Synthesis of Nanowires

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Nanoelectronics, Nanosensors and Devices".

Deadline for manuscript submissions: closed (30 June 2022) | Viewed by 5526

Special Issue Editors


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Guest Editor
L2n, University of Technology of Troyes, 12 Rue Marie Curie, 10004 Troyes, France
Interests: material sciences; condensed matter physics; nanomaterials; nanostructuring; nano-optics; photonics

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Guest Editor
L2n, University of Technology of Troyes, 12 Rue Marie Curie, 10004 Troyes, France
Interests: Zinc Oxide; nanomaterials; chemical synthesis; colloidal quantum dots; porous silicon; light emitting diodes

Special Issue Information

Dear Colleagues,

One-dimensional nanostructures, such as wires, tubes, belts, and rods, have been extensively studied for the past two decades due to their interesting and unique electronic, optical, thermal, mechanical, and magnetic properties. In the past decade, a tremendous amount of progress has been made in the field of one-dimensional nanostructures. However, there is still a significant need for the exploration and an improved understanding of the processes that occur during the growth of nanowires, improving our ability to assemble nanostructures into specific orientations with complex 3D geometries, as well as the engineering of the interfaces that control the transfer of energy, force, charge, and or mass across them. It is also important that these types of architectures be fabricated at a large scale, with high-throughput, and at low cost, while simultaneously maintaining the material properties at the nanoscale. An emphasis also needs to be placed on the use of low-cost, environmentally-friendly, and resource-abundant materials, while minimizing waste caused by the use of more expensive materials for processing.

This Special Issue of Nanomaterials will address the following key topics:

  1. Different types of nanowire synthesis techniques (chemical and physical methods), as well as unconventional or new emerging techniques;
  2. synthesis of NWs on new types of conventional and unconventional substrates;
  3. synthesis of complex nanowires with controlled crystalline morphologies, orientations, and surface architectures;
  4. selective or templated growth of NWs using new methods of patterning of the substrate;
  5. efficiency of the chemical synthesis method and the factors limiting the growth process;
  6. scaling behavior or strategies for large-scale growth of nanowires;
  7. controlling nanowire growth, i.e., controlling the morphology, orientation, dispersion, polarity, and intrinsic properties, and tuning the electrical and optical properties by doping;
  8. integration of the nanowires into new heterostructures combining different types of compound semiconductors;
  9. the impact of these nanomaterials on the environment;
  10. new properties of the synthesized nanowires; and
  11. applications of these nanowires for lighting, energy harvesting and storage, sensing, and biological purposes.

Prof. Dr. Gilles Lerondel
Prof. Dr. Anisha S. Gokarna
Guest Editors

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Keywords

  • Nanowires
  • heterostructures
  • chemical deposition techniques
  • physical deposition techniques
  • doping
  • patterned substrates
  • large scale growth
  • synthesis efficiency
  • multifunctionnal material
  • integration

Published Papers (4 papers)

