Environments doi: 10.3390/environments11030058
Authors: Antonietta Siciliano Marisa Spampinato Giovanna Salbitani Marco Guida Simona Carfagna Antonios Apostolos Brouziotis Marco Trifuoggi Rosanna Bossa Lorenzo Saviano Edith Guadalupe Padilla Suarez Giovanni Libralato
The significantly increasing levels of Rare Earth Elements (REEs) in seawater are largely due to multiple anthropogenic activities. Their effects on marine primary producers such as Phaeodactylum tricornutum have not been fully assessed. This study focused on examining the long-term impacts of these two commonly occurring REEs, cerium (Ce) and gadolinium (Gd), on marine diatoms by 28 d of exposure. The 72 h effective concentrations that inhibited the growth of 20% (EC20) and 50% (EC50) of the exposed population were used for long-term exposures. The growth, oxidative stress level, photosynthetic pigments, and chlorophyll fluorescence were assessed in the diatoms, after 7, 14, 21, and 28 d of REEs exposure. Results display a difference in the toxicity induced by the two elements. Exposure to 2.39 mg/L (EC20) and 3.13 mg/L (EC50) of Ce, and to 4.52 mg/L (EC20) and 6.02 mg/L (EC50) of Gd displayed a lower effect on the growth of algae cells, as the response remained below 20% for inhibition or stimulation. Except for GD, the ROS and the activities of SOD, and LPO showed, during the exposure, comparable levels respect to control cells. A change in chlorophyll levels was also observed especially under Ce exposure. Both elements showed changes in photosynthetic performance. This study provides new insights into the different effects of Ce and Gd on P. tricornutum, demonstrating their diverse modes of action on this important primary producer. The findings provide further evidence of the adverse effects of anthropogenic REEs pollution on marine ecosystems.
]]>Environments doi: 10.3390/environments11030057
Authors: Meng-Yuan Chu Peter Brimblecombe Peng Wei Chun-Ho Liu Zhi Ning
Air pollutants from traffic make an important contribution to human exposure, with pedestrians likely to experience rapid fluctuation and high concentrations on the pavements of busy streets. This monitoring campaign was on Hennessy Road in Hong Kong, a densely populated city with deep canyons, crowded footpaths and low wind speeds. Kerbside NOx concentrations were measured using electrochemical sensors with baseline correction and subsequently deconvoluted to determine concentrations at 1-s resolution to study the dispersion of exhaust gases within the first few metres of their on-road source. The pulses of NOx from passing vehicles were treated as segments of a Gaussian plume originating at the tailpipe. The concentration profiles in segments were fit to a simple analytical equation assuming a continuous line source with R2 > 0.92. Least squares fitting parameters could be attributed to vehicle speed and source strength, dispersion, and sensor position. The width of the plume was proportional to the inverse of vehicle speed. The source strength of NOx from passing vehicles could be interpreted in terms of individual emissions, with a median value of approximately 0.18 g/s, but this was sensitive to vehicle speed and exhaust pipe position. The current study improves understanding of rapid changes in pollutant concentration in the kerbside environment and suggests opportunities to establish the contribution from traffic flow to pedestrian exposure in a dynamic heavily occupied urban microenvironment.
]]>Environments doi: 10.3390/environments11030056
Authors: Srijana Thapa Magar Takeshi Fujino Thant Ko Ko Han
The growth of Heteranthera reniformis, an invasive alien paddy weed, can be affected by cultivation practices. The experiments were conducted using herbicide-free soil to understand the effects of irrigation regimes and nutrient treatments on the growth of H. reniformis, as well as yield parameters while competing with a pre-existing seedbank. The pot experiments were conducted in a randomized complete block design (RBCD) with three replicates and twelve treatments. The four irrigation regimes (IRs): continuous irrigation (CI), soil condition at near saturation (non-puddled) (S), alternate wetting and drying (AWD) irrigation under two conditions [rewatered when the soil water potential reached −25 kPa (25P) and −35 kPa (35P)], and three nutrient treatments (NTs) of 0–0–0 NPK (NT0), 40–25–30 NPK (NT1), 80–50–60 NPK (NT2), kg ha−1 were established. The IRs had a significant effect on the growth of H. reniformis and other paddy field weeds, and the growth of H. reniformis was suppressed in the AWD regimes. NT2 resulted in more rice panicles, higher grain yield, and increased irrigation water use efficiency (IWUE). The highest grain yield and protein content were observed in S–NT2 and 25P–NT2 treatments. The IR and NT can be maintained to prevent yield penalties and reduce the invasiveness of weeds.
]]>Environments doi: 10.3390/environments11030055
Authors: Jean-Philippe Aurambout Kurt K. Benke Garry J. O’Leary
Environmental heat stress is implicated in various animal health issues in ruminants, including reproduction rates, mortality rates, and animal physical quality. During extremely hot weather, there is often no overnight equilibration of animal temperature with its cooling effect, and the accumulated heat load becomes an important factor in animal health for ruminants such as sheep. Using the heat load index (HLI), a heat load model is used as an indicator of heat stress on an hourly basis and annually, using downscaling models for temperature, humidity, solar radiation, and wind speed, in both spatial and temporal cases, across several example sites in regional Victoria. Analysis is provided on the performance of the downscaling models and various adaptation and mitigation options are discussed and tested. These options include using different tree planting patterns to modify solar radiation exposure and wind effects, with mixed results because adding shading structures may also diminish the effect of wind-based cooling. The modelling experiments indicated that (1) heat stress is likely to increase under future climate conditions and could represent a serious threat to the health of small ruminants; (2) adaptation measures by means of tree planting to provide shade may not be sufficient to alleviate projected heat stress; and (3) other adaptation measures will need to be considered. Indicative results for heat stress under potential future environments are provided for 2030, 2050, and 2070. Also discussed is the performance of wind speed modelling, and the effect of heat stress on animal growth and ram fertility.
]]>Environments doi: 10.3390/environments11030054
Authors: Gabriela Cristina Sarti Mirta Esther Galelli Josefina Ana Eva Cristóbal-Miguez Eliana Cárdenas-Aguiar Hugo Daniel Chudil Ana Rosa García Antonio Paz-González
Over-fertilization and agrochemicals adversely affect soil quality and agricultural ecosystem sustainability. Tomato (Solanum lycopersicum) is ranked as an important crop due to its high profitability and nutritional value. In Argentina, tomato is mainly produced in horticultural belts at peri-urban areas, whose soils frequently are contaminated by heavy metals and/or agrochemicals. To explore safer alternatives, we investigated the effects of seed inoculation with a common plant-growth-promoting rhizobacteria (PGPR), i.e., Bacillus subtilis subsp. spizizenii, on development at various growth stages of two tomato varieties, “Platense” and “Río Grande”, and on production and fruit quality at harvest time of the “Río Grande” variety. The experimental design consisted of three treatments per variety: a control versus traditional planktonic or biofilm inoculation, with three replicates per treatment. Germination at 10 days and seedling agronomical parameters showed that the response to seed inoculation was superior in the “Río Grande” variety. At harvest time, and irrespective of the inoculant, several agronomical parameters of the “Río Grande” variety were significantly enhanced with respect to the control. The biofilm significantly increased tomato production, as quantified by fruit number and weight, compared to the planktonic inoculum. This case study demonstrates that the incorporation of bio-inoculants is relevant in sustainable agriculture to promote crop growth and quality.
