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Microstructure Characterization of Materials: In Situ TEM Investigation

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Materials Characterization".

Deadline for manuscript submissions: closed (20 August 2023) | Viewed by 3254

Special Issue Editor


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Guest Editor
Electron Microscopy Laboratory, Faculty of Mechanical Engineering, Wrocław University of Science and Technology, Wrocław, Poland
Interests: in situ TEM; transmission electron microscopy; microstructure characterization; smart materials; magnetic domain imaging; Lotentz microscopy; photocatalysis; catalytic materials

Special Issue Information

Dear Colleagues,

One picture means more than a thousand words. Undoubtedly, this is one of the slogans that guide researchers specializing in dynamic imaging experiments. There is no doubt, however, that despite the passage of years, in situ electron microscopy remains an exceptionally demanding technique. The experiments carried out with it allow pushing the boundaries of knowledge but often require significant interference in the microscope or the use of dedicated, prototype devices. Changing the sample temperature, interaction with a magnetic or electric field, mechanical, light, or accelerated particle influence, chemical experiments in liquids and gases, electron beam-driven reactions—despite the wide possibilities, the pool of available experiments remains open and limited only by the creativity of researchers.

It is my pleasure to invite you to submit a manuscript for this Special Issue. Full papers, communications, and reviews in the field of in situ electron microscopy are all welcome. We are interested in both research carried out with the use of commercial systems and your prototype designs, not limited to only TEM or SEM. If you want to propose or consult an article before preparing your work, the editorial board is at your disposal.

Dr. Andrzej Żak
Guest Editor

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • in situ
  • in situ heating
  • in situ straining
  • in situ magnetization
  • transmission electron microscopy
  • scanning electron microscopy
  • EBSD
  • Lorentz
  • electron holography

Published Papers (2 papers)

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Research

10 pages, 2153 KiB  
Article
On the Electronic Structure of 2H-MoS2: Correlating DFT Calculations and In-Situ Mechanical Bending on TEM
by Manuel Ramos, Oscar A. López-Galán, Javier Polanco and Miguel José-Yacamán
Materials 2022, 15(19), 6732; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15196732 - 28 Sep 2022
Viewed by 1257
Abstract
We present a systematic density functional theory study to determine the electronic structure of bending 2H-MoS2 layers up to 75° using information from in-situ nanoindentation TEM observations. The results from HOMO/LUMO and density of states plots indicate a metallic transition from the [...] Read more.
We present a systematic density functional theory study to determine the electronic structure of bending 2H-MoS2 layers up to 75° using information from in-situ nanoindentation TEM observations. The results from HOMO/LUMO and density of states plots indicate a metallic transition from the typical semiconducting phase, near Fermi energy level (EF) as a function of bending, which can mainly occur due to bending curvatures inducing a stretching and contracting of sulfur-sulfur chemical bonds located mostly over basal (001)-plane; furthermore, molybdenum ions play a major role in such transitions due to reallocation of their metallic d-character orbitals and the creation of “free electrons”, possibly having an overlap between Mo-dx2-y2 and Modz2 orbitals. This research on the metallic transition of 2H-MoS2 allows us to understand the high catalytic activity for MoS2 nanostructures as extensively reported in the literature. Full article
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7 pages, 3003 KiB  
Article
Real-Time Observation of Magnetic Domain Structure Changes with Increasing Temperature for Z-Type Hexagonal Ferrite
by Sung-Dae Kim and Ihho Park
Materials 2022, 15(10), 3646; https://0-doi-org.brum.beds.ac.uk/10.3390/ma15103646 - 20 May 2022
Cited by 3 | Viewed by 1326
Abstract
Z-type hexagonal ferrites have recently received attention for their room-temperature magnetoelectric (ME), which is activated when the temperature at which the transverse-conical spin-state transitions to a ferrimagnetic state is increased. The changes in the magnetic domain structure at the transition have been well-documented; [...] Read more.
Z-type hexagonal ferrites have recently received attention for their room-temperature magnetoelectric (ME), which is activated when the temperature at which the transverse-conical spin-state transitions to a ferrimagnetic state is increased. The changes in the magnetic domain structure at the transition have been well-documented; however, they are still not understood in detail. In the present study, Lorentz transmission electron microscopy (TEM) analysis combined with an in situ heating experiment was conducted to demonstrate the shift in magnetic domain structure during the transition from the transverse-conical spin arrangement to a ferrimagnetic spin order. The dynamics of the magnetic domain structure changes with the increasing temperature were acquired in real-time. At 490 K, the magnetization transition from the transverse-conical spin state to the ferromagnetic state was demonstrated. Cross-tie domain walls formed during the magnetic transition process. The increased effect of the demagnetizing field applied to the 180° magnetic domains was caused by a lower magnetocrystalline anisotropy (MCA) at the easy axis of magnetization. Full article
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