sensors-logo

Journal Browser

Journal Browser

Graphene Based Chemical Sensors

A special issue of Sensors (ISSN 1424-8220). This special issue belongs to the section "Chemical Sensors".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 25617

Special Issue Editors

Nanosensors and Intelligent System group (NoySI), Instituto de Tecnologías Físicas y de la Información ITEFI-CSIC, 28006 Madrid, Spain
Interests: chemical sensors; nanotechnology; nanomaterials (graphene, carbon nanotubes, 1D metal-oxide, etc.); sensor networks; air quality; electronic noses
Nanosensors and Intelligent System group (NoySI), Instituto de Tecnologías Físicas y de la Información ITEFI-CSIC, 28006 Madrid, Spain
Interests: chemical sensors; nanotechnology; graphene; sensor networks; air quality; electronic noses
Special Issues, Collections and Topics in MDPI journals
Italian National Agency for New Technologies, Energy and Sustainable Economic Development (ENEA), Portici (Naples), Italy
Interests: graphene-based materials; nanocomposite; chemical sensors; Raman spectroscopy; optoelectronic devices

Special Issue Information

Dear Colleagues,

Graphene has become one of the most studied two-dimensional (2D) materials due to its exceptional properties, such as high conductivity, high carrier mobility, and high surface area. These properties make graphene and its related materials (graphene oxide and reduced graphene oxide) excellent candidates for chemical sensing. The great advantage of graphene and other 2D materials is that they can be easily doped with catalytic materials that can improve the interactions on specific analytes (gases, ions, etc.) and thereby improve the selectivity of the sensor.

This Special Issue aims to publish original research papers, as well as review articles, with a focus on chemical sensors based on different sensing techniques and incorporating graphene-based materials. It also includes their applications in several fields, such as environmental, eHealth, food or automotive.

Dr. Isabel Sayago
Dr. José Pedro Santos
Dr. Tiziana Polichetti
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Sensors is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Graphene
  • Graphene derivatives (graphene oxide, graphene quantum dots, reduced graphene oxide)
  • Graphene-based nanocomposites
  • Chemical sensors (resistive, electrochemical, optical, mass sensors, etc..)
  • Applications (environmental, eHealth, food, automotive, etc.)

Published Papers (7 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

Jump to: Review

9 pages, 49366 KiB  
Communication
Effect of GNWs/NiO-WO3/GNWs Heterostructure for NO2 Gas Sensing at Room Temperature
by Seokhun Kwon, Seokwon Lee, Joouk Kim, Chulmin Park, Hosung Jung, Hyungchul Kim, Chulsoo Kim and Hyunil Kang
Sensors 2022, 22(2), 626; https://0-doi-org.brum.beds.ac.uk/10.3390/s22020626 - 14 Jan 2022
Cited by 2 | Viewed by 1578
Abstract
Recently, as air pollution and particulate matter worsen, the importance of a platform that can monitor the air environment is emerging. Especially, among air pollutants, nitrogen dioxide (NO2) is a toxic gas that can not only generate secondary particulate matter, but [...] Read more.
Recently, as air pollution and particulate matter worsen, the importance of a platform that can monitor the air environment is emerging. Especially, among air pollutants, nitrogen dioxide (NO2) is a toxic gas that can not only generate secondary particulate matter, but can also derive numerous toxic gases. To detect such NO2 gas at low concentration, we fabricated a GNWs/NiO-WO3/GNWs heterostructure-based gas sensor using microwave plasma-enhanced chemical vapor deposition (MPECVD) and sputter, and we confirmed the NO2 detection characteristics between 10 and 50 ppm at room temperature. The morphology and carbon lattice characteristics of the sensing layer were investigated using field emission scanning electron microscopy (FESEM) and Raman spectroscopy. In the gas detection measurement, the resistance negative change according to the NO2 gas concentration was recorded. Moreover, it reacted even at low concentrations such as 5–7 ppm, and showed excellent recovery characteristics of more than 98%. Furthermore, it also showed a change in which the reactivity decreased with respect to humidity of 33% and 66%. Full article
(This article belongs to the Special Issue Graphene Based Chemical Sensors)
Show Figures