]]>Environments doi: 10.3390/environments11030053
Authors: Stefano Salvestrini Eleonora Grilli Elio Coppola
The sorption/desorption processes of the cationic herbicide paraquat (PQ) onto various clays, namely, kaolinite (KLN), illite (ILT), and montmorillonite (MNT), were investigated. After the attainment of sorption equilibrium, PQ was extracted from the clays by a double-stage desorption process utilizing an electro–ultrafiltration (EUF) procedure. The Freundlich isotherm model and a pseudo-first kinetic release model were found to adequately fit the sorption and desorption data, respectively. The experimental maximum sorbable amounts of paraquat were 5.56, 31.88, and 91.63 mg g−1 for KLN, ILT, and MNT, respectively, consistently with the order of magnitude of the cation-exchange capacity (CEC) of the clay minerals. The desorption experiments revealed that the amounts of PQ retained by the MNT samples were significantly larger than the respective amounts retained by KLN or ILT. The EUF-PQ desorption patterns of differently cation-saturated MNT samples indicated that the presence of monovalent cations could further hamper PQ release, while the opposite seemed to be true for divalent cations. Our results clearly show that a substantial aliquot of PQ is strongly retained by montmorillonite, probably via interlayering, thus suggesting that smectitic clays could act as a stable soil sink for cationic herbicides such as paraquat, favoring soil long-term contamination.
]]>Environments doi: 10.3390/environments11030052
Authors: Gal Hochman Vijay Appasamy
In this paper, we use the literature to help us better understand carbon capture costs and how these estimates fare against those of avoided costs, focusing on bioenergy carbon capture and storage (BECCS), carbon capture and storage (CCS), as well as direct air capture technologies. We approach these questions from a meta-analysis perspective. The analysis uses meta-analysis tools while applying them to numerical rather than statistical studies. Our analysis shows that avoided costs are, on average, 17.4% higher than capture costs and that the carbon intensity of the feedstock matters: the estimates for coal-based electricity generation capture costs are statistically smaller than those for natural gas or air. From a policy perspective, the literature suggests that the costs of CCS are like the 45Q subsidy of USD 50 per metric ton of carbon captured.
]]>Environments doi: 10.3390/environments11030051
Authors: Maria Antonietta Nitopi Daniela Baldantoni Vincenzo Baldi Floriana Di Stefano Alessandro Bellino
Coastal marine areas are threatened by different forms of pollution, among which potentially toxic elements (PTEs) represent a primary hazard. In this study, 16 Mediterranean macroalgae colonizing the upper eulittoral and infralittoral zones were studied for their PTE accumulation capabilities in order to identify possible biomonitors that could replace the use of Posidonia oceanica, a protected species. To achieve this objective, macronutrients (Ca, K, Mg, P, S), micronutrients (Cr, Cu, Fe, Mn, Na, Ni, Si, V, Zn) and non-essential elements (Cd, Pb) were analyzed in the thalli of different algal species, the leaves of P. oceanica and in sediments collected from six sampling sites along the Cilento coast (Campania, Italy), all characterized by different anthropogenic pressures. For sediments, a sequential extraction of PTEs to evaluate their bioavailability profile was also carried out together with the analysis of mineralogical composition, particle size distribution, pH and organic matter content. Macrophytes, belonging to different divisions (six Rhodophyta, four Chlorophyta, six Heterokontophyta, one Embryophyta), are characterized by different PTE concentrations, with a few ones being characterized by an even accumulation response toward the different PTEs. One of these, the brown alga Dictyota spiralis, is able to accumulate PTEs in concentrations similar to P. oceanica and provides more accurate concentration gradients, highlighting clear pollution scenarios that were overlooked using P. oceanica only. Therefore, D. spiralis is a useful PTE biomonitor of coastal marine ecosystems and a suitable replacement for P. oceanica, also featuring the possibility of being employed in active biomonitoring applications.
]]>Environments doi: 10.3390/environments11030050
Authors: Yumara Martín-Cruz Pablo Bordón Elisenda Pulido-Melián Teresa Saura-Cayuela Mario Monzón
Outdoor and indoor atmospheric pollution is one of the major problems that humanity continues to face. As a mitigation pathway, numerous technologies have been developed for air purification, including the use of fibrous filters. In this study, the particle capture efficiencies and pressure drops of air filters manufactured with cellulose pulp extracted from banana pseudostems were studied across three particle size ranges (PM10, PM2.5, and PM1). Two pretreatments were applied, alkaline with soda-antraquinone (alkali-treated pulp) and a subsequent bleaching process (bleached pulp), and four manufacturing processes were tested: crushing, freeze-drying, vacuum filtration, and pressing. In addition, a study varying filter grammage (70, 100, and 160 g·m−2) and pressing pressures (2, 4, 6, and 8 t) was also performed. After conducting these particle tests, the filter manufactured with bleached pulp, having a grammage of 160 g·m−2 and pressed at 4 t, was deemed the optimal individual solution. It demonstrated high particle retention efficiencies across all particle size ranges (with values exceeding 80%), a moderate pressure drop below 1000 Pa, and high thermal stability (degradation above 220 °C). However, combining freeze-drying and two-ton pressing processes yielded improved results (83% for the smallest particles and 89% for others) with approximately half the pressure drop. Based on these results, this study stands as a noteworthy contribution to waste valorization and the advancement of environmentally friendly materials for particle air filters. This is achieved through the adoption of simple and cost-effective technology, coupled with the utilization of 100% natural agricultural waste as the primary manufacturing material.
