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Nanomaterial Interfaces: From Fundamentals to Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Nanomaterials and Nanotechnology".

Deadline for manuscript submissions: closed (20 May 2022) | Viewed by 3218

Special Issue Editor


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Guest Editor
Department of Chemistry, Humboldt-Universität zu Berlin, 10099 Berlin, Germany
Interests: nanoscale interfaces; graphene; functionalized (1D and 2D) nanostructures; sensors; electrocatalysis; electrochemistry and scanning probe microscopy

Special Issue Information

Dear Colleagues,

Nanomaterials. such as nanoparticles, carbon nanotubes, inorganic/polymer nanowires, graphene, transition metal dichalcogenides, and perovskites, etc., show great promise as active materials in a range of applications due to their unique and extraordinary physical and chemical properties. While designing new applications using such nanomaterials—either at a single object level or integrated in a composite form—interfaces occur inevitably and they play a vitally important role. There are different kinds of interfaces that one encounters when exploiting nanomaterials for applications: It could be between similar phases (solid–solid/liquid–liquid) or dissimilar phases (solid–liquid/solid–gas). For example, in sensors operating in liquids, the chemistry of the interface between the solid material and the medium needs to be optimized in order to achieve high sensitivity. In the fabrication of batteries and fuel cells, several material (often solid–solid) interfaces occur at the electrodes, and they have to be suitably designed in order to achieve maximum performance. Similarly, the nano(material)–bio(molecule) interface requires thorough investigation in the design of novel biomaterials as well as for realizing bioelectronic and biomedical applications.

This Special Issue is dedicated to addressing all such issues related to interfaces that are encountered when using nanomaterials for potential applications. Manuscripts (original articles or reviews) may address one or more of the following aspects:

  • Modeling of interfaces, which is key to engineering and optimizing new applications;
  • Fundamental aspects of nanomaterial interfaces focused on a specific application;
  • Synthesis of novel nanomaterials with optimized interfaces;
  • Characterization of nanomaterial interfaces;
  • Development of new analytical strategies for studying nanomaterial interfaces;
  • Chemical modification of nanomaterials;
  • Nano-biointerfaces with focus on biomaterials, bioelectronics, and biomedical aspects;
  • Interfacial phenomena in nanomaterial-based devices and systems;
  • Role of interfaces in nanomaterial-based strategies for applications, including but not limited to (opto)electronic devices, (bio)sensors, (electro/photo) catalysts, batteries, fuel/solar cells, and biomaterials.

When submitting a manuscript to this Special Issue, please mention in the cover letter how the reported research addresses the focus of this Special Issue.

Prof. Dr. Kannan Balasubramanian
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • solid–liquid interface
  • nanoscale interfaces
  • naon-biointerfaces
  • chemical functionalization
  • interfacial phenomena
  • nanoscale characterization

Published Papers (1 paper)

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Research

13 pages, 3046 KiB  
Communication
Removal of Thiol-SAM on a Gold Surface for Re-Use of an Interdigitated Chain-Shaped Electrode
by Hien T. Ngoc Le, Le Minh Tu Phan and Sungbo Cho
Materials 2022, 15(6), 2218; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15062218 - 17 Mar 2022
Cited by 4 | Viewed by 2731
Abstract
The self-assembled monolayer (SAM) is the most common organic assembly utilized for the formation of the monolayers of alkane-thiolates on gold electrode, resulting in a wide range of applications for the modified SAM on gold in various research areas. This study examined the [...] Read more.
The self-assembled monolayer (SAM) is the most common organic assembly utilized for the formation of the monolayers of alkane-thiolates on gold electrode, resulting in a wide range of applications for the modified SAM on gold in various research areas. This study examined the desorption of a SAM that was developed on the gold surface of an interdigitated chain-shaped electrode (the ICE, a unique electrode design, was fabricated by our group) with the goal of determining the most efficient strategy of SAM removal for the ICE to be re-used. A simple and proficient solution-based cleaning procedure was applied for the removal of a SAM on the gold surface of the ICE by using a sodium borohydride solution within short-term treatment, resulting in efficiency for the recovery of the originally electrochemical characteristic of ICE of 90.3%. The re-use of ICE after the removal process was confirmed by the successful re-deposition of a SAM onto the electrode surface, resulting in the high efficiency percentage of 90.1% for the reusability of ICE with the SAM modification. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) were used as tools to investigate the changes in the electrode interface at each stage of the SAM removal and the electrode recycling. X-ray photoelectron spectroscopy and Fourier-transform infrared spectroscopy were employed, being powerful spectrum techniques, for the characterization of the bonding structure and chemical state of the bare ICE and the modified ICE at each treatment step. Based on the comprehensive discussion of analytical chemistry from the obtained EIS and CV data in this study, we confirmed and proved the effectiveness of this promising method for the removal of a SAM from the ICE and the re-use of ICE in the field of material deposition, with the aims of saving money, improving experimental handling, and protecting the environment. Full article
(This article belongs to the Special Issue Nanomaterial Interfaces: From Fundamentals to Applications)
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