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Conversion of Fly Ash into Zeolites and Their Application as Adsorbents of Carbon Dioxide

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Porous Materials".

Deadline for manuscript submissions: closed (20 May 2022) | Viewed by 1419

Special Issue Editor


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Guest Editor
Department of Thermal and Nuclear Power Engineering, Technical University of Sofia, Sofia, Bulgaria
Interests: systems and devices for environmental protection; water treatment systems and processes; coal fly ash utilization; carbon capture and utilization

Special Issue Information

Dear Colleagues,

The Special Issue, “Conversion of Fly Ash into Zeolites and Their Application as Adsorbents of Carbon Dioxide”, will address novel approaches and the optimization of existing ones for the utilization of coal fly ash from the combustion of coals through its conversion into zeolite-like materials. Non-modified and modified coal fly ash zeolites reveal a high carbon capture potential and are considered to be efficient and low-cost CO2 adsorbents. Coal fly ash zeolites are distinguished from zeolites synthesized from pure starting materials in a significant content of iron oxides and variety of metal traces transferred from the raw material, as well as with a particular micro-mesoporous structure that predetermines strong surface unsaturation and facilitated mass transfer processes. These features define coal ash zeolites as a new class of materials with very promising valuable applications, especially in carbon capture systems. The utilization of coal ash in low-carbon technologies is of great research and technological interest and will contribute to a number of environmental benefits: reduction of coal ash deposits, preservations of natural resources and raw materials, development of affordable technological solutions for wide implementation to capture carbon emissions from thermal and industrial plants. This Special Issue aims to collect original research papers and reviews on the conversion of coal fly ash into zeolites and their application for CO2 adsorption. Both experimental and model studies are of particular interest. Articles and reviews dealing with CO2 adsorption at low and high pressures and regeneration of coal fly ash zeolites, adsorption/desorption cycles, elucidation of adsorption mechanisms through thermodynamic studies, kinetic models, studies on the influence of various components included into the coal ash zeolite matrix onto carbon capture potential, and studies on selectivity and capacity of CO2 adsorption in equilibrium and dynamic conditions are very welcome. Of great interest are publications on dual systems based on coal fly ash zeolites for CO2 capture and its catalytic transformation to synthetic fuels or chemical products.

Dr. Sylvia Boycheva
Guest Editor

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Keywords

  • coal fly ash zeolites
  • Surface studies
  • CO2 adsorption
  • adsorption kinetics
  • thermodynamics of CO2 adsorption
  • modified coal fly ash zeolites
  • pressure-swing adsorption
  • vacuum-swing adsorption
  • catalytic CO2 conversion
  • CO2 capture modeling

Published Papers (1 paper)

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Research

15 pages, 3808 KiB  
Article
Methodology for Evaluating the CO2 Sequestration Capacity of Waste Ashes
by Sara Tominc and Vilma Ducman
Materials 2023, 16(15), 5284; https://0-doi-org.brum.beds.ac.uk/10.3390/ma16155284 - 27 Jul 2023
Cited by 1 | Viewed by 1040
Abstract
The concentration of CO2 in the atmosphere is constantly increasing, leading to an increase in the average global temperature and, thus, affecting climate change. Hence, various initiatives have been proposed to mitigate this process, among which CO2 sequestration is a technically [...] Read more.
The concentration of CO2 in the atmosphere is constantly increasing, leading to an increase in the average global temperature and, thus, affecting climate change. Hence, various initiatives have been proposed to mitigate this process, among which CO2 sequestration is a technically simple and efficient approach. The spontaneous carbonation of ashes with atmospheric CO2 is very slow, and this is why accelerated carbonation is encouraged. However, not all ashes are equally suitable for this process, so a methodology to evaluate their potential should be developed. Such a methodology involves a combination of techniques, from theoretical calculations to XRF, XRD, DTA-TG, and the calcimetric determination of the CaCO3 content. The present study followed the approach of exposing ashes to accelerated carbonation conditions (4% v/v CO2, 50–55% and 80–85% RH, 20 °C) in a closed carbonation chamber for different periods of time until the maximum CO2 uptake is reached. The amount of sequestered CO2 was quantified by thermogravimetry. The results show that the highest CO2 sequestration capacity (33.8%) and carbonation efficiency (67.9%) were obtained for wood biomass bottom ash. This method was applied to eight combustion ashes and could serve to evaluate other ashes or comparable carbon storage materials. Full article
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