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Synthesis and Application of Intermetallic Compounds Catalytic Materials

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Applied Chemistry".

Deadline for manuscript submissions: closed (30 March 2022) | Viewed by 4726

Special Issue Editors

State Key Laboratory of Fine Chemicals and Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
Interests: heterogeneous catalysis; intermetallic compounds in catalysis; electrosynthesis industry
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
Interests: CO2 hydrogenation; heterogeneous catalysis; in situ characterization
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues, 

Catalysis is one of the key and core technologies in chemical industry, which plays a crucial role in various fields including petroleum refining, energy conversion, environmental protection and fine chemical. According to statistics, more than 90% of today's chemical processes involve the catalytic science and technology. The development and great progress of catalytic technology largely depends on the design of new catalytic materials. Therefore, the research and development of new catalytic materials has always been one of the core contents of chemical technology innovation, and also one of the most challenging topics in the field of catalytic science and technology.

Generally, for making chemical production more energy-efficient and selective to target products in catalysis, there are some strategies to control of the bond formation in reactions. The influences of the molecular structure (steric and/or electronic effects by the substituents) and the chemical/physical structure (nature of the metal atoms, local structure and texture of the support, and electronic and geometric effects of a second metal or of surface ligands) of the catalysts have been addressed. Among these catalytic materials, intermetallic compounds with controllable electronic structures and specifically ordered atomic-level structures are promising, which are capable of creating favourable reaction environments and suitable for developing efficient catalytic systems. Recently, intermetallic compounds in catalysis as a hot topic has received growing attention, especially in selective hydrogenation, oxidation, and electrochemical energy conversion. The synthetic principles and strategies developed to obtain intermetallic compounds catalysts as well as their surface chemical analysis have aroused extensive research interest. Additionally, the structure–properties relationship of intermetallic compounds is still a mystifying barrier, which is full of challenges and has received intensive study in catalysis.

Accordingly, researches on intermetallic compounds in catalysis are welcome in this Special Issue of Molecules, which will contribute to the rapid development of new catalytic materials. This Special Issue will collect communications, articles, and reviews which are at the leading edge of our field’s emerging technology and science.

Dr. Xiao Chen
Dr. Guanghui Zhang
Guest Editors

Manuscript Submission Information

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Keywords

  • heterogeneous catalysis
  • intermetallic compound
  • catalyst design
  • geometric and electronic effects

Published Papers (2 papers)

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Research

13 pages, 4020 KiB  
Article
Nano-Sized NiO Immobilized on Au/CNT for Benzyl Alcohol Oxidation: Influences of Hybrid Structure and Interface
by Yixue Zhou, Fengxiang Shan, Sihan Yang, Jingjie Luo and Changhai Liang
Molecules 2021, 26(20), 6276; https://0-doi-org.brum.beds.ac.uk/10.3390/molecules26206276 - 16 Oct 2021
Cited by 1 | Viewed by 1767
Abstract
Tiny gold nanoparticles were successfully anchored on carbon nanotubes (CNT) with NiO decoration by a two-step synthesis. Characterizations suggested that Ni species in an oxidative state preferred to be highly dispersed on CNT. During the synthesis, in situ reduction by NaBH4 and [...] Read more.
Tiny gold nanoparticles were successfully anchored on carbon nanotubes (CNT) with NiO decoration by a two-step synthesis. Characterizations suggested that Ni species in an oxidative state preferred to be highly dispersed on CNT. During the synthesis, in situ reduction by NaBH4 and thermal treatment in oxidation atmosphere were consequently carried out, causing the formation of Au-Ni-Ox interfaces and bimetal hybrid structure depending on the Ni/Au atomic ratios. With an appropriate Ni/Au atomic ratio of 8:1, Ni atoms migrated into the sub-layers of Au particles and induced the lattice contraction of Au particles, whilst a higher Ni/Au atomic ratio led to the accumulation of NiO fractions surrounding Au particles. Both contributed to the well-defined Au-Ni-Ox interface and accelerated reaction rates. Nickel species acted as structure promoters with essential Au-Ni-Ox hybrid structure as well as the active oxygen supplier, accounting for the enhanced activity for benzyl alcohol oxidation. However, the over-layer of unsaturated gold sites easily occured under a high Ni/Au ratio, resulting in a lower reaction rate. With an Au/Ni atomic ratio of 8:1, the specific rate of AuNi8/CNT reached 185 μmol/g/s at only 50 °C in O2 at ordinary pressure. Full article
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16 pages, 5794 KiB  
Article
Ni Foam-Supported Tin Oxide Nanowall Array: An Integrated Supercapacitor Anode
by Ye Tian, Qi Wang, Zhijian Peng, Shundong Guan and Xiuli Fu
Molecules 2021, 26(15), 4517; https://0-doi-org.brum.beds.ac.uk/10.3390/molecules26154517 - 27 Jul 2021
Cited by 9 | Viewed by 2071
Abstract
A novel product consisting of a homogeneous tin oxide nanowall array with abundant oxygen deficiencies and partial Ni-Sn alloying onto a Ni foam substrate was successfully prepared using a facile solvothermal synthesis process with subsequent thermal treatment in a reductive atmosphere. Such a [...] Read more.
A novel product consisting of a homogeneous tin oxide nanowall array with abundant oxygen deficiencies and partial Ni-Sn alloying onto a Ni foam substrate was successfully prepared using a facile solvothermal synthesis process with subsequent thermal treatment in a reductive atmosphere. Such a product could be directly used as integrated anodes for supercapacitors, which showed outstanding electrochemical properties with a maximum specific capacitance of 31.50 mAh·g−1 at 0.1 A·g−1, as well as good cycling performance, with a 1.35-fold increase in capacitance after 10,000 cycles. An asymmetric supercapacitor composed of the obtained product as the anode and activated carbon as the cathode was shown to achieve a high potential window of 1.4 V. The excellent electrochemical performance of the obtained product is mainly ascribed to the hierarchical structure provided by the integrated, vertically grown nanowall array on 3D Ni foam, the existence of oxygen deficiency and the formation of Ni-Sn alloys in the nanostructures. This work provides a general strategy for preparing other high-performance metal oxide electrodes for electrochemical applications. Full article
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