Hydrocarbon-based Ion Exchange Membranes for Electrochemical Devices

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Materials Processes".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 4273

Special Issue Editor


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Guest Editor
Chemical Engineering Department, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden
Interests: redox flow battery (RFB); ion exchange membranes (IEMs); solar cells; solar redox flow batteries

Special Issue Information

Dear Colleagues,

Nafion is considered the benchmark cation-exchange membrane (CEM) for most electrochemical devices, such as flow batteries, water electrolysis, and fuel cells. It shows excellent chemical and mechanical stability (Teflon backbone) and provides high ion conductivity. On the other hand, the high price (300–500 $/m2) and the low ion selectivity of Nafion have turned researchers’ attention to develop alternative ion-exchange membranes.

To achieve superior properties but at a lower total price than Nafion, different non-fluorinated hydrocarbon-based anion- and cation-exchange membranes have been developed. For instance, aliphatic (e.g., polyethylene), aromatic (e.g., polysulfone-based), and poly(phenyl)-based backbones carrying various cations, including ammonium, pyridinium, and imidazolium, have been studied. Therefore, getting improved and more economical ion-exchange membranes for electrochemical devices is crucial for the technology to be competitive.

This Special Issue aims to cover hydrocarbon-based ion-exchange membranes for electrochemical devices, including redox flow batteries, water electrolysis, and fuel cells, with regards to:

  • Membrane materials;
  • Preparation and characterization;
  • Application and processes;
  • Simulation and modeling.

Both original research and review papers are welcome.

Dr. Amirreza Khataee
Guest Editor

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Keywords

  • Hydrocarbon-based ion-exchange membranes
  • Non-fluorinated ion-exchange membranes
  • Energy storage
  • Redox flow battery
  • Water electrolysis
  • Fuel cell
  • Electrochemical device

Published Papers (1 paper)

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Research

14 pages, 1951 KiB  
Article
Vanadium Redox Flow Battery Using Aemion Anion Exchange Membranes
by Elias Lallo, Amirreza Khataee and Rakel Wreland Lindström
Processes 2022, 10(2), 270; https://0-doi-org.brum.beds.ac.uk/10.3390/pr10020270 - 29 Jan 2022
Cited by 7 | Viewed by 3530
Abstract
The vanadium redox flow battery (VRFB) is a promising and commercially available technology that poses advantageous features for stationary energy storage. A key component of the VRFB in terms of cost and system efficiency is the membrane. In recent years, anion exchange membranes [...] Read more.
The vanadium redox flow battery (VRFB) is a promising and commercially available technology that poses advantageous features for stationary energy storage. A key component of the VRFB in terms of cost and system efficiency is the membrane. In recent years, anion exchange membranes (AEMs) have gained interest in VRFB research as they in general exhibit lower vanadium crossover due to a more substantial Donnan exclusion effect. In this study, a low-resistance flow cell was developed and the electrochemical performance of Aemion™ anion exchange membranes AF1-HNN5-50-X, AF1-HNN8-50-X and AF1-ENN8-50-X were compared against commonly used cation exchange membranes, Nafion® 211 and 212. The VRFB using AF1-ENN8-50-X exhibited superior performance versus Nafion® 212 regarding cycling efficiency and rate performance. However, relatively high and comparable capacity losses were observed using both membranes. NMR analysis showed no sign of chemical degradation for AF1-ENN8-50-X by immersion in VO2+ solution for 800 h. Although Aemion™ AEMs showed good chemical and electrochemical performance, considerable electrolyte crossover was observed due to high water uptake. Full article
(This article belongs to the Special Issue Hydrocarbon-based Ion Exchange Membranes for Electrochemical Devices)
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