Metal Nanomaterials-Based Sensors

A special issue of Micromachines (ISSN 2072-666X). This special issue belongs to the section "A:Physics".

Deadline for manuscript submissions: closed (30 November 2020) | Viewed by 4546

Special Issue Editor

Special Issue Information

Dear Colleagues,

In recent decades we have witnessed the exploitation of nanotechnology potentialities in all technological fields connected to challenges faced by human society. In particular, in the sensing field, seminal breakthroughs have just been reached and, considering the long-term vision, further others are expected. In this sense, the increasing demand worldwide poses strict requirements (low cost, ultra-high sensitivity, selectivity, etc.) concerning new functional sensing devices for the detection of gases, volatile organic compounds, biomolecules, etc. Nanotechnology has the capacity to match such requirements with increasing efficiency in a sustainable fashion. This is due to its unique capability to provide novel functional materials and devices (through control of matter at the atomic scale). In this sense, metal-based nanomaterials are acquiring a key role in the high-efficiency and smart-sensing framework by exploiting characteristic plasmonic and electrical properties matched with feasibility and biocompatibility.

This Special Issue of Micromachines aims at collecting a compilation of review articles and original research papers illustrating the latest developments in the synthesis and self-assembly of metal-based nanomaterials (such as nanocrystals, nanoparticles, thin films, nanocomposites) whose combined physical and chemical properties can be efficiently exploited for the fabrication of sensing devices with ultra-high sensitivity and selectivity. In particular, for this Special Issue, contributions dealing with synthesis and self-assembly approaches, characterization methodologies, applications of structurally and/or chemically functional-designed nanomaterials for next-generation sensing devices are welcomed. Multidisciplinary approaches crossing physical, chemical, and engineering competences are expected for full exploitation of the nanomaterial properties at the forefront of nanotechnology.

Contributions regarding metal-based nanomaterials for sensing falling within the following topics are particularly encouraged:

  • Plasmonic-based sensing;
  • Chemoresistive sensing;
  • Electrochemical sensing;
  • Combinations of different classes of nanomaterials in rationale-designed nanocomposites (organic–inorganic, metallodielectric, 0D–1D–2D hybrids, metal–organic frameworks, etc.);
  • Gas sensors;
  • Volatile organic compound sensors;
  • Biosensors;
  • Device integration;
  • Cutting-edge techniques for the quantitative characterization of morphological, structural, chemical, optical, electrical, magnetic, etc. properties of metal-based nanomaterials (advanced spectroscopies, microscopies, etc.).

Prof. Francesco Ruffino
Guest Editor

Manuscript Submission Information

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Keywords

  • plasmonic sensors
  • chemoresistive sensors
  • nanofabrication
  • metal nanostructures
  • metal-based nanocomposites

Published Papers (2 papers)

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Research

14 pages, 3848 KiB  
Article
Effect of pH and Nanoparticle Capping Agents on Cr (III) Monitoring in Water: A Kinetic Way to Control the Parameters of Ultrasensitive Environmental Detectors
by Chawki Awada and Hassan Traboulsi
Micromachines 2020, 11(12), 1045; https://doi.org/10.3390/mi11121045 - 27 Nov 2020
Cited by 4 | Viewed by 1894
Abstract
In this work, we apply surface-enhanced Raman spectroscopy (SERS) to study the kinetics of chromium Cr (III) detection in solution using EDTA and silver nanoparticles (AgNPs). We examine for the first time the effect of pH and nanoparticles’ capping agent on the kinetic [...] Read more.
In this work, we apply surface-enhanced Raman spectroscopy (SERS) to study the kinetics of chromium Cr (III) detection in solution using EDTA and silver nanoparticles (AgNPs). We examine for the first time the effect of pH and nanoparticles’ capping agent on the kinetic mechanism of Cr (III) detection using SERS temporal variations. The full width at half maximum (FWHM) and Raman shift variations show that the mechanism of detection is composed of two steps: a first one consisting of chemical coordination between Cr (III) and AgNPs that leads to exalted chemical and electromagnetic enhancement and the second one is an aggregation process with an important optical enhancement. The obtained results showed that the first step in the detection at lower pH was five times faster than in a basic medium using citrate capped silver nanoparticles (Cit-AgNPs). On the other hand, using a capping agent with dicarboxylate groups such as oxalate (Oxa-AgNPs) led to an important enhancement in SERS detection signal (more than 30 times) compared with Cit-AgNPs, although the detection kinetic’s mechanism was slower. Full article
(This article belongs to the Special Issue Metal Nanomaterials-Based Sensors)
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14 pages, 3045 KiB  
Article
Laser-Based Synthesis of Au Nanoparticles for Optical Sensing of Glyphosate: A Preliminary Study
by Antonella Laura Sortino, Maria Censabella, Gabriella Munzi, Simona Boninelli, Vittorio Privitera and Francesco Ruffino
Micromachines 2020, 11(11), 989; https://0-doi-org.brum.beds.ac.uk/10.3390/mi11110989 - 31 Oct 2020
Cited by 9 | Viewed by 2085
Abstract
Nowadays, Au nanoparticles (AuNPs) capture great interest due to their chemical stability, optical properties, and biocompatibility. The success of technologies based on the use of AuNPs implies the development of simple synthesis methods allowing, also, the fine control over their properties (shape, sizes, [...] Read more.
Nowadays, Au nanoparticles (AuNPs) capture great interest due to their chemical stability, optical properties, and biocompatibility. The success of technologies based on the use of AuNPs implies the development of simple synthesis methods allowing, also, the fine control over their properties (shape, sizes, structure). Here, we present the AuNPs fabrication by nanosecond pulsed laser ablation in citrate-solution, that has the advantage of being a simple, economic and eco-sustainable method to fabricate colloidal solutions of NPs. We characterized the stability and the absorbance of the solutions by Ultraviolet-Visible (UV-Vis) spectroscopy and the morphology of the AuNPs by Transmission Electron Microscopy. In addition, we used the AuNPs solutions as colorimetric sensor to detect the amount of glyphosate in liquid. Indeed, glyphosate is one of the most widely used herbicides which intensive use represents a risk to human health. The glyphosate presence in the colloidal AuNPs solutions determines the aggregation of the AuNPs causing the change in the color of the solution. The variation of the optical properties of the colloidal solutions versus the concentration of glyphosate is studied. Full article
(This article belongs to the Special Issue Metal Nanomaterials-Based Sensors)
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