The transportation infrastructure for petroleum products contains complex pipeline systems, developed on a global scale and totaling investments of hundreds of millions of dollars. The operation and maintenance of these systems have to be performed in relation to the analysis of incidents of various types, which take place in various areas of the world. The present paper aims to analyze in as much detail as possible, from a statistical point of view, the case of the pipeline system for petroleum products in Romania in order to streamline the operation of this critical infrastructure for Romania. Through the statistical tools, we established the hierarchies of the causes of the analyzed incidents, weights of the effects generated by these sources of accidents, and correlations between various parameters, in order to create a useful plan of measures and actions in the efficient operation of the pipeline system. The importance and topicality of the subject is also demonstrated by the major negative impact of the accidents in this sector, through product leaks from pipes in the soil and in watercourses, which generate significant pollution values, thus influencing the balance of the environment. Full article

The environmental issue has become a global problem that needs to be examined frequently, motivating researchers to investigate it. Thus, the present study has investigated the asymmetric impact of globalization, economic growth and natural resources on the ecological footprint in the presence of environmental Kuznets curve (EKC) in Thailand. The study has used annual time series data from 1970 to 2018. The study applied a novel method of nonlinear autoregressive distributive lag (ARDL). In particular, the current study has investigated the effect of positive and negative shocks on the independent variable on the dependent variable. The findings have confirmed that the effect of globalization and natural resources are significant and nonlinear. However, the effect of negative shocks of globalization and natural resources is more dominant on the ecological footprint in Thailand than the positive shocks of both variables. Moreover, the present study has also tested the presence of EKC in Thailand, and the findings confirm the presence of an inverted U-shape curve in the Thailand economy. Full article

This paper presents an alternative way to maximize the utilization of palm waste by implementing a green approach to modify lignocellulosic materials into a highly crystalline biographite. A bio-graphite structure was successfully synthesized by converting lignocellulosic materials via a simple method using palm kernel shell (PKS) as a carbon precursor. This involved the direct impregnation of a catalyst into raw material followed by a thermal treatment. The structural transformation of the carbon was observed to be significantly altered by employing different types of catalysts and varying thermal treatment temperatures. Both XRD and Raman spectroscopy confirmed that the microstructural alteration occurred in the carbon structure of the sample prepared at 800 and 1000 °C using iron, nickel or the hybrid of iron-nickel catalysts. The XRD pattern revealed a high degree of graphitization for the sample prepared at 1000 °C, and it was evident that iron was the most active graphitization catalyst. The presence of an intensified peak was observed at 2θ = 26.5°, reflecting the formation of a highly ordered graphitic structure as a result of the interaction between the iron catalyst and the thermal treatment process at 1000 °C. The XRD observation was further supported by the Raman spectrum in which PKS-Fe1000 showed a lower defect structure associated with the presence of a significant amount of graphitic structure, as a low value of (I_d/I_g) ratio was reported. An HRTEM image showed a well-defined lattice fringe seen on the structure for PKS-Fe1000; meanwhile, a disordered microstructure was observed for the control sample, indicating that successful structural modification was achieved with the aid of the catalyst. Further analysis from BET found that the PKS-Fe1000 developed a surface area of 202.932 m2/g with a pore volume of 0.208 cm3/g. An overall successful modification from palm waste into graphitic material was achieved. Thus, this study will help those involved in waste management to evaluate the possibility of a sustainable process for the generation of graphite material from palm waste. It can be concluded that palm waste is a potential source of production for graphite material through the adoption of the proposed waste management process. Full article

The mining industry plays a significant role in economic growth and development. Coal is a viable renewable energy source with 185.175 billion deposits in Thar, which has not been deeply explored. Although coal is an energy source and contributes to economic development, it puts pressure on environmental sustainability. The current study investigates Sindh Engro coal mining’s impact on environmental sustainability and human needs and interest. The Folchi and Phillips Environmental Sustainability Mathematics models are employed to measure environmental sustainability. The research findings demonstrated that Sindh Engro coal mining is potentially unsustainable for the environment. The toxic gases (methane, carbon dioxide, sulfur, etc.) are released during operational activities. The four significant environment spheres (atmosphere, hydrosphere, biosphere, and lithosphere) are negatively influenced by Thar coal mining. The second part of the analysis results shows that human needs and interests have a positive and significant relationship except for human health and safety with Sindh Engro coal mining. Environmental pollution can be controlled by utilizing environmentally friendly coal mining operations and technologies. Plantation and ecological normalization can protect the species, flora, and fauna of the Thar Desert. The government of Pakistan and the provincial government of Sind should strictly check the adaptation of environmental standards. Furthermore, the researchers should explore the environmental issues and solutions so that coal mining becomes a cost-efficient and environmental-friendly energy source in Pakistan. Full article

The study investigates the Romanian entrepreneurial education training program emphasizing the secondary education student entrepreneurial intents included in technical and professional Vocational Education Training (VET) programs, in order to identify its role in increasing student intention in the process of choosing a career as an entrepreneur among graduates of the vocational and technical Romanian education system. The study research methodology was based on the interpretation of two questionnaires consisting of 23 questions, which were applied to a population of 253 and 159 respondents. The survey period was conducted between 2019 and 2020. The respondents were students from the vocational and technical education system in Romania, mostly from the Central Region of Romania, but the results of the study could be extended to the entire Romanian education system. The data were processed using SPSS software, and the results of the study revealed direct, positive, and significant links between psychological and behavioral traits and entrepreneurial intentions of the student surveyed, moderated by the entrepreneurial education acquired through the school curriculum. These results could also be the basis for developing future policies and programs to encourage entrepreneurial behavior, especially for secondary education students from the Romanian education system, specifically on pre-university education. Full article

This paper presents a part of the study referring to exploring Energy Recovery from Municipal Solid Waste in Maramures County. In order to analyze the possibility of energetic recovery of municipal solid waste (MSW), data referring to the management system of MSW from Maramures county were cumulated and processed in a first stage in order to estimate the quantity of municipal solid waste and its composition, which might be recovered energetically. In the next stage, samples of municipal solid waste were collected from landfills, which were submitted to specific processing and analyses. The experimental data were processed and in the end the energy potential of municipal solid waste from Maramures county was found. This study will help stakeholders and those involved in waste management to assess the possibility of energy recovery. The analysis of the study concluded that municipal solid waste in Maramures County is a potential source of renewable energy. Full article