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Microstructural Evolution, Electrical Properties and Conduction Mechanism of Novel Energy Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Energy Materials".

Deadline for manuscript submissions: closed (10 February 2023) | Viewed by 1564

Special Issue Editor

Department of Physics, Chungnam National University, Daejeon, Korea
Interests: semiconductor optical properties; photovoltaics; photoluminescence; semiconductor nanostructure; physics; quantum dots; Raman scattering

Special Issue Information

Dear Colleagues,

Our society faces rapidly growing global energy demands and the associated environmental concerns. In order to achieve sufficient efficiency with reduced cost, polycrystalline/nanocrystal films such as perovskite are fabricated with spin-cast and sintering processes rather than by utilizing expensive high-vacuum facilities. These energy materials offer interesting physical and chemical properties such as microstructural evolution (grain, grain boundary effect) and electrical properties (charge carrier transport, diffusion length, carrier trapping and detrapping). Improved efficiency in photovoltaic, piezoelectric, and thermoelectric materials is often associated with the efficient transport of carriers which have to overcome the potential barriers at the grain boundaries existing in polycrystalline or nanocrystalline films.

This Special Issue, “Microstructural Evolution, Electrical Properties and Conduction Mechanism of Novel Energy Materials”, will attempt to cover the recent advances in energy materials from polycrystalline or nanocrystalline film fabrication/material characterization to device fabrication and testing.

Topics of interest include, but are not limited to: polycrystalline/nanocrystalline film fabrication; structural evolution via post-growth treatment; optical and/or electrical properties; grain or ligand effect; carrier lifetime and transport; energy migration; energy-related characteristics such as photovoltaic, piezoelectric, and thermoelectric; etc.

Dr. Eunsoon Oh
Guest Editor

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • perovskite films
  • photovoltaic
  • solar energy conversion
  • piezoelectric
  • thermoelectric
  • nanocrystals
  • microcrystals

Published Papers (1 paper)

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Research

11 pages, 2277 KiB  
Article
Performance Enhancement in Powder-Fabricated Cu2(ZnSn)Se4 Solar Cell by Roll Compression
by Jaehyun Park, Hyobin Nam, Bong-Geun Song, Darya Burak, Ho Seong Jang, Seung Yong Lee, So-Hye Cho and Jong-Ku Park
Materials 2023, 16(3), 1076; https://0-doi-org.brum.beds.ac.uk/10.3390/ma16031076 - 26 Jan 2023
Cited by 1 | Viewed by 1168
Abstract
Despite the improved conversion efficiency of Cu2(ZnSn)Se4 (CZTSe) solar cells, their roll-to-roll fabrication nonetheless leads to low performance. The selenization time and temperature are typically considered major parameters for a powder-based CZTSe film; meanwhile, the importance of the densification during [...] Read more.
Despite the improved conversion efficiency of Cu2(ZnSn)Se4 (CZTSe) solar cells, their roll-to-roll fabrication nonetheless leads to low performance. The selenization time and temperature are typically considered major parameters for a powder-based CZTSe film; meanwhile, the importance of the densification during the roll-to-roll process is often overlooked. The densification process is related to the porosity of the light-absorbing layer, where high porosity lowers cell performance. In this study, we fabricated a dense CZTSe absorber layer as a method of controlling the compression of a powder precursor (Cu1.7(Zn1.2Sn1.0)S4.0 (CZTS)) during the roll-press process. The increased particle packing density of the CZTS layer was crucial in sintering the powder layer into a dense film and preventing severe selenization of the Mo back electrode. The pressed absorber layer of the CZTSe solar cell exhibited a more uniform chemical composition determined using dynamic secondary ion mass spectrometry (SIMS). Under the AM 1.5G illumination condition, the power conversion efficiency of the pressed solar cell was 6.82%, while the unpressed one was 4.90%. Full article
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