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Sustainable Biofuel Production from Lignocellulosic Biomass: Special Focus on Pretreatments Methods, Biomass Hydrolysis and Assessment Methods

A special issue of Sustainability (ISSN 2071-1050).

Deadline for manuscript submissions: closed (30 November 2022) | Viewed by 5725

Special Issue Editors


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Guest Editor
Metagenomics and Secretomics Research Laboratory, Department of Botany, School of Biological Sciences, Dr. H.S. Gour Central University, Sagar, MP, India
Interests: Plant–microbe interaction; rhizosphere microbiome; abiotic and biotic stress; next-generation sequencing
Special Issues, Collections and Topics in MDPI journals
James Watt School of Engineering, University of Glasgow, Glasgow, UK
Interests: bioenergy; waste-to-resources; LCA
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Development of Biorefineries, Laboratory of Chemical Engineering, Universidad Del Zulia, Maracaibo, Venezuela
Interests: chemical analysis of biomass; biorefining; plant design; bioprocesses; biorefining process; mechanical and chemical pretreatments

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Guest Editor
Department of Food Process Engineering, National Institute of Technology Rourkela, Sundargarh, Odisha, India
Interests: agriculture residues; pretreatments methods; nonedible oil seeds plants; underutilized crop for biodiesel and bioethanaol

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Guest Editor
Biorefinery Processes Group, Chemical and Environmental Engineering Department, University of the Basque Country UPV/EHU, Plaza Europa 1, 20018 Donostia-San Sebastián, Spain
Interests: Biorefinery processes; solvents recovery; energy consumption; green chemistry
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Worsening environmental and energy crises, due to rapid exploitation of fossil fuels, have led to an emergent need for the development of alternative energy resources. Among all alternatives, the production of bioethanol from lignocellulosic biomass particularly from agricultural residues and other waste is a viable option to mitigate the emission of greenhouse gases, impact of climate change and also reducing the loads on fossil fuels. To meet this huge demand energy researchers around the world have been searching for suitable biomass feedstocks, pretreatment methods, and appropriate microorganisms that can convert biomass into biofuels. Most importantly, there is a need for a better understanding of the inter and intramolecular changes that occur to lignocellulosic materials, during the fundamental processes of biorefining, conditioning, pretreatment, saccharification, fermentation, and purification. We are interested in the most recent advances in molecular processes that occur to biomass, during its passage through the biorefinery, using advanced instrumental analytical techniques, hypotheses, and models, validated with data from the literature, that allow the simulation and escalation of the processes. Innovative technological proposals that can eliminate the bottlenecks that interfere with lignocellulosic biofuel production specifically at the commercial level are also welcome.

The Editorial Team invites the submission of original research papers and critical review articles. Specific themes of interest include but are not limited to the following:

  • Biomass feedstock: production and processing procedure.
  • Inter and Intramolecular changes in the structure of biomass.
  • Pre-treatment technologies (chemical and biological) for rapid biomass hydrolysis.
  • Life cycle assessment of biofuel production.
  • Agriculture residues and waste biomass as a source of low-cost biomass feedstock
  • Optimization of process parameters using response surface methodology.
  • Application of methods such as FTIR, PXRD, CLSM, SEM, TEM, and NMR to assess the degradation of biomass.

Dr. Ashwani Kumar
Dr. Siming You
Prof. Alexis Manuel Faneite Noguera
Dr. Rama Chandra Pradhan
Prof. María González Alriols
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Sustainability is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Agriculture residues
  • Lignocellulosic biomass
  • Waste biomass
  • Biorefinery
  • Pretreatment technologies
  • Enzyme hydrolysis
  • Circular Bioeconomy

Published Papers (2 papers)