]]>Environments doi: 10.3390/environments11030049
Authors: Lea Deinert Achim Schmalenberger
Circular economy recycling-derived fertilizers (RDF) have the potential to replace linear economy fertilizers such as unsustainable superphosphates. Here, effects of ash RDF treatments in Irish grassland cultivation were investigated in a simulated second growing season. Soil fertilized in a preceding pot trial with superphosphate (SP), poultry-litter ash (PLA) and sewage-sludge ash (SSA) at P concentration of 60 kg P ha−1 and a P-free control (SP0) was reused in a microcosm trial. Lolium perenne was cultivated for 54 days in six replicates with a full complement of micro- and macro-nutrients other than P. PLA treatments provided higher dry weight shoot yields than SP0, while SSA and SP overlapped with SP0 and PLA. Most probable number (MPN) analysis showed that phosphonate- and phytate-utilizing bacterial abundance was significantly increased in PLA. Alkaline (phoD) phosphomonoesterase gene fragments were significantly more abundant (qPCR) in the ashes than the superphosphate or P-free control. Bacterial communities were significantly affected by the P application. Similarly, a significant separation of treatments was confirmed in a canonical correspondence analysis of the phoD-harboring community. The genera Streptomyces and Xanthomonas were significantly higher in abundance in the ash RDFs. These results demonstrated the potential benefits of ash RDF treatments as an alternative P source.
]]>Environments doi: 10.3390/environments11030048
Authors: Donald Vineyard K.G. Karthikeyan Phillip Barak
The wastewater treatment industry could benefit from new technologies for the removal and recovery of phosphorus (P). The CalPrex precipitation reactor has the potential to recover P in a readily land-applicable form by treating organic acid digestate with calcium hydroxide to produce brushite. Using data from a pilot-scale reactor at the local Nine Springs Wastewater Treatment Plant in Madison, WI, we modified the plant’s BioWin configuration using BioWin 6.2 to model the CalPrex technology and estimate performance under a variety of conditions. We produced dose/response curves for a range of possible lime dosages to estimate the impact of reagent dosage on the quantity and composition of precipitate produced by the CalPrex reactor and characterize the effects on downstream anaerobic digester performance. CalPrex was found to capture 46% of the plant’s influent P, reducing nuisance struvite precipitates by 57% and biosolid sludge production by 14%. The CalPrex module was also tested in two predesigned plant configurations in the BioWin cabinet with the intention of testing applicability to other configurations and searching for the impacts of CalPrex on treatment train performance. This is the first work simulating a full-scale implementation of CalPrex and the first to model interactions of CalPrex with other treatment processes.
]]>Environments doi: 10.3390/environments11030047
Authors: Annika Ehmke Jens Karl Wegener Andreas Melfsen Eberhard Hartung
Up to 58% of NH3 emissions can be reduced through the use of the urease inhibitor Atmowell® in cattle farming. Automated manure scraper and drag hose systems should be used to apply urease inhibitors (UIs) to stable floors. Proof of safe use is also needed. A risk assessment of the urease inhibitor PPDA was conducted utilising estimated and calculated exposure data along with established and verified model calculation tools. Risk assessment models can be improved using measured dermal exposure data. The fluorescent dye pyranine and a Tyvek® collector were used to measure exposure. Tyvek® was attached to a lifelike cow dummy. Regarding the drag hose system, two worst-case scenarios were considered: over the cow and passing the cow. Regarding the robot application system, a 0 m frontal scenario was considered. The over the cow scenario exhibited the highest dermal exposure, with 1.5 mg of PPDA/cow per application run. The robot scenario exhibited the smallest amount, with 0.8 mg of PPDA/cow per application run. The risk of using PPDA was already excluded by model calculation tools in a risk assessment. Compared with the estimated and calculated dermal exposure values, the measured dermal exposure levels were reduced by a factor of two to six.
]]>Environments doi: 10.3390/environments11030046
Authors: Tessa E. Pronk Elvio D. Amato Stefan A. E. Kools Thomas L. Ter Laak
Water quality monitoring programs yield a wealth of data. It is often unclear why a certain substance occurs in higher concentrations at a certain location or time. In this study, substances were considered in clusters with co-varying concentrations rather than in isolation. A total of 196 substance clusters at 19 monitoring sites in the rivers Rhine and Meuse were identified. A total of nine clusters were found repeatedly with a similar composition at different monitoring sites. Several environmental conditions and substance properties could be linked to clusters. In addition, overlap with reference substance lists was determined. These lists group multiple substances according to emission sources, substance types, or type of use. The reference substance lists revealed that Rhine and Meuse are similarly affected. The nine ‘repeating clusters’ were analyzed in more detail to identify drivers. For instance, a repeating cluster with herbicides was specifically linked to high temperatures and a high number of hours in the sun per day, e.g., summer conditions. A cluster containing polychlorinated biphenyls, identified as persistent and with a high tendency to bind organic matter, was linked to high river discharge and attributed to a potential release from sediment resuspension. Not all substances could be clustered, because their concentration did not structurally vary in the same way as other substances. The presented explorative cluster analyses, along with the obtained relations with substance properties, local environmental conditions, and reference substance lists, may facilitate the reconstruction of the processes that lead to the observed variation in concentrations. This knowledge can subsequently be used by water managers to improve water quality.
]]>Environments doi: 10.3390/environments11030045
Authors: Saoli Chanda Sanku Dattamudi Krishnaswamy Jayachandran Leonard J. Scinto Mahadev Bhat
Cyanobacteria, an important addition to biofertilizers, are gaining popularity for their multifaceted benefits in sustainable agriculture and ecosystem restoration. However, harmful algal blooms (HABs) in freshwater, predominantly caused by cyanobacteria, prevent sunlight penetration into the water and develop hypoxic and anoxic conditions. We collected cyanobacteria slurry from Lake Jesup (Central Florida, USA), repurposed it as a biofertilizer, and incorporated it in a typical South Florida calcite soil for high-value okra (Abelmoschus esculentus; var: Clemson spineless) production. Experiments were conducted at the Organic Garden Shade House and Greenhouse located inside the main campus of the Florida International University (FIU), FL, USA. A two-year experiment with four different treatments was conducted, namely, (a) control (C; no fertilizer applied), (b) total synthetic (TS), (c) total biofertilizer (TB; only cyanobacteria biofertilizer was applied), and (d) half and half (HH; 50% biofertilizer + 50% synthetic fertilizer), which were arranged in a randomized complete block design (RCBD) with six replications for each treatment. Our results indicate that TB and TS produced about 29 to 33% higher SPAD (soil plant analytical development) readings than the control. The absence of interveinal chlorosis (yellowing of leaves) in the TB and HH treatments suggests that the cyanobacteria-based biofertilizer had a role in supplying one of the critical micronutrients, iron (Fe). Analysis of the biofertilizer indicated 2000 ppm Fe content, which directly supports our observation. Similarly, average plant height (61 cm), yield (130 gm per pot), and crop biomass (67 gm) productions were significantly higher in TB than in the control. Overall, this study documents the potential of cyanobacteria biofertilizers as a viable option compared to synthetic fertilizers for sustainable crop production and soil health improvement.
