Advanced Polymer Electrolytes

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: closed (20 August 2022) | Viewed by 6617

Special Issue Editors


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Guest Editor
Department of Chemical Engineering, National United University, Miaoli 36063, Taiwan
Interests: advanced polymer chemistry; electrochromic materials; hydrogels; LED & IC encapsulants
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Department of Chemical Engineering, National United University, Miaoli 36063, Taiwan
Interests: advanced polymer chemistry; energy storage battery materials; smart hydrogel materials
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Department of Materials Science and Engineering, National United University, Miaoli, Taiwan
Interests: advanced polymer chemistry; conductive polymer; solar cells; nanocomposites
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

This Special Issue of the journal Polymers, entitled “Advanced Polymer Electrolyte,” aims to bring together papers focused on the advanced polymer materials concerning optical or optoelectrochemical properties, ionic conductive properties and mechanical properties. These polymeric electrolyte materials mainly for energy or building applications. We aim to cover the fields of solar cell, electrochromic devices, batteries, fuel cells and sensors. Thus, we want to highlight the efforts of researchers who have contributed to recent development in those fields based on advanced polymer electrolyte as the aims of this Special Issue.

Dr. Chi-Ping Li
Prof. Dr. Shu-Ling Huang
Prof. Dr. Fang-Chi Hsu
Guest Editors

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • polymer electrolytes
  • solid-state polymer electrolytes
  • gel polymer electrolytes
  • block copolymer electrolytes
  • electrochromics
  • batteries
  • fuel cells
  • solar cells
  • electrochemical devices
  • sensors
  • actuators

Published Papers (3 papers)

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Research

13 pages, 4449 KiB  
Article
Characteristics of Water Transport of Membrane Electrolyte over Selected Temperature for Proton Exchange Membrane Fuel Cell
by Ngoc Van Trinh, Xuan Linh Nguyen, Younghyeon Kim and Sangseok Yu
Polymers 2022, 14(15), 2972; https://0-doi-org.brum.beds.ac.uk/10.3390/polym14152972 - 22 Jul 2022
Cited by 8 | Viewed by 2177
Abstract
The water contents at both the anode and cathode of PEMFCs depend on the water-transport mechanism at the membrane. The humidity at the outside layers of the membrane determines the diffusion of water through it. The operating temperatures and pressures regulate the humidity [...] Read more.
The water contents at both the anode and cathode of PEMFCs depend on the water-transport mechanism at the membrane. The humidity at the outside layers of the membrane determines the diffusion of water through it. The operating temperatures and pressures regulate the humidity conditions in the system. Because these parameters are nonlinear, the water-transport mechanism is analyzed via the difference in the water concentration on each side of the membrane. In this work, an experimental configuration is designed to investigate the diffusion mechanism of water through the membrane. A flat membrane module is tested in an isothermal test chamber to test the influence of temperature on the water-absorption and -transport characteristics of Nafion 117 and Nafion 211 membranes. A parametric study is conducted to test the water-transport mechanism at an operating pressure of 1 bar; temperatures of 30 °C, 50 °C, 70 °C and 90 °C; and a relative humidity ranging from 10% to 100%. The results indicate that the water content of Nafion 211 is higher than that of Nafion 117. The water content and diffusion coefficient are proportional to the operating temperature. In addition, the diffusion coefficient reaches its peak at conditions of 1 bar, 100% humidity, and 90 °C for both membrane types. Full article
(This article belongs to the Special Issue Advanced Polymer Electrolytes)
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15 pages, 3298 KiB  
Article
Role of Substrate Type in the Process of Polyelectrolyte Multilayer Formation
by Mia Mesić, Tin Klačić, Anže Abram, Klemen Bohinc and Davor Kovačević
Polymers 2022, 14(13), 2566; https://0-doi-org.brum.beds.ac.uk/10.3390/polym14132566 - 24 Jun 2022
Cited by 4 | Viewed by 1616
Abstract
Polyelectrolyte multilayers are coatings formed by the alternate deposition of polycations and polyanions on a charged surface. In this study we examined how the type of substrate affects a multilayer prepared from poly(allylamine hydrochloride) and poly(acrylic acid). Silicon and titanium wafers were used [...] Read more.
Polyelectrolyte multilayers are coatings formed by the alternate deposition of polycations and polyanions on a charged surface. In this study we examined how the type of substrate affects a multilayer prepared from poly(allylamine hydrochloride) and poly(acrylic acid). Silicon and titanium wafers were used as substrates. Their properties were systematically studied using ellipsometry, tensiometry, atomic force microscopy and streaming potential measurements. Multilayers were built up at pH = 7 with tetramethylammonium chloride as the background salt. The growth of films was monitored by ellipsometry, while the morphology and surface roughness were determined by atomic force microscopy. It was found that the thickness of multilayers containing 10 layers on silicon is 10 nm, whereas the thickness of the same film on titanium is three times higher. It was shown that multilayers formed on silicon display a grain-like structure, which was not the case for a film formed on titanium. Such morphological properties are also reflected in the surface roughness. Finally, it was shown that, in addition to the electrostatic interactions, the hydrophobicity of the substrate also plays an important role in the polyelectrolyte multilayer formation process and influences its thickness and properties. Full article
(This article belongs to the Special Issue Advanced Polymer Electrolytes)
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15 pages, 6046 KiB  
Article
Imidazolium-Quaternized Poly(2,6-Dimethyl-1,4-Phenylene Oxide)/Zeolitic Imidazole Framework-8 Composite Membrane as Polymer Electrolyte for Fuel-Cell Application
by Thabakgolo T. Letsau, Penny P. Govender and Phumlani F. Msomi
Polymers 2022, 14(3), 595; https://0-doi-org.brum.beds.ac.uk/10.3390/polym14030595 - 01 Feb 2022
Cited by 6 | Viewed by 2044
Abstract
Anion exchange membrane fuel cells (AEMFCs) are considered superior to their counterpart proton exchange fuel cells due to their many advantages. Both fuel cells use membranes as polymer electrolytes to improve fuel-cell properties and power output. This work evaluates a series of imidazolium-quaternized [...] Read more.
Anion exchange membrane fuel cells (AEMFCs) are considered superior to their counterpart proton exchange fuel cells due to their many advantages. Both fuel cells use membranes as polymer electrolytes to improve fuel-cell properties and power output. This work evaluates a series of imidazolium-quaternized poly(2,6-dimethyl-1,4-phenylene oxide) (ImPPO) functionalized zeolitic imidazole framework-8 (ZIF-8) (ImPPO/ZIF-8) as anion exchange membrane (AEM) electrolytes in a direct methanol alkaline fuel cell. FTIR and 1H NMR were used to confirm the successful membrane fabrication. SEM and TGA were used to study the morphological and thermal stability properties of the ImPPO/ZIF-8 membranes. The AEMs obtained in this work had contact angles ranging from 55.27–106.73°, water uptake from 9–83%, ion exchange capacity (IEC) from 1.93–3.15 mmol/g, and ion conductivity (IC) from 1.02–2.43 mS/cm. The best-performing membrane, ImPPO/3%ZIF-8, showed a water uptake of up to 35% at 80 °C, a swelling ratio of 15.1% after 72 h, IEC of 4.06 mmol/g, and IC of 1.96 mS/cm. A power density of 158.10 mW/cm2 was obtained. This makes ZIF-8 a good prospect as a filler for enhancing membrane properties. Full article
(This article belongs to the Special Issue Advanced Polymer Electrolytes)
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