Analysis and Modeling of Conversion Processes for Biomass, Coal and Other Solid Fuels to Overcome Current Issues

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Environmental and Green Processes".

Deadline for manuscript submissions: closed (31 October 2021) | Viewed by 2667

Special Issue Editors


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Guest Editor
Institute of Energy Process Engineering and Chemical Engineering, TU Bergakademie Freiberg, Fuchsmühlenweg 9, 09599 Freiberg, Germany
Interests: experimental investigation of the ash behavior of biomass and residues for co-use with coal or mono-use; thermochemical modeling of slag phases; ash melting behavior; build-up and slag-induced corrosion of lining materials in high-temperature processes
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Department of Heat Engineering and Environment Protection, Faculty of Metals Engineering and Industrial Computer Science, AGH University of Krakow, 30-059 Krakow, Poland
Interests: thermochemical conversion (pyrolysis and gasification) of biomass and municipal solid waste in accordance with the circular economy concept (e.g., modification and application of biochar); kinetics and thermodynamic calulations; problems related to the transformation of the mineral phase of fuels and waste (high-temperature corrosion, agglomeration, slagging, and ash depostion)
Special Issues, Collections and Topics in MDPI journals

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Department of Chemical and Biochemical Engineering, Technical University of Denmark, P. Søltofts Plads, DTU Building 229, DK-2800 Lyngby, Denmark
Interests: extensive experience on fuel characterization incl. advanced fuel analysis (XRD; SEM; STA; TOF-SIMS etc.); ash and deposit formation; release of ash-forming elements from fuels; build-up and shedding of deposits; high-temperature corrosion in boilers fired with coal; biomass and waste; use of additives; cement clinker burning; reuse of ash as fertilizer; mineral processing and ore refinery (e.g. Cu and Al production); trace element transformation and partitioning in thermal fuel conversion. expert on high-temperature global equilibrium analysis of inorganic metal/ash chemistry

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Guest Editor
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
Interests: biomass; coal and waste conversion by pyrolysis and gasification; ash chemistry of biomass and coal

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Guest Editor
Dean of Chemical Engineering Department, Heze University, Heze, China
Interests: coal ash chemistry; conversion of coal, biomass and sludge; gas purification

Special Issue Information

Dear Colleagues,

Thermochemical conversion processes, such as combustion, gasification, and pyrolysis, of biomasses and other solid fuels are always determined by their ash behavior. Ash-related effects of agglomeration, fouling, sintering, slagging, catalytic ash components, etc. will strongly affect the process design and appropriate parameters. The ongoing trend of the substitution of fossil fuels by renewable and secondary ones has to consider completely different ash systems. Ashes of biomasses and other secondary carbon resources typically contain higher contents of K, P, Ca, Mg, and Cl compared to fossil ones and thus tend to form eutectic systems. The process-related ash behavior of solid fuels is strongly affected by differences in origin by authigenic, detrital, and technogenic minerals in the fuels. Key factors of ash behavior in industrial processes are inter alia the selective gas phase transfer of ash species (e.g., heavy metals), fouling, sintering, slagging, agglomeration, catalytic effects, mineral formation and transformation, ash fusion, and slag viscosity. Due to the requirements of an increased efficiency in energy and resources, process optimization uses more and more frequently modeling tools, e.g., thermochemical or neuronal networks, to simulate and optimize ash behavior. In addition to that, processes for recovery of valuable ash components have to be developed to enhance efficiency. This Special Issue assembles papers covering recent approaches to improved process control based on a complementary understanding of ash behavior from the initial fuel up to the high temperature range by various measurement and modeling tools.

Prof. Dr. Markus Reinmöller
Prof. Dr. Aneta Magdziarz
Dr. Flemming Jappe Frandsen
Prof. Dr. Jin Bai
Prof. Dr. Fenghai Li
Guest Editors

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Keywords

  • Biomass and secondary carbon resources
  • Thermochemical conversion processes
  • Fouling, sintering, slagging, and agglomeration
  • Selective gas phase transfer
  • Ash composition
  • Mineral phases
  • Ash fusion
  • Slag viscosity
  • Thermodynamic modeling
  • Recovery of valuable ash components (e.g., phosphor)
  • Process control and optimization

Published Papers (1 paper)

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Research

14 pages, 3314 KiB  
Article
Interaction between Coal and Biomass during Co-Gasification: A Perspective Based on the Separation of Blended Char
by Xiaoming Li, Jingxia He, Mengjie Liu, Jin Bai, Zongqing Bai and Wen Li
Processes 2022, 10(2), 286; https://0-doi-org.brum.beds.ac.uk/10.3390/pr10020286 - 31 Jan 2022
Cited by 10 | Viewed by 2035
Abstract
Co-gasification of coal and biomass is an important way to reduce the consumption of fossil fuels and achieve the efficient utilization of biomass resources. Two kinds of biomass containing corn straw (CS) and poplar sawdust (PS) were blended with different coal. Then, the [...] Read more.
Co-gasification of coal and biomass is an important way to reduce the consumption of fossil fuels and achieve the efficient utilization of biomass resources. Two kinds of biomass containing corn straw (CS) and poplar sawdust (PS) were blended with different coal. Then, the coal char was separated from the blended char after co-pyrolysis based on the difference in particle size. The structural properties, including alkali and alkaline earth metals (AAEMs), microcrystalline structures, and molecular structures of the char samples were analyzed. Gasification reactivity of the char was determined by thermogravimetric analyzer (TGA). Results indicated that K and Mg contents in biomass evaporated easily and deposited on coal char, resulting in the increase in those in coal char during co-pyrolysis, and then the AAEMs contents in coal char were determined by the AAEM species and contents in biomass. Meanwhile, the inhibition effect on the graphitization degree of coal char increased with increasing blend ratio. Likewise, the inhibition effect of CS was higher than that of PS at the same blend ratio. The catalytic activity of inorganic mineral played a much more important role in predicting gasification reactivity than graphitization degree, and then the combination of alkali index and stacking layer number was proposed to better predict the reactivity of coal char. Full article
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