]]>Environments doi: 10.3390/environments11030044
Authors: Suhad A. A. A. N. Almuktar Suhail N. Abed Miklas Scholz
As an alternative wood source for biochar and a cost-effective renewable energy source, sustainable biomass production based on fast-growing willows irrigated with treated wastewater has been explored. Salix alba L. and Salix viminalis L. were selected for assessment of their potentially high woody biomass productivity and phytoremediation efficiency when irrigated with greywater treated by floating treatment wetlands. Both Salix species produced significantly (p < 0.05) high woody biomass in the second harvest, with a significantly higher fresh woody biomass weight with higher water content (53%) for S. viminalis compared to S. alba. The dry biomass weight of S. alba was greater than of S. viminalis at the first harvest. The element accumulations in substrates changed significantly after irrigation, with greywater compared to the raw substrate following this order: Mg > Fe > Al > Cr > Mn > Cd > Cu > B. Element concentrations accumulated in twigs of S. alba following this order: Ca > Mg > Na > Mn > Zn > Fe > Al > Cd > Cu > Cr > Ni > B, but for S. viminalis the order was Ca > Mg > Mn > Zn > Na > Fe > Al > Cd > Cu > Ni > Cr > B. The accumulations of Al, B, Ca, Fe, Mg, Mn, and Ni were significantly greater in S. alba leaves compared to their twigs, which showed significantly high accumulations of Na and Zn. The accumulations of Al, B, Ca, Fe, Mg, Mn, and Na were significantly greater in S. viminalis leaves compared to their twigs.
]]>Environments doi: 10.3390/environments11030043
Authors: Jorge Briseño-Bugarín Xelha Araujo-Padilla Victor Manuel Escot-Espinoza Jaime Cardoso-Ortiz Juan Armando Flores de la Torre Argelia López-Luna
Lead (Pb) is a toxic metal associated with several health disorders. The mining and Pb battery industry are related to Pb increase in air, water, and soil. Mexico is an important worldwide Pb producer; however, reviews on environmental Pb contamination in Mexico are insufficient. Since Pb remains stable in soil and its concentration is an indicator of Pb exposure, this systematic review focused on reports of Pb concentrations in soil from Mexico published in 2010–2023. The retrieved reports were ordered, and contamination grade and health risk were estimated for location. From 36 retrieved reports, 24 were associated with mining Pb pollution, while a unique report mentioned the battery industry. The publications evaluated mining (13), agricultural (11), and residential (16) soils. Pb concentrations in soil were higher than the allowed limits in more than half of the reports. According to the Pb concentrations in soil, the locations evaluated in Mexico presented a contamination grade from heavily contaminated to extremely contaminated and health risks results suggested severe hazards, particularly for children. This work can guide other researchers to identify potentially contaminated but understudied Mexican locations.
]]>Environments doi: 10.3390/environments11030042
Authors: Johann Michael Köhler Linda Ehrhardt Peter Mike Günther Manfred Böhme Jialan Cao
Six soil samples from three layers of an archaeological investigation profile from a pre-industrial ash deposit place have been investigated by NGS analyses of 16 S rRNA. The three pairs of sample originate from top soil (internal reference), from an intermediate ash layer and from a lower ash layer, formed about two centuries ago. In addition to general abundant bacteria, special genera known as halophilic or alkaline-tolerant have been found as expected from the history of the place and from the measured pH-value and conductivity measurements. The close relations between samples of pairs and the differences between the three soil layers are clearly indicated by abundance correlation and PCA-diagrams. Comparative PCA correlation plots including samples from an archaeological excavation site dedicated to pre-industrial coal mining illustrate the high distinguishability of investigated soils. These relations are particular clearly shown when lower abundant bacteria are regarded. The investigations are a further example for the “ecological memory of soil” reflecting the strong human impact on this pre-industrial embossed place.
]]>Environments doi: 10.3390/environments11030041
Authors: Pietro Cacialli Serena Ricci Flavia Frabetti Sara Ferrando Valeria Franceschini
Nitrogen-based fertilizers represent the most common fertilization tools, particularly used in crop food agriculture, despite the low cost-efficiency and the high negative environmental impact. At present, there is still inadequate information available about the effects of urea on human health; nevertheless, previous studies in animals observed that high urea concentration exposure can damage different tissues, including the brain. In several vertebrates, a crucial factor involved in neuronal cell formation is represented by the gas molecule, nitric oxide (NO), derived from the conversion of arginine to citrulline through the enzymatic activity of nitric oxide synthases (NOS). In zebrafish, three different isoforms of the NOS gene are known: nos1, nos2a, and nos2b. In the present study we show that nos1 represents the unique isoform with a stable high expression in the brain and spinal cord during all the embryonic stages of zebrafish development. Then, by using a specific transgenic zebrafish line, Tg(HuC:GFP), to mark neuronal cells, we observed nos1 to be specifically expressed in neurons. Interestingly, we observed that urea exposure at sub-lethal doses affected cell proliferation and the number of nos1-expressing cells, inducing apoptosis. Consistently, brain NO levels were observed to be reduced in urea-treated animals compared to untreated ones. This finding represents the first evidence that urea exposure affects the expression of a key gene involved in neuronal cell formation during embryonic development.
]]>Environments doi: 10.3390/environments11030040
Authors: Oguz Sariyildiz Buddhi R. Gyawali George F. Antonious Kenneth Semmens Demetrio Zourarakis Maya P. Bhatt
Kentucky is one of the largest coal-producing states; surface coal mining has led to changes in natural land cover, soil loss, and water quality. This study explored relationships between actively mined and reclaimed areas, vegetation change, and water quality parameters. The study site evaluated 58 watersheds with Landsat-derived variables (reclamation age and percentage of mining, reclaimed forest, and reclaimed woods) as well as topographic variables (such as elevation, slope, drainage density, and infiltration). Water samples were collected in spring (n = 9), summer (n = 14), and fall (n = 58) 2017 to study changes in water quality variables (SO42−, alkalinity, conductivity, Ca2+, Mg2+, Mn2+, Al3+, and Fe2+, Fe3+) in response to changes in land cover. Pearson correlation analyses indicated that conductivity has strong to very strong relationships with water quality variables related to coal mining (except Al3+, Fe2+, Fe3+, Mn2+, elevation, slope, and drainage density) and land cover variables. In addition, separate regression analyses were performed, with conductivity values based on samples collected in the fall. First, conductivity responses to mining percentage, reclamation age and topographic variables were examined (adjusted R2 = 0.818, p < 0.01). Next, vegetation cover change parameters were added to the same model, which yielded slightly improved R2 (adjusted R2 = 0.826, p < 0.01). Finally, reclamation age and mining percentages were used to explain the quantity of reclaimed forested areas as a percentage of watersheds. The model was significant (p < 0.01), with an adjusted R2 value of 0.641. Results suggest that the quantity (area as a percentage) of reclaimed forests may be a predictor of the mining percentage and reclamation age. This study indicated that conductivity is a predictable water quality indicator that is highly associated with Coal-Mine-Related Stream Chemistry in areas where agriculture and urban development are limited. Water quality is not suitable for various purposes due to the presence of contaminants, especially in mined sites. These findings may help the scientific community and key state and federal agencies improve their understanding of water quality attributes in watersheds affected by coal mining, as well as refine land reclamation practices more effectively while such practices are in action.
