(1) Background: It is well known that various toxic substances, including carcinogens, are generated at the fire scenes, so it is very important for firefighters to wear comprehensive personal protective equipment. The extent of the type and amount of harmful substances contained in the washing water of fire protection suits (FPS) exposed to fire scenes have not yet been confirmed. The purpose of this study is to evaluate the characteristics of harmful substances contained in wash water extracted from FPSs exposed to fire. (2) Methods: The study design was a simulation-based experimental study. To evaluate the degree of contamination exposure of FPSs, 10 sets of fire suits were classified into four groups as follows: newly supplied, field use, one fire exposure, and two consecutive fire exposures. In the experimental environment, after exposing three to four groups of FPSs to residential fire conditions. they were sealed in a plastic bag in the experimental space. The washing water for FPSs was extracted through manual washing in the order of Groups 1 to 4, and 24 items were analyzed according to the water pollution process test standards. (3) Results: According to the results of the FPS laundry analysis, the concentration of acrylonitrile in laundry was higher when exposed to fire twice than when exposed to fire once. Moreover, there was a dose–response relationship, and the risk of cumulative toxicity was shown. Naphthalene and diethylhexyl phthalate (DEHP) were detected to be high in the washing water of Group 3 FPSs exposed to incomplete combustion fire. Of the 24 items that were analyzed for in the water, four item exceeded the standard for sewage discharge facilities in accordance with the Water Environment Conservation Act. Copper and its compounds exceeded the standards by 3.4 times, antimony 4.8 times, acrylonitrile 26.0 times, and DEHP 4.1 times, respectively. (4) Conclusions: Therefore, when removing FPSs after firefighting activities, care should be taken to avoid contaminating the skin. In addition, facilities that wash FPS that have been exposed to a fire scene must have a sewage treatment and purification facility. However, if emergency decontamination of FPSs is conducted at the fire scene, the concentration of toxic substances contained in laundry can be reduced. In the case of large-scale fire, there is a risk of water pollution near the fire scene, so it is necessary to prepare a national countermeasure. The results of this study can be applied to the revision of regulations related to the building of the fire departments, reduction of water pollution, and water environment policy. Full article

In modern dentistry, dental units are used for the treatment of patients’ teeth, and they need water to operate. Water circulates in a closed vessel system and finally reaches the mucous membranes of the patient as well as the dentist themselves. Therefore, the microbiological safety of this water should be a priority for physicians. This study aims to identify and determine the microbial count, expressed in CFU/mL, in water samples from various parts of the dental unit that are in direct contact with the patient. Thirty-four dental units located in dentistry rooms were analysed. The dentistry rooms were divided into three categories: surgical, conservative, and periodontal. It was found that in surgical rooms, the bacterial count was 1464.76 CFU/mL, and the most common bacterium was Staphylococcus pasteuri—23.88% of the total bacteria identified. In dentistry rooms where conservative treatments were applied, the average bacterial concentration was 8208.35 CFU/mL, and the most common bacterium was Ralsonia pickettii (26.31%). The periodontal rooms were also dominated by R. pickettii (45.13%), and the average bacterial concentration was 8743.08 CFU/mL. Fungi were also detected. Rhodotorula spp., Alternaria spp., and Candida parapsilosis were found to be the most common bacteria which are potentially harmful. This study indicates the need for effective decontamination of the water that is used in dental units and for constant monitoring of the level of contaminants present in the closed vessel system. Full article

Metal ion studies in wastewater are required on a regular basis for environmental monitoring and assessment. Less metal ion concentrations and the interference from complex sample matrices remains challenging for instrumental quantification. Herein, we proposed a fix-bed solid phase extraction method, consisting of a newly prepared dimercaptosuccinic acid functionalized polystyrene beads. The ligand forms stable complex with Hg(II), Pb(II), and Cd(II), evident by experimental as well as density functional theory. The metal-ligand stabilization energy calculations, suggested the higher selectivity of polystyrene dimercaptosuccinic acid (PSDMSA) toward Pb(II) compared to Cd(II) and Hg(II). The prepared adsorbent was utilized to enrich Hg(II), Pb(II), and Cd(II) ions from environmental samples. Column parameters were studied in detail and optimized accordingly. The preconcentration factor for Hg(II), Pb(II), and Cd(II) were found to be 900, with the preconcentration limit of 0.74 µg L⁻¹. The detection limit for Pb(II), Cd(II), and Hg(II) ions was found to be 1.3 ± 0.2, 1.5 ± 0.3, and 1.8 ± 0.3 ng L⁻¹, respectively. The method accuracy was tested against systematic and continuous errors by standard addition method (<5% RSD). Real samples was successfully analyzed following the proposed method. Full article

One of the oldest and most promising applications of natural zeolites (NZs) is in water and wastewater treatment processes. Modified zeolites (MZs), with improved ion exchange and adsorption capacities, have been extensively applied to the removal of pollutants from aqueous solutions. However, the application of MZs in pathogens or indicator organisms has not been extensively explored. This study examines the effect of both natural Greek zeolite (NZ), with a clinoptilolite content of up to 85% (OLYMPUS SA-INDUSTRIAL MINERALS), and modified Greek zeolite through incorporation with silver ions (Ag-MNZ), on the survival of two selected faecal indicator bacteria (Escherichia coli and Enterococcus faecalis). A series of dynamic batch experiments with a slow agitation of 12 rpm were conducted at a constant ambient temperature (22°C) in order to examine the inactivation of the above bacteria by NZ and Ag-MNZ. It was found that the Ag-MNZ resulted in a much higher reduction in the bacterial numbers when compared to the NZ and the control (absence of zeolites). Moreover, the reduction in bacterial numbers was affected by NZ particle size, with higher removal rates observed for coarse (1–3 mm) than for fine (0–1 mm) NZ. Finally, the E. faecalis was found to be more resistant than E. coli to Ag-MNZ. Full article

