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Nanomaterial for Gas Sensing Application

A special issue of Sensors (ISSN 1424-8220). This special issue belongs to the section "Sensor Materials".

Deadline for manuscript submissions: closed (28 February 2023) | Viewed by 7261

Special Issue Editors


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Guest Editor
Department of Electronic, Electric and Automatic Engineering (DEEEA), Electrical, Engineering and Computer Science Faculty (ETSE), Universitat Rovira i Virgili, 43003 Tarragona, Spain
Interests: semiconductors; metal oxides; gas sensors; functionalization; decoration; nanomaterials; nanocomposites; nanostructures; heterojunction; toxic gases
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Guest Editor
Department of Electronic, Electric and Automatic Engineering(DEEEA), Electrical, Engineering and Computer Science Faculty (ETSE), Rovira i Virgili University, 43003 Tarragona, Spain
Interests: chemoresistive gas sensors; metal oxides; nanostructures; aerosol assisted CVD; gas sensing mechanisms; material caracterisations; transdermal detection via gas sensors; pattern recognition; artificial sensing systems based nanomaterials; temperature modulation; feature selection

Special Issue Information

Dear Colleagues,

In recent decades, gas sensors have triggered the attention of many researchers and scientists, owing to their widespread application in different fields, for example, environmental monitoring, automotive production, chemical and pharmaceutical industries, medical diagnosis, etc. They are well-known by their small size, low cost, easy manufacture and a wide spectrum of detectable gases. With the emergence of nanotechnologies, nanomaterials (compounds with at least one external dimension between 1 nm and 100 nm) have become suitable candidates for gas sensing applications. They possess unique physical and chemical properties (such as high surface-to-volume ratio, quantum confinement effects, etc.) that promote sensor performances (stability, sensitivity, selectivity). Among these nanomaterials, we can cite metal oxide nanomaterials, which are characterized by their reliability in detecting various toxic gases with enough sensitivity and good reproducibility. However, they also suffer from some drawbacks that influence their usability, such as lack of selectivity and high working temperature. These shortcomings have opened various pathways of innovative research—e.g., metal/metal oxides functionalization, nanocomposites and so forth. Transition metal dichalcogenide (TMD) nanomaterials have also sparked the interest of scientists in the field of gas sensors, especially in the development of high-performance room-temperature sensors for detection of toxic gases at very low levels. They consist of metal atomic layers (such as Mo, W, Hf, Ti, Zr, V, Nb, Ta, Re, etc.) between two chalcogen atomic layers (S, Se or Te), and then these multiple trilayers are stacked on top of one another by van der Waals interactions. They have a direct band gap and large specific surface area due to sheet-like structures, thus bestowing the sensors with improved sensitivity, selectivity and low power consumption. This Special Issue will highlight the recent developments in gas sensors based either on metal oxides or transition metal dichalcogenides nanomaterials that show promising results in terms of sensitivity, selectivity, humidity cross sensitivity and low temperature detection.

Dr. Annanouch Fatima Ezahra
Dr. Zouhair Haddi
Guest Editors

Manuscript Submission Information

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Keywords

  • nanomaterials
  • gas sensors
  • gas sensor array
  • metal oxides
  • transition metal dichalcogenides
  • nanocomposites
  • environmental monitoring
  • selectivity

Published Papers (3 papers)