Figure 1

14 pages, 1338 KiB  
Article
A Novel Reduced Graphene Oxide Modified Carbon Paste Electrode for Potentiometric Determination of Trihexyphenidyl Hydrochloride in Pharmaceutical and Biological Matrices
by Josip Radić, Maša Buljac, Boštjan Genorio, Ema Gričar and Mitja Kolar
Sensors 2021, 21(9), 2955; https://0-doi-org.brum.beds.ac.uk/10.3390/s21092955 - 23 Apr 2021
Cited by 14 | Viewed by 2500
Abstract
A novel promising carbon paste electrode with excellent potentiometric properties was prepared for the analysis of trihexyphenidyl hydrochloride (THP), the acetylcholine receptor and an anticholinergic drug in real samples. It contains 10.2% trihexyphenidy-tetraphenylborate ionic pair as the electroactive material, with the addition of [...] Read more.
A novel promising carbon paste electrode with excellent potentiometric properties was prepared for the analysis of trihexyphenidyl hydrochloride (THP), the acetylcholine receptor and an anticholinergic drug in real samples. It contains 10.2% trihexyphenidy-tetraphenylborate ionic pair as the electroactive material, with the addition of 3.9% reduced graphene oxide and 0.3% of anionic additive into the paste, which consists of 45.0% dibutylphthalate as the solvent mediator and 40.6% graphite. Under the optimized experimental conditions, the electrode showed a Nernstian slope of 58.9 ± 0.2 mV/decade with a regression coefficient of 0.9992. It exhibited high selectivity and reproducibility as well as a fast and linear dynamic response range from 4.0 × 10−7 to 1.0 × 10−2 M. The electrode remained usable for up to 19 days. Analytical applications showed excellent recoveries ranging from 96.8 to 101.7%, LOD was 2.5 × 10−7 M. The electrode was successfully used for THP analysis of pharmaceutical and biological samples. Full article
(This article belongs to the Special Issue Graphene Based Chemical Sensors)
Show Figures

Figure 1

12 pages, 3662 KiB  
Article
Graphene-Doped Tin Oxide Nanofibers and Nanoribbons as Gas Sensors to Detect Biomarkers of Different Diseases through the Breath
by Carlos Sánchez-Vicente, José Pedro Santos, Jesús Lozano, Isabel Sayago, José Luis Sanjurjo, Alfredo Azabal and Santiago Ruiz-Valdepeñas
Sensors 2020, 20(24), 7223; https://0-doi-org.brum.beds.ac.uk/10.3390/s20247223 - 17 Dec 2020
Cited by 12 | Viewed by 2689
Abstract
This work presents the development of tin oxide nanofibers (NFs) and nanoribbons (NRs) sensors with graphene as a dopant for the detection of volatile organic compounds (VOCs) corresponding to different chronic diseases (asthma, chronic obstructive pulmonary disease, cystic fibrosis or diabetes). This research [...] Read more.
This work presents the development of tin oxide nanofibers (NFs) and nanoribbons (NRs) sensors with graphene as a dopant for the detection of volatile organic compounds (VOCs) corresponding to different chronic diseases (asthma, chronic obstructive pulmonary disease, cystic fibrosis or diabetes). This research aims to determine the ability of these sensors to differentiate between gas samples corresponding to healthy people and patients with a disease. The nanostructures were grown by electrospinning and deposited on silicon substrates with micro-heaters integrated. The morphology of NFs and NRs was characterized by Scanning Electron Microscopy (SEM). A gas line was assembled and programmed to measure a wide range of gases (ethanol, acetone, NO and CO) at different concentrations simulating human breath conditions. Measurements were made in the presence and absence of humidity to evaluate its effect. The sensors were able to differentiate between the concentrations corresponding to a healthy person and a patient with one of the selected diseases. These were sensitive to biomarkers such as acetone and ethanol at low operating temperatures (with responses above 35%). Furthermore, CO and NO response was at high temperatures (above 5%). The sensors had a rapid response, with times of 50 s and recovery periods of about 10 min. Full article
(This article belongs to the Special Issue Graphene Based Chemical Sensors)
Show Figures

Figure 1

11 pages, 2000 KiB  
Communication
Low-Humidity Sensing Properties of Multi-Layered Graphene Grown by Chemical Vapor Deposition
by Filiberto Ricciardella, Sten Vollebregt, Tiziana Polichetti, Pasqualina M. Sarro and Georg S. Duesberg
Sensors 2020, 20(11), 3174; https://0-doi-org.brum.beds.ac.uk/10.3390/s20113174 - 03 Jun 2020
Cited by 5 | Viewed by 2705
Abstract
Humidity sensing is fundamental in some applications, as humidity can be a strong interferent in the detection of analytes under environmental conditions. Ideally, materials sensitive or insensitive towards humidity are strongly needed for the sensors used in the first or second case, respectively. [...] Read more.
Humidity sensing is fundamental in some applications, as humidity can be a strong interferent in the detection of analytes under environmental conditions. Ideally, materials sensitive or insensitive towards humidity are strongly needed for the sensors used in the first or second case, respectively. We present here the sensing properties of multi-layered graphene (MLG) upon exposure to different levels of relative humidity. We synthesize MLG by chemical vapor deposition, as shown by Raman spectroscopy, Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM). Through an MLG-based resistor, we show that MLG is scarcely sensitive to humidity in the range 30%–70%, determining current variations in the range of 0.005%/%relative humidity (RH) well below the variation induced by other analytes. These findings, due to the morphological properties of MLG, suggest that defective MLG is the ideal sensing material to implement in gas sensors operating both at room temperature and humid conditions. Full article
(This article belongs to the Special Issue Graphene Based Chemical Sensors)
Show Figures