Hotel water systems colonized with Legionella spp. have been the source of travel-associated Legionnaires’ disease, and cases, clusters and outbreaks continue to be reported worldwide each year. A total of 132 hotels linked with travel-associated Legionnaires’ disease, as reported through the European Legionnaires’ Disease Surveillance Network, were inspected and tested for Legionella spp. during 2000–2019 by the public health authorities of the island of Crete (Greece). A total of 3311 samples were collected: 1885 (56.93%) from cold water supply systems, 1387 (41.89%) from hot water supply systems, 37 (1.12%) were swab samples and two (0.06%) were soil. Of those, 685 (20.69%), were collected from 83 (62.89%) hotels, testing positive (≥50 CFU/L) for Legionella pneumophila) serogroups 1–10, 12–14 and non-pneumophila species (L. anisa, L. erythra, L. tusconensis, L. taurinensis, L. birminghamensis, L. rubrilucens, L. londiniesis, L. oakridgensis, L. santicrusis, L. brunensis, L. maceacherii). The most frequently isolated L. pneumophila serogroups were 1 (27.92%) and 3 (17.08%). Significantly higher isolation rates were obtained from hot water supply systems (25.96%) versus cold water systems (16.98%) and swab samples (13.51%). A Relative Risk (R.R.) > 1 (p < 0.0001) was calculated for hot water temperature <55 °C (R.R.: 4.43), chlorine concentrations <0.2 mg/L (R.R.: 2.69), star ratings <4 (R.R.: 1.73) and absence of Water Safety Plan implementation (R.R.: 1.57). Full article

This paper estimates the prevalence and severity of dental fluorosis among participants in the first wave of The Aguascalientes Longitudinal Study of Child Development (EDNA). The analytical sample includes 1052 children in 100 public elementary schools. Dental fluorosis is determined using the Modified Dean’s Index. There is a 43% general dental fluorosis prevalence, and the estimated Community Fluorosis Index is 0.99. Five municipalities report average groundwater fluoride concentrations above the official Mexican guideline value of 1.5 mg/L. In those municipalities, there is a 50% average dental fluorosis prevalence. An ordered logistic regression analysis indicates that obesity in participants increases the likelihood of suffering more severe dental fluorosis symptoms compared with normal-weight participants (OR = 1.62, p < 0.05). Households consuming tap water are more likely to have children suffering more severe dental fluorosis symptoms (OR = 1.63, p < 0.05). Children aged 8 years are more likely to present more severe dental fluorosis symptoms than their peers aged 7 years (OR = 1.37, p < 0.05). Dental fluorosis will persist as a public health problem in Aguascalientes State unless appropriate technologies for fluoride removal from water are installed and operated. Full article

In September 2017, two category-5 hurricanes Irma and Maria swept through the Caribbean Sea in what is now known as the region’s most active hurricane season on record, leaving disastrous effects on infrastructure and people’s lives. In the U.S. Virgin Islands, rain cisterns are commonly used for harvesting roof-top rainwater for household water needs. High prevalence of Legionella spp. was found in the cistern water after the hurricanes. This study carried out a quantitative microbial risk assessment to estimate the health risks associated with Legionella through inhalation of aerosols from showering using water from cisterns after the hurricanes. Legionella concentrations were modeled based on the Legionella detected in post-hurricane water samples and reported total viable heterotrophic bacterial counts in cistern water. The inhalation dose was modeled using a Monte Carlo simulation of shower water aerosol concentrations according to shower water temperature, shower duration, inhalation rates, and shower flow rates. The risk of infection was calculated based on a previously established dose–response model from Legionella infection of guinea pigs. The results indicated median daily risk of 2.5 × 10⁻⁶ to 2.5 × 10⁻⁴ depending on shower temperature, and median annual risk of 9.1 × 10⁻⁴ to 1.4 × 10⁻². Results were discussed and compared with household survey results for a better understanding of local perceived risk versus objective risk surrounding local water supplies. Full article

Recognition of sustainability issues around water resource consumption is gaining traction under global warming and land utilization complexities. These concerns increase the challenge of gaining an appropriate comprehension of the anthropogenic activities and natural processes, as well as how they influence the quality of surface water and groundwater systems. The characteristics of water resources cause difficulties in the comprehensive assessment regarding the source types, pathways, and pollutants behaviors. As the behavior and prediction of widely known contaminants in the water resources remain challenging, some new issues have developed regarding heavy metal pollutants. The main aim of this review is to focus on certain essential pollutants’ discharge from anthropogenic activities categorized based on land-use sectors such as industrial applications (solid/liquid wastes, chemical compounds, mining activities, spills, and leaks), urban development (municipal wastes, land use practices, and others), and agricultural practices (pesticides and fertilizers). Further, important pollutants released from natural processes classified based on climate change, natural disasters, geological factors, soil/matrix, and hyporheic exchange in the aquatic environment, are also discussed. Moreover, this study addresses the major inorganic substances (nitrogen, fluoride, and heavy metals concentrations). This study also emphasizes the necessity of transdisciplinary research and cross-border communication to achieve sustainable water quality using sound science, adaptable legislation, and management systems. Full article