]]>Environments doi: 10.3390/environments11030039
Authors: Tanya Baycheva-Merger Andy Selter Chris Seijger Sabeth Häublein
In Germany, modern digital technologies like Internet of Things (IoT) have been increasingly promoted for better environmental and natural resources management through “smart” monitoring and real-time data. However, adopting such advanced technologies is complex and brings a wide array of risks and challenges, and it remains unclear whether local actors are in fact willing and sufficiently equipped to adopt them. Using the Motivations and Abilities (MOTA) framework, and quantitative data collection and analysis methods, this study explores the motivations and abilities of German local (governmental) actors by focusing on the adoption of IoT-based forest and water monitoring systems. The findings reveal an early-stage adoption of IoT environmental monitoring, with limited awareness and no plans for adoption. The lack of willingness, however, is not attributed to a lack of motivation; it is, rather, influenced by perceived insufficient financial and technical capacities and resources. This study provides novel insights for understanding the complex relationship between actors’ behavior and the adoption of advanced digital technologies in the realm of environmental and natural resources management. The results provide a robust foundation for future research, and inform policy and practice aimed at facilitating digitalized natural resources management.
]]>Environments doi: 10.3390/environments11030038
Authors: Kunle Babaremu Adedapo Adediji Nmesoma Olumba Silifat Okoya Esther Akinlabi Muyiwa Oyinlola
The impact of plastic pollution on the world and its inhabitants is yet to be fully measured. Significant quantities of microplastics and nanoplastics have been found in human organs, and many diseases have been traced to their presence. Even human placentas have been found to contain microplastics. This study examines the recycling landscape, advanced reprocessing techniques, and technical challenges in this industry. It points out the top recyclable types of plastics (such as high-density polyethylene, polyethylene terephthalate, and thermoplastic elastomers) by analyzing their different recycling capacities globally. It highlights the most advisable recycling techniques by identifying those most successful, least environmentally damaging, and easiest. Mechanical recycling is arguably the easiest and most common recycling technique. This study examines mechanical reprocessing technologies for construction materials, composite boards, additive manufacturing, and other applications. It also points out prevailing setbacks of these approaches and analyzes different solutions. Promising recycling processes are suggested for further investigation.
]]>Environments doi: 10.3390/environments11020037
Authors: António Louvado Victor Galhano Fernanda Lima Daniel F. R. Cleary Isabel Lopes Newton C. M. Gomes Francisco J. R. C. Coelho
Ecosystem functioning depends on complex interactions between microorganisms, hosts, and the environment. Changes in environmental conditions (e.g., ocean acidification) in combination with anthropogenic pollution have been shown to affect the composition and function of free-living microbial communities, but little is known about the effects these stressors on host-associated communities. This study aims to characterize the response of host-associated bacterial communities of the bottom-dwelling polychaete Hediste diversicolor and the epibenthic gastropod Peringia ulvae to oil contamination and reduced seawater pH. The independent and interactive effects of both stressors were simulated under controlled conditions. The response of host-associated bacterial communities was assessed using the high-throughput sequencing of the 16S rRNA gene and several biochemical markers related to host metabolic pathways, e.g., neurotransmission, anaerobic metabolism, biotransformation, oxidative stress, and energy consumption. In H. diversicolor, reduced seawater pH was associated with a high relative abundance of Cyanobacteria, while in P. ulvae oil contamination was associated with a reduction in the relative abundance of Chitinophagales. In P. ulvae, enrichment with oil hydrocarbon-degrading bacteria suggests a possible role of these organisms in the dispersion of oil hydrocarbon degraders. Furthermore, oil supplementation shifted some specific biochemical markers of gastropods related to oxidative stress and energy consumption, which suggests host stress. In general, the bacterial communities and biochemical markers of the gastropod were more affected by stressors than those of the polychaete. Overall, this study contributes to a better understanding of the response of host-associated bacterial communities of benthic macrofauna to anthropogenic contamination and environmental change.
]]>Environments doi: 10.3390/environments11020036
Authors: Maria Cristina Collivignarelli Stefano Bellazzi Francesca Maria Caccamo Marco Sordi Barbara Crotti Alessandro Abbà Marco Baldi
This paper focuses on using a novel approach to assess the statistical variability of management data from an aerobic thermophilic biological plant (AWTP) utilizing a fluidized bed biological reactor. A proper statistical characterization of full-scale thermophilic biological systems, in fact, may inform process optimization in the light of a future automation of treatment plants. We present a case study that spans the period from 2018 to 2023 and encompasses various high-strength aqueous waste (AW) in continuous mode. Key aspects of the proposed analytical approach include: (i) utilizing advanced descriptive statistics, such as violin graphs, to depict the variability of monitored parameters over five years; (ii) conducting correlation analyses (Spearman and Pearson correlation matrices) specifically focusing on nitrogenous forms within the AW; (iii) applying multivariate statistical analysis to assess the correlation between pollutants released and the plant’s energy and oxygen consumption; and (iv) reconstructing parameter trends by considering periodic and random components, thus enhancing the understanding of the system’s behavior over time. The findings presented in this paper offer valuable insights into the performance and optimization of AWTPs, potentially leading to a proper planning of the loads and consequent feeding of the plants. If properly enacted, our approach may provide a significant contribution to the field of aqueous waste management.
]]>Environments doi: 10.3390/environments11020035
Authors: Sandro Xavier de Campos Manuel Soto
Constructed wetland systems (CWs) are technologies based on natural processes for pollutant removal and have been more and more accepted in the treatment of domestic and industrial wastewater. This study selected and reviewed articles published in the last six years involving the use of different CW conceptions and their association with other technologies to treat different effluents and evaluated the quality of the effluents for reuse. From a total of 81 articles reviewed, 41 presented quantitative data on the quality of the treated effluent in relation to the requirements of the reuse regulations in different countries of the world. CWs can be used to treat gray water and runoff water, as well as domestic and industrial effluents with the purpose of reusing them. While studies on the removal of new chemical and biological substances have increased, challenges are associated with the optimization of CWs to improve the removal of pathogens and new contaminants that have appeared more recently. The potential for the improved removal of those pollutants lies in the association of CWs with conventional and advanced technologies in new configurations. We concluded that studies related to the reuse of effluents using CWs are in constant evolution, with experiments at different scales. The perspectives are promising since CWs are an economic, environmentally friendly, and efficient technology to help in the mitigation of water scarcity problems imposed by climate changes.
