...] Read more.
Ferrochrome slag (FS) and tundish slag (TS) are two typical slags containing high contents of Cr2O3 (3.88 wt.%) and MnO (18.69 wt.%), respectively. In this study, batches of ceramics were prepared from FS and TS, and their Cr/Mn leaching behaviors, mechanical properties and microstructures were investigated. Results showed that ceramics with 80 wt.% FS or 85 wt.% TS had acceptable properties. By controlling its composition and sintering temperature, pyroxene or spinel phases could become the main crystalline phases of the fired ceramics containing either of the two slags. For both slag series, pyroxene phases contributed to higher bending strengths, whereas spinel phases led to lower Cr/Mn leaching rates. Both ceramic containing 20 wt.% FS and ceramic containing 85 wt.% TS had the main crystals of pyroxene phases and possessed the highest bending strengths (FS20: 114.52 MPa and TS85: 124.61 MPa). However, both ceramic containing 80 wt.% FS and ceramic containing 25 wt.% TS with main crystals from the spinel phases had the lowest Cr/Mn leaching rates (FS80: Cr 0.05% and TS25: Mn 0.43%). Therefore, optimum designs for the compositions of ceramics from different slags were achieved by changing the proportions of pyroxene and spinel phases to obtain a balance between the high strengths of materials and the stable retention of heavy metal ions. This study provides an important basis for long-term research on the large-scale reuse of heavy metal-containing slags in the ceramic industry. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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11 pages, 3622 KiB  
Article
Crystal Evolution of Calcium Silicate Minerals Synthesized by Calcium Silicon Slag and Silica Fume with Increase of Hydrothermal Synthesis Temperature
by Zhijie Yang, De Zhang, Yang Jiao, Chengyang Fang, Dong Kang, Changwang Yan and Ju Zhang
Materials 2022, 15(4), 1620; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15041620 - 21 Feb 2022
Cited by 8 | Viewed by 1618
Abstract
In order to realize high-value utilization of calcium silicon slag (CSS) and silica fume (SF), the dynamic hydrothermal synthesis experiments of CSS and SF were carried out under different hydrothermal synthesis temperatures. In addition, phase category, microstructure, and micropore parameters of the synthesis [...] Read more.
In order to realize high-value utilization of calcium silicon slag (CSS) and silica fume (SF), the dynamic hydrothermal synthesis experiments of CSS and SF were carried out under different hydrothermal synthesis temperatures. In addition, phase category, microstructure, and micropore parameters of the synthesis product were analyzed through testing methods of XRD, SEM, EDS and micropore analysis. The results show that the main mechanism of synthesis reaction is that firstly β-Dicalcium silicate, the main mineral in CSS, hydrates to produce amorphous C–S–H and Ca(OH)2, and the environment of system is induced to strong alkaline. Therefore, the highly polymerized Si-O bond of SF is broken under the polarization of OH− to form (SiO4) of Q0. Next, amorphous C–S–H, Ca(OH)2 and (SiO4) of Q0 react each other to gradually produce various of calcium silicate minerals. With an increase of synthesis temperature, the crystal evolution order for calcium silicate minerals is cocoon-like C–S–H, mesh-like C–S–H, large flake-like gyrolite, small flake-like gyrolite, petal-like gyrolite, square flake-like calcium silicate hydroxide hydrate, and strip-like tobermorite. In addition, petal-like calcium silicate with high average pore volume (APV), specific surface area (SSA) and low average pore diameter (APD) can be prepared under the 230 °C synthesis condition. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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15 pages, 6415 KiB  
Article
The Effect of Alcohol Compound on the Solidification of Magnesium Oxysulfate Cement-Boron Mud Blends
by Yuanyuan Liang, Yan Guan and Wanli Bi
Materials 2022, 15(4), 1446; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15041446 - 15 Feb 2022
Cited by 2 | Viewed by 1311
Abstract
At present, the utilization of boron resources in China is increasing, and the problem of boron tailing pollution is becoming increasingly serious. To fundamentally solve the problem of boron tailing, many scholars at home and abroad have mainly studied the curing effect in [...] Read more.
At present, the utilization of boron resources in China is increasing, and the problem of boron tailing pollution is becoming increasingly serious. To fundamentally solve the problem of boron tailing, many scholars at home and abroad have mainly studied the curing effect in terms of compressive strength, and little research has been carried out into the solidification effect and hydration products. This study explored the effects of adding different alcohol-based modifiers on the hydration products of magnesium oxysulfate cement-boron mud mixture, the microstructure, physical properties and curing effects of the samples. The results show that magnesium oxysulfate cement is beneficial to the solidification of boron in boron mud due to its low-alkali. Adding an alcohol-based modifier can increase the compressive strength of magnesium oxysulfate cement-boron mud blends. After adding acrylic acid and D-Mannitol, the 28-day compressive strength of the sample increased by 44.7 MPa. The blending of alcohol-based modifiers has a very good effect on the curing of boron in the whole system. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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20 pages, 66143 KiB  
Article
In-Situ Crystallization and Characteristics of Alkali-Activated Materials-Supported Analcime-C from a By-Product of the Lithium Carbonate Industry
by Lixiang Huang, Le Han, Ze Liu, Jixiang Wang, Yanbo Zhang and Dongmin Wang
Materials 2022, 15(3), 1261; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15031261 - 08 Feb 2022
Cited by 1 | Viewed by 1856
Abstract
The present study proposes a new process for synthesis of alkali-activated materials (AAM)-supported analcime-C foam materials (AFs), utilizing a by-product of the lithium carbonate industry. This material has great application value as a bulk-type solid adsorbent. Characterization analyses show that the alkaline activator [...] Read more.