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Research

14 pages, 3007 KiB  
Article
Dysprosium Doped Zinc Oxide for NO2 Gas Sensing
by Ghada El Fidha, Nabila Bitri, Sarra Mahjoubi, Fatma Chaabouni, Eduard Llobet and Juan Casanova-Chafer
Sensors 2022, 22(14), 5173; https://0-doi-org.brum.beds.ac.uk/10.3390/s22145173 - 10 Jul 2022
Cited by 3 | Viewed by 1527
Abstract
Pure and dysprosium-loaded ZnO films were grown by radio-frequency magnetron sputtering. The films were characterized using a wide variety of morphological, compositional, optical, and electrical techniques. The crystalline structure, surface homogeneity, and bandgap energies were studied in detail for the developed nanocomposites. The [...] Read more.
Pure and dysprosium-loaded ZnO films were grown by radio-frequency magnetron sputtering. The films were characterized using a wide variety of morphological, compositional, optical, and electrical techniques. The crystalline structure, surface homogeneity, and bandgap energies were studied in detail for the developed nanocomposites. The properties of pure and dysprosium-doped ZnO thin films were investigated to detect nitrogen dioxide (NO2) at the ppb range. In particular, ZnO sensors doped with rare-earth materials have been demonstrated as a feasible strategy to improve the sensitivity in comparison to their pure ZnO counterparts. In addition, the sensing performance was studied and discussed under dry and humid environments, revealing noteworthy stability and reliability under different experimental conditions. In this perspective, additional gaseous compounds such as ammonia and ethanol were measured, resulting in extremely low sensing responses. Therefore, the gas-sensing mechanisms were discussed in detail to better understand the NO2 selectivity given by the Dy-doped ZnO layer. Full article
(This article belongs to the Special Issue Nanomaterial for Gas Sensing Application)
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13 pages, 5179 KiB  
Article
Embedded Transdermal Alcohol Detection via a Finger Using SnO2 Gas Sensors
by Fatima Ezahra Annanouch, Virginie Martini, Tomas Fiorido, Bruno Lawson, Khalifa Aguir and Marc Bendahan
Sensors 2021, 21(20), 6852; https://0-doi-org.brum.beds.ac.uk/10.3390/s21206852 - 15 Oct 2021
Cited by 5 | Viewed by 2570
Abstract
In this paper, we report the fabrication and characterization of a portable transdermal alcohol sensing device via a human finger, using tin dioxide (SnO2) chemoresistive gas sensors. Compared to conventional detectors, this non-invasive technique allowed us the continuous monitoring of alcohol [...] Read more.
In this paper, we report the fabrication and characterization of a portable transdermal alcohol sensing device via a human finger, using tin dioxide (SnO2) chemoresistive gas sensors. Compared to conventional detectors, this non-invasive technique allowed us the continuous monitoring of alcohol with low cost and simple fabrication process. The sensing layers used in this work were fabricated by using the reactive radio frequency (RF) magnetron sputtering technique. Their structure and morphology were investigated by means of X-ray spectroscopy (XRD) and scanning electron microscopy (SEM), respectively. The results indicated that the annealing time has an important impact on the sensor sensitivity. Before performing the transdermal measurements, the sensors were exposed to a wide range of ethanol concentrations and the results displayed good responses with high sensitivity, stability, and a rapid detection time. Moreover, against high relative humidity (50% and 70%), the sensors remained resistant by showing a slight change in their gas sensing performances. A volunteer (an adult researcher from our volunteer group) drank 50 mL of tequila in order to realize the transdermal alcohol monitoring. Fifteen minutes later, the volunteer’s skin started to evacuate alcohol and the sensor resistance began to decline. Simultaneously, breath alcohol measurements were attained using a DRAGER 6820 certified breathalyzer. The results demonstrated a clear correlation between the alcohol concentration in the blood, breath, and via perspiration, which validated the embedded transdermal alcohol device reported in this work. Full article
(This article belongs to the Special Issue Nanomaterial for Gas Sensing Application)
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13 pages, 2884 KiB  
Article
Tungsten Disulfide Nanotube-Modified Conductive Paper-Based Chemiresistive Sensor for the Application in Volatile Organic Compounds’ Detection
by Song-Jeng Huang, Philip Nathaniel Immanuel, Yi-Kuang Yen, Ching-Lung Yen, Chi-En Tseng, Guan-Ting Lin, Che-Kuan Lin and Zhong-Xuan Huang
Sensors 2021, 21(18), 6121; https://0-doi-org.brum.beds.ac.uk/10.3390/s21186121 - 12 Sep 2021
Cited by 2 | Viewed by 2421
Abstract
Toxic and nontoxic volatile organic compound (VOC) gases are emitted into the atmosphere from certain solids and liquids as a consequence of wastage and some common daily activities. Inhalation of toxic VOCs has an adverse effect on human health, so it is necessary [...] Read more.
Toxic and nontoxic volatile organic compound (VOC) gases are emitted into the atmosphere from certain solids and liquids as a consequence of wastage and some common daily activities. Inhalation of toxic VOCs has an adverse effect on human health, so it is necessary to monitor their concentration in the atmosphere. In this work, we report on the fabrication of inorganic nanotube (INT)-tungsten disulfide, paper-based graphene–PEDOT:PSS sheet and WS2 nanotube-modified conductive paper-based chemiresistors for VOC gas sensing. The WS2 nanotubes were fabricated by a two-step reaction, that is oxide reduction and sulfurization, carried out at 900 °C. The synthesized nanotubes were characterized by FE-SEM, EDS, XRD, Raman spectroscopy, and TEM. The synthesized nanotubes were 206–267 nm in diameter. The FE-SEM results show the length of the nanotubes to be 4.5–8 µm. The graphene–PEDOT:PSS hybrid conductive paper sheet was fabricated by a continuous coating process. Then, WS2 nanotubes were drop-cast onto conductive paper for fabrication of the chemiresistors. The feasibility and sensitivity of the WS2 nanotube-modified paper-based chemiresistor were tested in four VOC gases at different concentrations at room temperature (RT). Experimental results show the proposed sensor to be more sensitive to butanol gas when the concentration ranges from 50 to 1000 ppm. The limit of detection (LOD) of this chemiresistor for butanol gas was 44.92 ppm. The WS2 nanotube-modified paper-based chemiresistor exhibits good potential as a VOC sensor with the advantages of flexibility, easy fabrication, and low fabrication cost. Full article
(This article belongs to the Special Issue Nanomaterial for Gas Sensing Application)
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