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Carbon Nanotube Yarn-Based Sensors

A special issue of Sensors (ISSN 1424-8220). This special issue belongs to the section "Physical Sensors".

Deadline for manuscript submissions: closed (31 March 2020) | Viewed by 8491

Special Issue Editor


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Guest Editor
Department of Mechanical Engineering, The Catholic University of America, Washington, DC 20064, USA
Interests: experimental stress mechanics; polymeric composite materials; carbon nanotube fibers; integrated and distributed structural health monitoring in composite materials; piezoresistive sensors
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Special Issue Information

Dear Colleagues,

Carbon nanotube (CNT) yarns or fibers are piezoresistive continuous structures composed of several thousand carbon nanotubes in their cross sections that can be twisted, densified, and further tailored to serve as sensors. Due to their microscale dimensions, they are amenable to integration in materials, and especially in fiber reinforced polymeric composite materials. The proofs of concept to detect damage and measure distributed strain in laminated polymeric composite materials using integrated CNT yarns are already available. Additional concepts of standalone or integrated piezoresistive strain gauges and other sensing mechanisms to monitor temperature or detect chemicals are also being explored for the CNT yarns. This Special Issue focuses on papers that include experimental, modeling, or theoretical studies about the fabrication and characterization of CNT yarns and their use as sensors to monitor the health of structures or sensing in aerospace, mechanical, civil, or biomedical applications. Of special interest are studies on the piezoresistive response of the CNT yarns and the effect of their structure, geometry, and loading parameters on that response. The main sensing mechanisms of the CNT yarns are based on their piezoresistive response, but piezoimpedance or other mechanisms that may be tapped for sensing are also of interest. The papers of this Special Issue may contribute to realize integrated, distributed, and real-time sensing using CNT yarns and lead to robust and simple health monitoring techniques and he tmaintenance of structures, components, or devices.

Prof. Dr. Jandro Abot
Guest Editor

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Published Papers (2 papers)

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17 pages, 4020 KiB  
Article
Electrical Resistance Sensing of Epoxy Curing Using an Embedded Carbon Nanotube Yarn
by Omar Rodríguez-Uicab, Jandro L. Abot and Francis Avilés
Sensors 2020, 20(11), 3230; https://0-doi-org.brum.beds.ac.uk/10.3390/s20113230 - 05 Jun 2020
Cited by 11 | Viewed by 3326
Abstract
Curing effects were investigated by using the electrical response of a single carbon nanotube yarn (CNTY) embedded in an epoxy resin during the polymerization process. Two epoxy resins of different viscosities and curing temperatures were investigated, varying also the concentration of the curing [...] Read more.
Curing effects were investigated by using the electrical response of a single carbon nanotube yarn (CNTY) embedded in an epoxy resin during the polymerization process. Two epoxy resins of different viscosities and curing temperatures were investigated, varying also the concentration of the curing agent. It is shown that the kinetics of resin curing can be followed by using the electrical response of an individual CNTY embedded in the resin. The electrical resistance of an embedded CNTY increased (~9%) after resin curing for an epoxy resin cured at 130 °C with viscosity of ~59 cP at the pouring/curing temperature (“Epon 862”), while it decreased (~ −9%) for a different epoxy cured at 60 °C, whose viscosity is about double at the corresponding curing temperature. Lowering the curing temperature from 60 °C to room temperature caused slower and smoother changes of electrical resistance over time and smaller (positive) residual resistance. Increasing the concentration of the curing agent caused a faster curing kinetics and, consequently, more abrupt changes of electrical resistance over time, with negative residual electrical resistance. Therefore, the resin viscosity and curing kinetics play a paramount role in the CNTY wicking, wetting and resin infiltration processes, which ultimately govern the electrical response of the CNTY immersed into epoxy. Full article
(This article belongs to the Special Issue Carbon Nanotube Yarn-Based Sensors)
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13 pages, 1541 KiB  
Article
Carbon Nanotube Yarn Microelectrodes Promote High Temporal Measurements of Serotonin Using Fast Scan Cyclic Voltammetry
by Alexander Mendoza, Thomas Asrat, Favian Liu, Pauline Wonnenberg and Alexander G. Zestos
Sensors 2020, 20(4), 1173; https://0-doi-org.brum.beds.ac.uk/10.3390/s20041173 - 20 Feb 2020
Cited by 31 | Viewed by 4418
Abstract
Carbon fiber-microelectrodes (CFMEs) have been the standard for neurotransmitter detection for over forty years. However, in recent years, there have been many advances of utilizing alternative nanomaterials for neurotransmitter detection with fast scan cyclic voltammetry (FSCV). Recently, carbon nanotube (CNT) yarns have been [...] Read more.
Carbon fiber-microelectrodes (CFMEs) have been the standard for neurotransmitter detection for over forty years. However, in recent years, there have been many advances of utilizing alternative nanomaterials for neurotransmitter detection with fast scan cyclic voltammetry (FSCV). Recently, carbon nanotube (CNT) yarns have been developed as the working electrode materials for neurotransmitter sensing capabilities with fast scan cyclic voltammetry. Carbon nanotubes are ideal for neurotransmitter detection because they have higher aspect ratios enabling monoamine adsorption and lower limits of detection, faster electron transfer kinetics, and a resistance to surface fouling. Several methods to modify CFMEs with CNTs have resulted in increases in sensitivity, but have also increased noise and led to irreproducible results. In this study, we utilize commercially available CNT-yarns to make microelectrodes as enhanced neurotransmitter sensors for neurotransmitters such as serotonin. CNT-yarn microelectrodes have significantly higher sensitivities (peak oxidative currents of the cyclic voltammograms) than CFMEs and faster electron transfer kinetics as measured by peak separation (ΔEP) values. Moreover, both serotonin and dopamine are adsorption controlled to the surface of the electrode as measured by scan rate and concentration experiments. CNT yarn microelectrodes also resisted surface fouling of serotonin onto the surface of the electrode over thirty minutes and had a wave application frequency independent response to sensitivity at the surface of the electrode. Full article
(This article belongs to the Special Issue Carbon Nanotube Yarn-Based Sensors)
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