]]>Environments doi: 10.3390/environments11020034
Authors: Monica Shree Chandramohan Isabel Martinho da Silva Joaquim Esteves da Silva
Urban agricultural soils have important social, environmental, and economic roles in big cities, contributing to their sustainability. However, food production in urban soils may be compromised due to soil pollution that resulted from decades of industrial, non-regulated environmental activity and mobile transport. In this study, 12 soils from the urban agricultural area of Rome (Italy) were analyzed for the potentially toxic elements (PTEs) Be, Ba, Pb, Co, Ni, V, Zn, Hg, Cd, As, Cu, and Cr. All but one of the soils under analysis were characterized by at least one PTE concentration above the threshold limit defined by the D.Lgs 152/06 for agricultural soils. Multivariate analysis showed that the soils could be classified into five clusters: clusters I and II had relatively lower mean PTE concentrations; clusters III, IV, and V had relatively higher mean PTE concentrations with several PTE concentrations above the threshold proposed by ILD. Three factors contributing to the variability of the PTE’s concentration in the soils under investigation were identified: a geological factor related to PTE As, Ba, Be, and V; an anthropogenic factor related to Pb and Cu; and a mixed factor related to Co, Cr, Ni, and Zn. High PTE content may limit the utilization of urban soils for food production.
]]>Environments doi: 10.3390/environments11020033
Authors: Aleš Hrdina Dušan Romportl
Purely natural land formations are increasingly rare in today’s world, as most areas have been shaped, to varying degrees, by human influence over time. To better understand ongoing changes in the natural environment, we adopted an approach that involves identifying global systems with a significant anthropogenic component. In this study, we developed a new classification of Global Environmental Systems based on over 20 high-resolution datasets, covering abiotic, biotic, and anthropogenic conditions. We created abiotic, biotic, and anthropogenic classifications, each with ten classes. The combinations of these classes result in 169 distinct classes of Global Environmental Systems. This classification provides a suitable spatial framework for monitoring land use dynamics, biodiversity changes, global climate change impacts, and various processes exhibiting complex spatial patterns.
]]>Environments doi: 10.3390/environments11020032
Authors: Ulung Muhammad Sutopo Erda Rahmilaila Desfitri Yukio Hayakawa Shinji Kambara
Coal remains an important fuel for use in thermal power plants. However, coal-burning power plants produce large amounts of CFA, which contains TEs such as B, F, and Se, which are leached upon contact with water and act as potential polluters of aquifer systems and soil. To study the transformation of TEs, a thermodynamic calculation (FactSage 7.2) was used. Paper sludge ash was used as a calcium compound additive. The influence of blending a high-calcium additive on the environmental safety of TEs was investigated based on the effect of the mass addition ratio of PS ash. This study’s results confirmed that the leaching processes of TEs, namely (CaO)2(Al2O3), CaF2, Ca10(PO4)F2, and CaSeO4(H2O)2, were caused by the formation of B, F, and Se compounds during the leaching process. Thus, it is clear that calcium has the greatest influence on the transformation of TEs due to their reaction, which, in turn, minimizes the effects of the TEs’ release into the environment. The concentrations of TEs from the sample and addition of PS ash decreased slightly, indicating that the inhibition of TEs was enabled through the addition of PS ash. Although the PS ash YB had the highest calcium content, the PS ash YC gave the best results during the B and Se inhibition processes. The experimental observation was also evaluated for comparison. For the analysis of TEs’ leaching ratios using the thermodynamic calculation and experiment, the experimental results were lower than those initially predicted. These results will help us to choose the best available control technology to minimize the effects of TEs released into the environment.
]]>Environments doi: 10.3390/environments11020031
Authors: Donald Vineyard K.G. Karthikeyan Christy Davidson Phillip Barak
BioWin 6.0 does not accurately predict phosphorus (P) speciation in acidogenic anaerobic digesters under default kinetics characterization and parameterization. The accurate modeling of acid-phase digestion is needed to predict the performance of novel nutrient recovery technologies that act on these digester effluents. The main thrust of this work was to identify and correct the causes of inaccurate P partitioning and precipitation within BioWin models of acid-phase digestion reactors. A BioWin configuration including an organic acid digester was parameterized and recalibrated based on the known traits of acid-phase digestion and then validated against a full-scale digester in a municipal wastewater treatment plant. This digester, with pH 5.14 and 61–74% solubilized P, was predicted by BioWin default parameters to have only 27% soluble P and a net formation of P precipitates. Corrections to the polyphosphate-accumulating organism decay, endogenous product decay, hydrolysis rate, and brushite behavior resulted in 67% solubilization with no precipitate formation. Cabinet configurations showed similar behavior when modified to include an acid-phase digester under default parameters, but predictions were similarly amended by our parameter changes. This improved modeling technique should allow operators to effectively characterize acid digesters for their own treatment trains and allow engineers to predict the performance of novel nutrient recovery technologies acting on acidogenic digest.
]]>Environments doi: 10.3390/environments11020030
Authors: Joana C. Prata
Microplastics resulting from the fragmentation of plastics in electronic waste (e-waste) are an emerging but understudied environmental concern. This systematic review employs a Driver–Pressure–State–Impact–Response (DPSIR) framework to investigate the sources, prevalence, and environmental effects of e-waste microplastics, identifying knowledge gaps. The available literature on e-waste microplastics was retrieved from Scopus and Web of Science (n = 24), and trends in electrical and electronic equipment were retrieved from European Union databases. The growing incorporation of electronics into daily life results in a global annual growth rate of 3–4% for e-waste, of which only 17.4% is collected for recycling. E-waste microplastics are frequently found in soils near disposal or disassembly facilities, potentially leaching hazardous metals (e.g., Pb) or organic compounds (e.g., flame retardants). These microplastics contaminate the food chain and can have adverse effects on the soil and gut microbiome, organisms, and human health, either independently or associated with other chemicals. Responses include the implementation of regulations, improvement of waste management systems, and mitigation measures. Despite these concerns, the literature on the topic remains limited, emphasizing the need for additional research on the identification of e-waste microplastics and their toxicity.