The present study proposes a new process for synthesis of alkali-activated materials (AAM)-supported analcime-C foam materials (AFs), utilizing a by-product of the lithium carbonate industry. This material has great application value as a bulk-type solid adsorbent. Characterization analyses show that the alkaline activator modulus greatly affects the crystallinity of analcime-C in AFs. Furthermore, the compressive strength, zeolite yield, and microstructure of AFs are significantly affected by the saturated steam parameters, including crystallization pressure, temperature, and time. The synthesized materials comprise pores of different sizes (micro to macro). They combine the functional micro-porosity of the analcime-C, the meso-porosity of the gel matrix, and the macro-porosity of the foamed AAM. The maximum compressive strength, density, total porosity, and Pb2+ adsorption capacity of AFs investigated in this study are 1.15 MPa, 350 kg/m3, 76.5%, and 69.3 mg/g Pb2+, respectively. Unlike many granular adsorbents, the bulk AFs adsorbent produced by this process is easy to recycle. In addition, it also contributes to the comprehensive utilization of a by-product of the lithium carbonate industry. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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14 pages, 6750 KiB  
Article
Properties of Blended Cement Containing Iron Tailing Powder at Different Curing Temperatures
by Heng Wang, Fanghui Han, Shaochang Pu and Hongbo Zhang
Materials 2022, 15(2), 693; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15020693 - 17 Jan 2022
Cited by 4 | Viewed by 1684
Abstract
The properties of blended cement containing 0%, 20%, and 50% iron tailing powder (ITP) at 20 °C and 60 °C were investigated by determining the hydration heat, microstructure, and compressive strength. The addition of ITP decreases the exothermic rate and cumulative hydration heat [...] Read more.
The properties of blended cement containing 0%, 20%, and 50% iron tailing powder (ITP) at 20 °C and 60 °C were investigated by determining the hydration heat, microstructure, and compressive strength. The addition of ITP decreases the exothermic rate and cumulative hydration heat of blended cement at 20 °C. The high temperature increases the hydration rate and leads to the hydration heat of blended cement containing 20% ITP higher than that of Portland cement. Increasing the amount of ITP decreases the non-evaporable water content and Ca(OH)2 content as well as compressive strength at both of the two studied temperatures. The addition of ITP coarsens the early-age pore structure but improves the later-age pore structure at 20 °C. The high temperature significantly improves the early-age properties of blended cement containing ITP, but it is detrimental to the later-age properties development. The reaction of ITP is limited even at high temperature. The large ITP particles bond poorly with surrounding hydration products under early high-temperature curing condition. The properties of blended cement containing a large amount of ITP are much poorer at high temperature. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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12 pages, 5768 KiB  
Article
An Eco-Friendly Acid Leaching Strategy for Dealkalization of Red Mud by Controlling Phase Transformation
by Jiaming Wu, Tianyu Lei, Beibei Wang, Shuwei Ma, Yulong Lin, Xiaolei Lu and Zhengmao Ye
Materials 2022, 15(2), 580; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15020580 - 13 Jan 2022
Cited by 5 | Viewed by 1632
Abstract
The alkaline components in red mud represent one of the crucial factors restricting its application, especially for the construction and building industry. The phase state of alkaline components has a significant influence on the dealkalization of red mud. In this work, an environmentally [...] Read more.
The alkaline components in red mud represent one of the crucial factors restricting its application, especially for the construction and building industry. The phase state of alkaline components has a significant influence on the dealkalization of red mud. In this work, an environmentally friendly acid leaching strategy is proposed by controlling the phase transformation of red mud during active roasting pretreatment. With a moderate roasting temperature, the alkaline component is prevented from converting into insoluble phases. After acid leaching with a low concentration of 0.1 M, a high dealkalization rate of 92.8% is obtained. Besides, the leachate is neutral (pH = 7) and the valuable metals in red mud are well preserved, manifesting a high selectivity and efficiency of diluted acid leaching. The calcination experiment further confirms the practicability of the strategy in the construction field, where the cementitious minerals can be formed in large quantities. Compared with the traditional acid leaching routes, the diluted acid leaching strategy in this work is acid saving with low valuable element consumption. Meanwhile, the secondary pollution issue can be alleviated. Hence, the findings in this work provide a feasible approach for the separation and recovery of alkali and resource utilization of red mud. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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18 pages, 12967 KiB  
Article
C-A-S-H Gel and Pore Structure Characteristics of Alkali-Activated Red Mud–Iron Tailings Cementitious Mortar
by Chao Li, Na Zhang, Jiancong Zhang, Shuai Song and Yihe Zhang
Materials 2022, 15(1), 112; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15010112 - 24 Dec 2021
Cited by 13 | Viewed by 3836
Abstract
Red mud and iron tailings are representative solid wastes in China, which have caused serious environmental pollution and potential harmful risk to people. Based on the alkali characteristic of Bayer red mud and natural fine-grained feature of iron tailings, these two solid wastes [...] Read more.