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Research

17 pages, 7020 KiB  
Article
Enhancing Biogas Production of Co-Digested Cattle Manure with Grass Silage from a Local Farm in Landshut, Bavaria, through Chemical and Mechanical Pre-Treatment and Its Impact on Biogas Reactor Hydraulic Retention Time
by Verónica Hidalgo-Sánchez, Uwe Behmel, Josef Hofmann and María Emma Borges
Sustainability 2023, 15(3), 2582; https://0-doi-org.brum.beds.ac.uk/10.3390/su15032582 - 31 Jan 2023
Cited by 3 | Viewed by 1372
Abstract
Cattle manure usually contains a proportion of carbohydrates in the form of organic residues from incompletely digested feed and farm husbandry practices. These are not usually available for biogas production due to the long fermentation time. This paper investigates the optimal application of [...] Read more.
Cattle manure usually contains a proportion of carbohydrates in the form of organic residues from incompletely digested feed and farm husbandry practices. These are not usually available for biogas production due to the long fermentation time. This paper investigates the optimal application of alkali, NaOH and KOH and mechanical pre-treatments to improve the degradation of the lignocellulosic content and the potential biogas yields from a local farm in Bavaria, Germany. Parameters such as temperature, pH, soluble chemical oxygen demand, organic acids, dry matter and volatile solids were analysed for this purpose. Alkali pre-treatments in 0.2, 0.1 and 0.05 M NaOH concentrations were tested in single mode and combined with shredding in batch experiments. The maximum increment of the soluble chemical oxygen demand during the pre-treatments took place during the first 50 h of experimentation, and it showed an improvement of 10,060.0 ± 8% mg/L s COD after the application of 0.2 M NaOH compared to the untreated substrate, which had an initial value of 2145.0 ± 8% mg/L s COD. Pre-treatments with 0.1 and 0.05 M NaOH concentrations showed similar s COD increments, with an additional 6860.0 ± 8% mg/L s COD and 8505.0 ± 8% mg/L s COD, respectively. The pH values varied strongly after the addition of the pre-treatment chemicals, with a continuous pH of 12 by 0.2 M NaOH during the 7 days of pre-treatment. Batch biogas experiments were done by applying 0.05 M NaOH and 0.05 M KOH pre-treatments in single mode and combined with shredding. The chemically pre-treated substrates showed a faster biogas production with an advantage of 18 days in comparison to the untreated cattle manure by a biogas yield of 350.0 NL/kg VS. All experiments were done under mesophilic conditions. Full article
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16 pages, 2511 KiB  
Article
Biological Characterization and Instrumental Analytical Comparison of Two Biorefining Pretreatments for Water Hyacinth (Eichhornia crassipes) Biomass Hydrolysis
by Jitendra Kumar Singh, Bhawana Chaurasia, Anamika Dubey, Alexis Manuel Faneite Noguera, Aditi Gupta, Richa Kothari, Chandrama Prakash Upadhyaya, Ashwani Kumar, Abeer Hashem, Abdulaziz A. Alqarawi and Elsayed Fathi Abd Allah
Sustainability 2021, 13(1), 245; https://0-doi-org.brum.beds.ac.uk/10.3390/su13010245 - 29 Dec 2020
Cited by 15 | Viewed by 3490
Abstract
Water hyacinth is a rapidly growing troublesome aquatic weed plant, which causes eutrophication in water bodies and irreversible damage to the ecological system. In this work, we have investigated the water hyacinth biomass (WHB) hydrolysis efficacy of dilute alkaline (DA) pretreatment followed by [...] Read more.
Water hyacinth is a rapidly growing troublesome aquatic weed plant, which causes eutrophication in water bodies and irreversible damage to the ecological system. In this work, we have investigated the water hyacinth biomass (WHB) hydrolysis efficacy of dilute alkaline (DA) pretreatment followed by biological pretreatment with white-rot fungus Alternaria alternata strain AKJK-2. The effectiveness of the dilute alkaline (DA) and biological pretreatment process on WHB was confirmed by using X-ray Diffraction (XRD) and Fourier Transform Infrared Spectrophotometer (FTIR), and was further visualized by Scanning Electron Microscope (SEM) and Confocal Laser Scanning Microscopy (CLSM). XRD spectra showed the increase in the crystallinity of pretreated samples, attributed to the elimination of amorphous components as lignin and hemicellulose. FTIR peak analysis of pre-treated WHB showed substantial changes in the absorption of cellulose functional groups and the elimination of lignin signals. Scanning electron microscopy (SEM) images showed firm, compact, highly ordered, and rigid fibril structures without degradation in the untreated WHB sample, while the pretreated samples exhibited loose, dispersed, and distorted structures. XRD indices (Segal, Landis, and Faneite), and FTIR indices [Hydrogen bond intensity (HBI); Total crystallinity index (TCI); and Lateral order crystallinity (LOI)] results were similar to the aforementioned results, and also showed an increase in the crystallinity both in alkaline and biological pretreatments. Alkaline pretreated WHB, with these indices, also showed the highest crystallinity and a crystalline allomorphs mixture of cellulose I (native) and cellulose II. These results were further validated by the CLSM, wherein fluorescent signals were lost after the pretreatment of WHB over control. Overall, these findings showed the significant potential of integrated assessment tools with chemical and biological pretreatment for large-scale utilization and bioconversion of this potential aquatic weed for bioenergy production. Full article
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