]]>Environments doi: 10.3390/environments11020029
Authors: Serena Doni Grazia Masciandaro Cristina Macci Davide Manzi Giovan Battista Mattii Eleonora Cataldo Maria Gispert Francesca Vannucchi Eleonora Peruzzi
In semiarid environments, vine cultivation is a land use with a high impact with regard to soil erosion, loss of organic matter and biodiversity, contamination, and compaction. In addition, the wine supply chain produces a considerable quantity of organic waste, which remains as residues in the ecosystem. Within this context, we developed a sustainable vine management system to improve the efficient use of fertilisers by applying a by-product derived from the composting of winery wastes and zeolite. We evaluated the effects of the zeolite-based compost on the chemical, physical, and biochemical soil properties of a productive vineyard. Four treatments were set up and monitored for about two years. These were as follows: (1) Commercial compost (COM); (2) Zeolite (Z); (3) 30% zeolite and 70% winery waste compost (30 ZEO); (4) 10% zeolite and 90% winery waste compost (10 ZEO). The results demonstrated that the ZEO treatments could be considered a win–win solution able to improve soil water content, nutrient retention, carbon sequestration, and biochemical activity while also recycling wastes. In particular, 10 ZEO seems to be the amendment that best combines an improvement in soil biochemical properties with gradual and constant nutrient availability, thus satisfying, without exceeding, soil and plant needs.
]]>Environments doi: 10.3390/environments11020028
Authors: Spyros Beltaos
Timely release of flow from upstream hydropower generation facilities on the Peace River can enhance potential ice-jam flooding near the drying Peace–Athabasca Delta (PAD), a Ramsar wetland of international importance and homeland to Indigenous Peoples. An important consideration in deciding whether and when to commence a release is the celerity of the breakup front as it advances along the Peace River. Relevant historical data for a key stretch of the river are analyzed to determine average celerities, which can vary by an order of magnitude from year to year. Seven breakup events are identified that might have been candidates for a release, and the predictability of associated celerities is explored in terms of antecedent hydroclimatic variables, including cumulative winter snowfall, snow water equivalent on 1 April, ice cover thickness, coldness of the winter, and freezeup level. It is shown that celerity can be predicted to within a factor of two or less, with the freezeup level giving the best results. Three of the seven “promising” events culminated in PAD floods and were associated with the three highest celerities. The empirical findings are shown to generally align with physical understanding of breakup driving and resisting factors.
]]>Environments doi: 10.3390/environments11020027
Authors: Emmanuel Eze Alexander Siegmund
The foremost priority of the Sendai Framework for Disaster Risk Reduction (SFDRR) is the increased understanding of disaster risk and strengthening its management. Detailed insights into African disaster risk drivers and assessment of policies for Disaster Risk Reduction (DRR) are sparse, hence this study. Using the Index for Risk Management (INFORM) data for 2022, this study determines important disaster risk drivers in Africa using a random forest machine learning model. Violent conflicts, current and projected, emerge as the only hazard factor significantly predictive of disaster risk in Africa, from the analyzed data. Other factors are mostly the sub-components of lack of coping capacity. Furthermore, 25 policies of the 10 countries of very high disaster risk were analyzed to evaluate their inclusion of pre-identified disaster risk factors. The findings of this study depart from the viewpoint of giving natural hazards greater attention in African disaster risk literature. Moreover, identified disaster risk drivers in Africa coincide with the social dimension of disasters, and broader continental developmental and policy issues. As Africa grapples with the complex interplay of environmental, socioeconomic, and conflict-related factors shaping disaster risk, the imperative arises for the development and implementation of comprehensive policies aimed at poverty and vulnerability-reduction to foster resilience across the region.
]]>Environments doi: 10.3390/environments11020026
Authors: Gianniantonio Petruzzelli Francesca Pedron
Tungsten is an essential element for many cutting-edge industries. Its use is increasing, so much that it has become a “critical element”. With the increase in the use of tungsten, a possible increase in its presence in environmental matrices including soil is expected. In this research, we assessed the environmental availability and bioaccessibility of W in relation to soil properties. Four representative Mediterranean soils, collected in Italy, were spiked with tungsten and incubated for 12 months. In the spiked soils, the environmental availability of the element was determined by the Wenzel sequential extractions. The bioaccessibility was determined by the UBM (BARGE) method in both the gastric and intestinal phases. The findings indicated that the environmental availability is largely influenced by soil properties such as pH and organic matter, while a lower influence was discovered for bioaccessibility, particularly for the gastric phase. These differences could be ascribed to the characteristics of the extractants utilized in the various tests, in particular the pH values. These results could be a valuable reference to integrate with studies on really and not spiked contaminated soils, for the improvement of risk assessments and the development of strategies for remediating soils polluted with tungsten.
]]>Environments doi: 10.3390/environments11020025
Authors: Chonghee Lee Yong-Chul Jang Kyunghoon Choi Byeonghwan Kim Hakyun Song Youngsun Kwon
The recycling and proper management of PET bottles is needed to avoid plastic pollution, as well as to achieve a plastic circular economy. In this study, we examined the recycling system of PET bottles and their material flows by life cycle, from production to recycling and disposal under different scenarios with reduced consumption for PET bottles. In Korea, PET bottle recycling has been managed by the extended producer responsibility system since 2003. As of 2021, annual usage of PET bottles per capita in Korea was estimated to be approximately 6.5 kg. The recycling rate of PET bottles after collection was determined to be 79% in 2021. However, recycled PET (or r-PET) from mechanical recycling is mostly used in low-grade PET applications such as short fibers, bands, and sheets. More than 112 thousand tons of r-PET chips would be needed to meet the 30% recycled content requirement in PET bottles in 2030 by regulation. Thus, there is an urgent need for high-quality secondary raw materials (i.e., food-grade) by adopting advanced sorting and recycling technologies for PET bottles with recycled content. PET bottle-to-bottle recycling practices can ensure the production of high-quality recycled materials and move Korea toward a plastic circular economy.
]]>Environments doi: 10.3390/environments11020024
Authors: Manfred Sager Oliver Wiche
The rare earth elements (REE) comprise a group of 16 chemically very similar elements that occur widespread in rocks, soils, and water bodies, share similar ionic radii to the essential element Ca2+, and consequently also occur in biota. Given that REE form mainly trivalent cations, they also share similarities to Al3+. Compared to their chemical cognate Ca, they have a higher reactivity. Thus, their accumulation in soils may constitute a severe environmental threat. Over the last decades, the increasing use of REE in modern technology and fertilizers raised concerns about the pollution of soils and water bodies, which led to a rapidly increasing number of publications dealing with REE toxicity to plants, animals and humans, the fate of REE in soil–plant systems, REE cycling in ecosystems and impacts of REE pollution on food security. This review aims to give an overview of the current knowledge on the occurrence of REE in the total environment, including relevant environmental processes governing their mobility, chemical speciation and transfer from abiotic compartments into biota. Beginning with an overview of analytical approaches, we summarize the current knowledge on the ecology of REE in the lithosphere, pedosphere, hydrosphere and biosphere, including impacts of soil pollution on food security and public health.