Red mud and iron tailings are representative solid wastes in China, which have caused serious environmental pollution and potential harmful risk to people. Based on the alkali characteristic of Bayer red mud and natural fine-grained feature of iron tailings, these two solid wastes were used as raw materials to prepare alkali-activated cementitious mortar (AACM). The microstructure of C-A-S-H gel, pore structure characteristics, environmental impact and economic potential of this AACM were investigated. The results show that C-A-S-H gel was mainly composed of SiQ3 structure in the 28-day cured AACM. The relative content of SiQ4 structure increased while that of SiQ2 structure decreased as the hydration time advanced from 7 to 28 days, resulting in the increase of relative bridge oxygen value by 11.02%. The pores in the AACM sample accounted for 6.73% of the total volume, and these pores were not connected. The pore distribution was relatively uniform, which supported the good development of mechanical strength for AACM. This research elucidates the formation mechanism of C-A-S-H gels in the Bayer red mud–iron tailings-based AACM. In addition, the lower embodied carbon and material cost demonstrate that the prepared AACM has great environmental benefit and certain economic potential. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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13 pages, 13479 KiB  
Article
Rapid Evaluation of the Pozzolanic Activity of Bayer Red Mud by a Polymerization Degree Method: Correlations with Alkali Dissolution of (Si+Al) and Strength
by Yaguang Wang, Xiaoming Liu, Zhiqing Xie, Huimin Wang, Wei Zhang and Yang Xue
Materials 2021, 14(19), 5546; https://0-doi-org.brum.beds.ac.uk/10.3390/ma14195546 - 24 Sep 2021
Cited by 8 | Viewed by 1612
Abstract
A large amount of Bayer process red mud is discharged in the process of alumina production, which has caused significant pollution in the environment. The pozzolanic activity of Bayer red mud as a supplementary cementitious material is a research hotspot. In this work, [...] Read more.
A large amount of Bayer process red mud is discharged in the process of alumina production, which has caused significant pollution in the environment. The pozzolanic activity of Bayer red mud as a supplementary cementitious material is a research hotspot. In this work, a new method for Fourier-transform infrared spectrometry is used to determine the polymerization degree of Bayer red mud in order to evaluate its pozzolanic activity. Based on the results of the dissolution concentration of (Si+Al), strength index and polymerization degree of Bayer red mud, the relationships between different evaluation methods were analyzed, and the relevant calculation formulas of pozzolanic activity were obtained. The results showed that different evaluation methods can reflect the variation law of pozzolanic activity in Bayer red mud. The polymerization degree of Bayer red mud had a good linear relationship with the pozzolanic activity index obtained by the strength index and dissolution concentration of (Si+Al), respectively. The polymerization degree was negatively correlated with pozzolanic activity index and dissolution concentration of (Si+Al), and the correlation coefficients were greater than 0.85. Therefore, this method was found to be effective and hence can be used as a rapid and simple test for pozzolanic activity evaluation of Bayer red mud. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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Review

Jump to: Research

24 pages, 7714 KiB  
Review
Comprehensive Understanding of Aluminosilicate Phosphate Geopolymers: A Critical Review
by Shanliang Ma, Zengqi Zhang and Xiaoming Liu
Materials 2022, 15(17), 5961; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15175961 - 29 Aug 2022
Cited by 10 | Viewed by 1669
Abstract
Aluminosilicate phosphate (ASP) geopolymers are a new kind of green cementitious materials synthesized from aluminosilicate precursors and acidic activators (phosphoric acid or phosphate), which have received extensive attention from researchers because of their excellent and unique characteristics. The current investigation indicates that ASP [...] Read more.
Aluminosilicate phosphate (ASP) geopolymers are a new kind of green cementitious materials synthesized from aluminosilicate precursors and acidic activators (phosphoric acid or phosphate), which have received extensive attention from researchers because of their excellent and unique characteristics. The current investigation indicates that ASP geopolymers have the characteristics of a low-carbon synthesis process, high mechanical properties (e.g., the highest compressive strength can reach 146 MPa), a strong heat resistance (e.g., withstanding a high temperature of 1500 °C), and excellent dielectric properties. These excellent properties make them have broad application prospects in the fields of new building materials, coating materials, insulating materials, and heavy metal curing. Based on the research findings of approximately 85 relevant literatures on ASP geopolymers in past decades, this paper focuses on the latest research progress of ASP geopolymers from the perspectives of synthesis processes, performances, modifications, and application developments. In addition, this study summarizes the key problems existing in the current research of ASP geopolymers and suggests their possible applications in the future, which will help to provide directions for further research activities of relevant researchers. Full article
(This article belongs to the Special Issue Industrial Solid Wastes for Construction and Building Materials)
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