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Surface Activation of Polymer Materials

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Macromolecular Chemistry".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 3985

Special Issue Editors


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Guest Editor
Institute of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, Poland
Interests: polymer materials; functional surfaces and coatings; surface and interface modification; surface characterization

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Guest Editor
Łukasiewicz Research Network-Institute for Engineering of Polymer Materials and Dyes, Maria Skłodowska-Curie 55, 87-100 Toruń, Poland
Interests: polymer materials; polymer chemistry; polymer processing; modification and research of surface; films activation
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Special Issue Information

Dear Colleagues,

In recent decades, there has been a huge interest in surface science of polymer materials. This is the result of numerous applications of these materials in the automotive, electronics, medical device, power tool, and engineering construction industries. Wherever polymer material comes into contact with another material, liquid or a gas, surface properties play a significant role. By applying appropriate techniques to modify the surface layer of polymeric materials, completely new or improved surface properties can be induced without affecting their volumetric properties. Altering the chemistry of surface by introducing chemical groups or charges on the surface or physical changes created on the surface through etching, ablation, roughening, wavy shapes, and voids formation is often referred to as the surface activation method. The surface of polymer materials can be activated by any of the physical or chemical methods like laser, plasma, flame, corona or discharge treatments, or using acid or another compound to induce reduction or oxidation reactions onto the surface of polymer materials. In that context, the current issue is open for scientific research on the molecular and atomic level of polymer properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such surface activations and their applications.

Dr. Piotr Rytlewski
Dr. Rafał Malinowski
Guest Editors

Manuscript Submission Information

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Keywords

  • Polymer materials
  • Surface activation
  • Functional surfaces and coatings
  • Surface engineering and functionalization
  • Surface and interface modification
  • Surface characterization

Published Papers (2 papers)

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Research

14 pages, 5815 KiB  
Article
Laser Activated and Electroless Metalized Polyurethane Coatings Containing Copper(II) L-Tyrosine and Glass Microspheres
by Piotr Rytlewski, Bartłomiej Jagodziński, Rafał Malinowski, Bogusław Budner, Krzysztof Moraczewski, Agnieszka Wojciechowska and Piotr Augustyn
Molecules 2021, 26(18), 5571; https://0-doi-org.brum.beds.ac.uk/10.3390/molecules26185571 - 13 Sep 2021
Cited by 3 | Viewed by 1606
Abstract
Polyurethane coatings containing copper(II) L-tyrosine and glass microspheres were laser irradiated and underwent electroless metallization. Various sizes of glass microspheres were incorporated into the polyurethane coating matrix in order to examine their effects on surface activation and electroless metallization. The surface of the [...] Read more.
Polyurethane coatings containing copper(II) L-tyrosine and glass microspheres were laser irradiated and underwent electroless metallization. Various sizes of glass microspheres were incorporated into the polyurethane coating matrix in order to examine their effects on surface activation and electroless metallization. The surface of the coatings was activated by using ArF excimer laser emitting ultraviolet radiation (λ = 193 nm) using different number of laser pulses and their fluence. The effects of surface activation and metallization were evaluated mainly based on optical and scanning electron microcopies (SEM), energy-dispersive X-ray spectroscopy (EDX) and photoelectron spectroscopy (XPS). It was found that the presence of glass microspheres enabled the reduction in copper complex content, intensified the ablation process (higher cone-like structures created) and resulted in higher content of copper metallic seeds. On the other hand, the glass microspheres concentration, which was higher for lower size microspheres, was advantageous for obtaining a fully metallized layer. Full article
(This article belongs to the Special Issue Surface Activation of Polymer Materials)
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12 pages, 4235 KiB  
Article
Development of PE/PCL Bilayer Films Modified with Casein and Aluminum Oxide
by Anita Ptiček Siročić, Ana Rešček, Zvonimir Katančić and Zlata Hrnjak-Murgić
Molecules 2021, 26(11), 3090; https://0-doi-org.brum.beds.ac.uk/10.3390/molecules26113090 - 21 May 2021
Viewed by 1809
Abstract
The studied samples were prepared from polyethylene (PE) polymer which was coated with modified polycaprolactone (PCL) film in order to obtain bilayer films. Thin PCL film was modified with casein/aluminum oxide compound to enhance vapor permeability as well as mechanical and thermal properties [...] Read more.
The studied samples were prepared from polyethylene (PE) polymer which was coated with modified polycaprolactone (PCL) film in order to obtain bilayer films. Thin PCL film was modified with casein/aluminum oxide compound to enhance vapor permeability as well as mechanical and thermal properties of PE/PCL films. Casein/aluminum oxide modifiers were used in order to achieve some functional properties of polymer film that can be used in various applications, e.g., reduction of water vapor permeability (WVTR) and good mechanical and thermal properties. Significant improvement was observed in mechanical properties, especially in tensile strength as well as in water vapor values. Samples prepared with aluminum oxide particles indicated significantly lower values up to 60%, and samples that were prepared with casein and 5% Al2O3 showed the lowest WVTR value. Full article
(This article belongs to the Special Issue Surface Activation of Polymer Materials)
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