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Functional Porous Materials for Gas Storage and Separations in Emerging Energy Technologies

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Porous Materials".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 5464

Special Issue Editor


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Guest Editor
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA
Interests: carbon and porous materials; electronic structure; x-ray spectroscopy; adsorption, separations, heterogeneous catalysts, energy storage and conversion

Special Issue Information

Dear Colleagues,

Hydrogen (H2) and methane (CH4) are emerging clean fuel alternatives to petroleum derivatives and coal. Meeting the US Department of Energy goals for efficiently storing and transporting these gases is of utmost importance for commercialization of these technologies in different sectors, i.e., energy, transportation, etc. The production of each is further tied to harmful byproduct emissions. Different types of porous materials have been extensively investigated for gas storage, and for H2 and CH4 enrichment, and have been instrumental in the successful implementation of the H2- and CH4- based economy.

In recent years, CH4 has been the subject of scrutiny, as geological resources require fracking and horizontal drilling technologies, which are associated with other environmental impacts, including the contamination of water plates. There is also the need for reducing or even completely eliminating gas leaks in geological production sites. Nonetheless, CH4 could reduce CO2 emissions by 50% or more compared to coal, and this gas could power the world for over 100 years. Methane is also the most abundant component of biogas, a largely wasted resource that is directly released into the atmosphere in farming areas; of the biodegradation of algae in coastal areas; and of organic waste in landfills. Since CH4 diffuses into the atmosphere faster than CO2, it is one of the major contributors to global warming. Moreover, natural CH4 resources contain hydrocarbons, CO2, and highly corrosive H2S impurities. In the case of H2, coal gasification and water–gas shift reactions constitute the main sources of this gas. To date, porous materials for membrane separations have been widely used to enrich H2 and CH4 feeds by separating them from generated CO, CO2, and other species. Consequently, sorbents to capture and store these gases play an ever-growing role in more sustainable energy and environmental processes. This particularly applies to H2 and CH4 production, distribution, and energy conversion steps, which further require the separation and storage of CO2 from post-combustion of CH4. These are only a few examples of technological challenges in the widespread implementation of the H2 and CH4 as cleaner fuels, which can easily complement other zero emission technologies such as solar, wind, marine, and nuclear energy.

In this Special Issue on “Functional Porous Materials for Gas Storage and Separations in Emerging Energy Technologies", researchers are invited to submit their recent works on the development of stable and selective sorbents for the enrichment of H2 and CH4 fuels and for H2S, CO, CO2, and other hydrocarbon byproducts’ capture and storage. These will be examined in detail together with materials for safe, high-capacity H2 and CH4 storage for uses in the automotive, aerospace, and energy sectors, in addition to alternative technologies for the recovery of biogas.

Dr. Pasquale Fernando Fulvio
Guest Editor

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Keywords

  • porous materials
  • functional nanocomposites
  • membranes
  • hydrogen
  • methane
  • enrichment
  • storage
  • transportation

Published Papers (2 papers)

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Research

11 pages, 2362 KiB  
Article
Design of Zeolite-Covalent Organic Frameworks for Methane Storage
by Ha Huu Do, Soo Young Kim, Quyet Van Le and Nguyen-Nguyen Pham-Tran
Materials 2020, 13(15), 3322; https://0-doi-org.brum.beds.ac.uk/10.3390/ma13153322 - 26 Jul 2020
Cited by 5 | Viewed by 2555
Abstract
A new type of zeolite-based covalent organic frameworks (ZCOFs) was designed under different topologies and linkers. In this study, the silicon atoms in zeolite structures were replaced by carbon atoms in thiophene, furan, and pyrrole linkers. Through the adoption of this strategy, 300 [...] Read more.
A new type of zeolite-based covalent organic frameworks (ZCOFs) was designed under different topologies and linkers. In this study, the silicon atoms in zeolite structures were replaced by carbon atoms in thiophene, furan, and pyrrole linkers. Through the adoption of this strategy, 300 ZCOFs structures were constructed and simulated. Overall, the specific surface area of ZCOFs is in the range of 300–3500 m2/g, whereas the pore size is distributed from 3 to 27 Å. Furthermore, the pore volume exhibits a wide range between 0.01 and 1.5 cm3/g. Screening 300 ZCOFs with the criteria towards methane storage, 11 preliminary structures were selected. In addition, the Grand Canonical Monte Carlo technique was utilized to evaluate the CH4 adsorption ability of ZCOFs in a pressure ranging from 1 to 85 bar at a temperature of 298 K. The result reveals that two ZCOF structures: JST-S 183 v/v (65–5.8 bar) and NPT-S 177 v/v (35–1 bar) are considered as potential adsorbents for methane storage. Furthermore, the thermodynamic stability of representative structures is also checked base on quantum mechanical calculations. Full article
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13 pages, 3794 KiB  
Article
Influence of the Presence of Different Alkali Cations and the Amount of Fe(CN)6 Vacancies on CO2 Adsorption on Copper Hexacyanoferrates
by Gunnar Svensson, Jekabs Grins, Daniel Eklöf, Lars Eriksson, Darius Wardecki, Clara Thoral and Loic Bodoignet
Materials 2019, 12(20), 3371; https://0-doi-org.brum.beds.ac.uk/10.3390/ma12203371 - 15 Oct 2019
Cited by 7 | Viewed by 2287
Abstract
The CO2 adsorption on various Prussian blue analogue hexacyanoferrates was evaluated by thermogravimetric analysis. Compositions of prepared phases were verified by energy-dispersive X-ray spectroscopy, infra-red spectroscopy and powder X-ray diffraction. The influence of different alkali cations in the cubic Fm3m [...] Read more.
The CO2 adsorption on various Prussian blue analogue hexacyanoferrates was evaluated by thermogravimetric analysis. Compositions of prepared phases were verified by energy-dispersive X-ray spectroscopy, infra-red spectroscopy and powder X-ray diffraction. The influence of different alkali cations in the cubic Fm3m structures was investigated for nominal compositions A2/3Cu[Fe(CN)6]2/3 with A = vacant, Li, Na, K, Rb, Cs. The Rb and Cs compounds show the highest CO2 adsorption per unit cell, ~3.3 molecules of CO2 at 20 °C and 1 bar, while in terms of mmol/g the Na compound exhibits the highest adsorption capability, ~3.8 mmol/g at 20 °C and 1 bar. The fastest adsorption/desorption is exhibited by the A-cation free compound and the Li compound. The influence of the amount of Fe(CN)6 vacancies were assessed by determining the CO2 adsorption capabilities of Cu[Fe(CN)6]1/2 (Fm3m symmetry, nominally 50% vacancies), KCu[Fe(CN)6]3/4 (Fm3m symmetry, nominally 25% vacancies), and CsCu[Fe(CN)6] (I-4m2 symmetry, nominally 0% vacancies). Higher adsorption was, as expected, shown on compounds with higher vacancy concentrations. Full article
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