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Research

12 pages, 4041 KiB  
Article
Nanostructuration of YAG:Ce Coatings by ZnO Nanowires: A Smart Way to Enhance Light Extraction Efficiency
by Nehed Amara, Aubry Martin, Audrey Potdevin, François Réveret, David Riassetto, Geneviève Chadeyron and Michel Langlet
Nanomaterials 2022, 12(15), 2568; https://0-doi-org.brum.beds.ac.uk/10.3390/nano12152568 - 26 Jul 2022
Cited by 1 | Viewed by 1253
Abstract
In this study, we report on the enhancement of the light extraction efficiency of sol–gel-derived Y3Al5O12:Ce3+ (YAG:Ce) coatings using ZnO nanowire (NW) arrays. The ZnO NWs were grown by hydrothermal synthesis from a ZnO seed layer [...] Read more.
In this study, we report on the enhancement of the light extraction efficiency of sol–gel-derived Y3Al5O12:Ce3+ (YAG:Ce) coatings using ZnO nanowire (NW) arrays. The ZnO NWs were grown by hydrothermal synthesis from a ZnO seed layer directly deposited on a YAG:Ce coating. Highly dense and vertically aligned ZnO NW arrays were evidenced on the top of the YAG:Ce coating by electron microscopy. A photoluminescence study showed that this original design leads to a different angular distribution of light together with an increase in emission efficiency of the YAG:Ce coating upon blue excitation, up to 60% more efficient compared to a non-structured YAG:Ce coating (without NWs). These improvements are ascribed to multi-scattering events for photons within the structure, allowing them to escape from the phosphor layer by taking optical paths different from those of the non-structured coating. This strategy of light extraction enhancement appears to be very promising, since it uses soft chemical processes and cheap ZnO NWs and is applicable to any sol–gel-derived luminescent coating. Full article
(This article belongs to the Special Issue Synthesis of Nanowires)
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20 pages, 6445 KiB  
Article
MOCVD Growth and Structural Properties of ZnS Nanowires: A Case Study of Polytypism
by Sumit Kumar, Frédéric Fossard, Gaelle Amiri, Jean-Michel Chauveau and Vincent Sallet
Nanomaterials 2022, 12(14), 2323; https://0-doi-org.brum.beds.ac.uk/10.3390/nano12142323 - 06 Jul 2022
Cited by 2 | Viewed by 1558
Abstract
Controlling the morphology, orientation, and crystal phase of semiconductor nanowires is crucial for their future applications in nanodevices. In this work, zinc sulfide (ZnS) nanowires have been grown by metalorganic chemical vapor deposition (MOCVD), using gold or gold–gallium alloys as catalyst. At first, [...] Read more.
Controlling the morphology, orientation, and crystal phase of semiconductor nanowires is crucial for their future applications in nanodevices. In this work, zinc sulfide (ZnS) nanowires have been grown by metalorganic chemical vapor deposition (MOCVD), using gold or gold–gallium alloys as catalyst. At first, basic studies on MOCVD growth regimes (mass-transport, zinc- or sulfur- rich conditions) have been carried out for ZnS thin films. Subsequently, the growth of ZnS nanowires was investigated, as a function of key parameters such as substrate temperature, S/Zn ratio, physical state and composition of the catalyst droplet, and supersaturation. A detailed analysis of the structural properties by transmission electron microscopy (TEM) is given. Depending on the growth conditions, a variety of polytypes is observed: zinc-blende (3C), wurtzite (2H) as well as an uncommon 15R crystal phase. It is demonstrated that twinning superlattices, i.e., 3C structures with periodic twin defects, can be achieved by increasing the Ga concentration of the catalyst. These experimental results are discussed in the light of growth mechanisms reported for semiconductor nanowires. Hence, in this work, the control of ZnS nanowire structural properties appears as a case study for the better understanding of polytypism in semiconductor 1D nanostructures. Full article
(This article belongs to the Special Issue Synthesis of Nanowires)
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15 pages, 4751 KiB  
Article
Enhanced Photocatalytic Activity and Photoluminescence of ZnO Nano-Wires Coupled with Aluminum Nanostructures
by Mondher Rtimi, Nour Beydoun, Artur Movsesyan, Suzanna Akil, Sergei Kostcheev, Xavier Gassmann, Mohamed Lajnef, Radhouane Chtourou and Safi Jradi
Nanomaterials 2022, 12(11), 1941; https://0-doi-org.brum.beds.ac.uk/10.3390/nano12111941 - 06 Jun 2022
Viewed by 1850
Abstract
In this study, we fabricated a hybrid plasmonic/semiconductor material by combining the chemical bath deposition of zinc oxide nanowires (ZnONWs) with the physical vapor deposition of aluminum nanostructures (AlNSs) under controlled temperature and atmosphere. The morphological and the optical properties of the ZnONWs/AlNSs [...] Read more.
In this study, we fabricated a hybrid plasmonic/semiconductor material by combining the chemical bath deposition of zinc oxide nanowires (ZnONWs) with the physical vapor deposition of aluminum nanostructures (AlNSs) under controlled temperature and atmosphere. The morphological and the optical properties of the ZnONWs/AlNSs hybrid material fabricated at different temperatures (250, 350, and 450 °C) and thicknesses (5, 7, and 9 nm) of Al layers were investigated. By adjusting the deposition and annealing parameters, it was possible to tune the size distribution of the AlNSs. The resonant coupling between the plasmonic AlNSs and ZnONWs leads to an enhanced photoluminescence response. The photocatalytic activity was studied through photodegradation under UV-light irradiation of methylene blue (MB) adsorbed at the surface of ZnO. The MB photodegradation experiment reveals that the ZnONWs covered with 7 nm aluminum film and annealed at 450 °C exhibit the highest degradation efficiency. The comparison between ZnONws and ZnONws/AlNSs shows a photoluminescence enhancement factor of 1.7 and an increase in the kinetics constant of photodegradation with a factor of 4. Full article
(This article belongs to the Special Issue Synthesis of Nanowires)
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13 pages, 1714 KiB  
Article
Implementing the Reactor Geometry in the Modeling of Chemical Bath Deposition of ZnO Nanowires
by Clément Lausecker, Bassem Salem, Xavier Baillin and Vincent Consonni
Nanomaterials 2022, 12(7), 1069; https://0-doi-org.brum.beds.ac.uk/10.3390/nano12071069 - 24 Mar 2022
Cited by 7 | Viewed by 1849
Abstract
The formation of nanowires by chemical bath deposition is of great interest for a wide variety of optoelectronic, piezoelectric, and sensing devices, from which the theoretical description of their elongation process has emerged as a critical issue. Despite its strong influence on the [...] Read more.
The formation of nanowires by chemical bath deposition is of great interest for a wide variety of optoelectronic, piezoelectric, and sensing devices, from which the theoretical description of their elongation process has emerged as a critical issue. Despite its strong influence on the nanowire growth kinetics, reactor size has typically not been taken into account in the theoretical modeling developed so far. We report a new theoretical description of the axial growth rate of nanowires in dynamic conditions based on the solution of Fick’s diffusion equations, implementing a sealed reactor of finite height as a varying parameter. The theoretical model is applied in various chemical bath deposition conditions in the case of the growth of ZnO nanowires, from which the influence of the reactor height is investigated and compared to experimental data. In particular, it is found that the use of reactor heights smaller than 2 cm significantly decreases the ZnO nanowires’ axial growth rate in typical experimental conditions due to the faster depletion of reactants. The present approach is further used predictively, showing its high potential for the design of batch reactors for a wide variety of chemical precursors and semiconductor materials in applied research and industrial production. Full article
(This article belongs to the Special Issue Synthesis of Nanowires)
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