Figure 1

11 pages, 1812 KiB  
Article
Determination of Trace Lead and Cadmium in Decorative Material Using Disposable Screen-Printed Electrode Electrically Modified with Reduced Graphene Oxide/L-Cysteine/Bi-Film
by Xiaopeng Hou, Benhai Xiong, Yue Wang, Li Wang and Hui Wang
Sensors 2020, 20(5), 1322; https://0-doi-org.brum.beds.ac.uk/10.3390/s20051322 - 28 Feb 2020
Cited by 21 | Viewed by 2682
Abstract
Cadmium (Cd) and lead (Pb) in decorative materials threaten human health. To determine the content of Cd(II) and Pb(II), a disposable screen-printed electrode (DSPE) electrically modified with reduced graphene oxide (rGO) and L-cysteine (LC) was fabricated, which was further electroplated with bismuth film [...] Read more.
Cadmium (Cd) and lead (Pb) in decorative materials threaten human health. To determine the content of Cd(II) and Pb(II), a disposable screen-printed electrode (DSPE) electrically modified with reduced graphene oxide (rGO) and L-cysteine (LC) was fabricated, which was further electroplated with bismuth film (Bi/LC-rGO/DSPE) in situ. The electrochemical properties of this electrode were studied using cyclic voltammetry, electrochemical impedance spectroscopy, linear sweep voltammetry and differential pulse voltammetry. The results indicated that the Bi/LC-rGO/DSPE had excellent sensitivity, selectivity and stability with low cost and easy production. After optimizing the detection parameters, the linear range of the Bi/LC-rGO/DSPE was from 1.0 to 30.0 μg/L for Cd(II) and Pb(II), and the detection limits were 0.10 μg/L for Cd(II) and 0.08 μg/L for Pb(II). Finally, the Bi/LC-rGO/DSPE was applied to determine the concentrations of Cd(II) and Pb(II) in different decorative materials where the recoveries were in the range from 95.86% to 106.64%. Full article
(This article belongs to the Special Issue Graphene Based Chemical Sensors)
Show Figures

Figure 1

Review

Jump to: Research

23 pages, 2776 KiB  
Review
Electrochemical Detection of Glucose Molecules Using Laser-Induced Graphene Sensors: A Review
by Jingrong Gao, Shan He and Anindya Nag
Sensors 2021, 21(8), 2818; https://0-doi-org.brum.beds.ac.uk/10.3390/s21082818 - 16 Apr 2021
Cited by 14 | Viewed by 6062
Abstract
This paper deals with recent progress in the use of laser-induced graphene sensors for the electrochemical detection of glucose molecules. The exponential increase in the exploitation of the laser induction technique to generate porous graphene from polymeric and other naturally occurring materials has [...] Read more.
This paper deals with recent progress in the use of laser-induced graphene sensors for the electrochemical detection of glucose molecules. The exponential increase in the exploitation of the laser induction technique to generate porous graphene from polymeric and other naturally occurring materials has provided a podium for researchers to fabricate flexible sensors with high dynamicity. These sensors have been employed largely for electrochemical applications due to their distinct advantages like high customization in their structural dimensions, enhanced characteristics and easy roll-to-roll production. These laser-induced graphene (LIG)-based sensors have been employed for a wide range of sensorial applications, including detection of ions at varying concentrations. Among the many pivotal electrochemical uses in the biomedical sector, the use of these prototypes to monitor the concentration of glucose molecules is constantly increasing due to the essentiality of the presence of these molecules at specific concentrations in the human body. This paper shows a categorical classification of the various uses of these sensors based on the type of materials involved in the fabrication of sensors. The first category constitutes examples where the electrodes have been functionalized with various forms of copper and other types of metallic nanomaterials. The second category includes other miscellaneous forms where the use of both pure and composite forms of LIG-based sensors has been shown. Finally, the paper concludes with some of the possible measures that can be taken to enhance the use of this technique to generate optimized sensing prototypes for a wider range of applications. Full article
(This article belongs to the Special Issue Graphene Based Chemical Sensors)
Show Figures

Figure 1

27 pages, 3271 KiB  
Review
A Review on Functionalized Graphene Sensors for Detection of Ammonia
by Xiaohui Tang, Marc Debliquy, Driss Lahem, Yiyi Yan and Jean-Pierre Raskin
Sensors 2021, 21(4), 1443; https://0-doi-org.brum.beds.ac.uk/10.3390/s21041443 - 19 Feb 2021
Cited by 64 | Viewed by 6268
Abstract
Since the first graphene gas sensor has been reported, functionalized graphene gas sensors have already attracted a lot of research interest due to their potential for high sensitivity, great selectivity, and fast detection of various gases. In this paper, we summarize the recent [...] Read more.
Since the first graphene gas sensor has been reported, functionalized graphene gas sensors have already attracted a lot of research interest due to their potential for high sensitivity, great selectivity, and fast detection of various gases. In this paper, we summarize the recent development and progression of functionalized graphene sensors for ammonia (NH3) detection at room temperature. We review graphene gas sensors functionalized by different materials, including metallic nanoparticles, metal oxides, organic molecules, and conducting polymers. The various sensing mechanism of functionalized graphene gas sensors are explained and compared. Meanwhile, some existing challenges that may hinder the sensor mass production are discussed and several related solutions are proposed. Possible opportunities and perspective applications of the graphene NH3 sensors are also presented. Full article
(This article belongs to the Special Issue Graphene Based Chemical Sensors)
Show Figures

Figure 1

Back to TopTop