]]>Environments doi: 10.3390/environments11010023
Authors: Laura Canonica Grazia Cecchi Vittorio Capra Simone Di Piazza Alessandro Girelli Sandro Zappatore Mirca Zotti
The paper deals with the possible use of fungi to decontaminate polluted waters. Specifically, the focus is the selection of the most promising fungal strain capable of bioaccumulating arsenic, which is a globally widespread environmental contaminant. To this aim, allochthonous fungal strains from the ColD UNIGE JRU MIRRI strains collection were selected. Their capability to survive and accumulate this kind of pollutant was evaluated and compared with that of an autochthonous fungi set directly isolated from the arsenic polluted water. A preliminary screening at various concentrations of arsenic (0, 200, 400, 800, 1600 μg L−1) revealed that the best performing strains were Aspergillus niger and Penicillium expansum among the autochthonous strains and Aspergillus niger and Penicillium expansum among the allochthonous strains. Moreover, all the strains were subjected to bioaccumulation tests at a 1600 μg L−1 concentration. Local and allochthonous fungal strains showed different behaviors: the allochthonous strains grew rapidly and in a sustained way but without expressing any bioaccumulation activity. On the contrary, the indigenous fungi, despite a moderate growth, showed a good bioaccumulation capacity (in particular, Aspergillus niger). The results highlight the importance of employing native strains isolated from contaminated matrices to make a mycoremediation protocol more efficient.
]]>Environments doi: 10.3390/environments11010022
Authors: Teresa Sani Mauro Marini Alessandra Campanelli Mariana Machado Toffolo Stefano Goffredo Federica Grilli
The evaluation of the hydrography and biogeochemistry of the Adriatic Sea over the last century was summarized in this review to point out any changes in river runoff and provide an overview of the cause and effect of these trends on marine ecosystems. Although several rivers flow into the Adriatic, the most affected area is the northern Adriatic, where the Po River loads into the basin half of the total freshwater input, carrying river runoff and causing algal blooms and hypoxia phenomena. These fresh waters of the northern Adriatic flow predominantly along the entire western side, reaching the southernmost part of the basin up to the Mediterranean Sea. Here, and in the whole basin, variations in river runoff and nutrient concentration have been observed through the years. Starting from 1960 until the end of the century, an increase in nutrient discharge and phytoplankton activity was reported, with negative repercussions on local fisheries, species richness, and recreational activities within the basin. However, a recent decrease in river inflow has been observed along the coastal belt, which can trigger negative consequences for the food web of the marine ecosystem. These trends, more broadly, corroborate the vulnerability of the Adriatic Sea and stress the importance of implementing strategies for the defense of the relevant ecosystems within its confines.
]]>Environments doi: 10.3390/environments11010021
Authors: Luoana Florentina Pascu Bogdan Adrian Stănescu Marian Gabriel Gâsnac Lidia Kim
The present study is dedicated to the assessment of soil and vegetation pollution with toxic metals on a section of the oldest highway in Romania, which has been in operation for more 50 years. In the assessment, the limits of the national legislation were complied with, and the analysis was related to locally identified reference levels at a distance from the road, the main potential source of pollution. The average concentrations of toxic metals in the investigated soils had wide amplitudes, and the variations were quite large. The recorded values of the concentrations were at high or moderate levels compared to those in previous research. The contamination factor, geo-accumulation index and other calculated indices indicate the presence of pollution at a moderate level. The concentrations of toxic metals in the range 0.15–0.42 mg/kg d.m. for Cd; 2.00–6.04 mg/kg d.m. for arsenic, 16.20–76.27 mg/kg d.m. for Cu, 17.40–28.40 mg/kg d.m. for Ni, and 149.00–535.00 mg/kg d.m. for Zn exceeded the reference levels in the soil in at least one studied area. The concentrations of Zn at two observation points exceeded the alert threshold, indicating the presence of pollution caused by road traffic. Among the factors that can influence pollution, the following can be distinguished: the specifics of the areas and the activities carried out, the increase in cars transiting the highway, and the location in relation to the entrance or exit areas of the highway.
]]>Environments doi: 10.3390/environments11010020
Authors: Ramin Samiei-Fard Ahmad Heidari Patrick J. Drohan Shahla Mahmoodi Shirin Ghatrehsamani
This study addresses the escalating global concern surrounding land degradation (LD) and its far-reaching implications on water and nutrient availability, as well as on human health and well-being. Focused on the southeastern Caspian Sea region, this research employs a novel remote sensing geo-pedological methodology to comprehensively assess soil and land quality dynamics, particularly influenced by salts, and investigates the intricate relationship between LD and soil development. The study area, marked by a susceptibility to seawater level fluctuations and diverse landforms (lagoons, barriers, and coastal plains) offers a unique opportunity for geopedologic analysis. Utilizing particle size distribution data, six distinct landforms are identified, providing insights into the region’s complex sedimentary history. A soil quality assessment is conducted remotely through the calculation of two indexes—the Integrated Quality Index (IQI) and the Nemoro Quality Index (NQI)—employing both Total Data Set (TDS) and Minimum Data Set (MDS) methodologies. The investigation highlights the role of soluble salts in shaping soil quality, thereby influencing LD and development dynamics. The differentiation of landforms significantly enhances classification accuracy, providing a more nuanced understanding of the multifaceted factors governing LD. The study’s implications extend beyond the southeastern Caspian Sea region, and demonstrate that the potential for incorporating a geopedologic approach when assessing soil and land quality dynamics in arid regions globally. Our analytic approach can inform policymakers and land managers when making decisions to combat LD and foster sustainable land development. This research also contributes towards advancing knowledge in geopedology by providing a robust foundation for future studies aimed at enhancing land management practices in the face of ongoing environmental challenges.
]]>Environments doi: 10.3390/environments11010019
Authors: Valentin De Carsalade du Pont Amani Ben Azzouz Hind El Hadri Philippe Chéry Gaëtane Lespes
Copper (Cu) has been used to treat vines for a long time, which has led to its accumulation in vineyard soils. In the present work, the mobilization of copper from these soils and its transport, and diffusion outside the plots by drain water were investigated. For this, the distribution of copper between the dissolved and colloidal phases, and within the colloidal phase, of these waters was determined using an investigation strategy based on the coupling between a size separation technique, asymmetric flow field-flow fractionation, and several detectors. First, the total copper concentrations in water from different drains were monitored over a period of 2 years: Cu was mainly found in the fraction of < 450 nm. Then, the distribution of copper on the size continuum was more closely studied in water from one of the drains, sampled over a winter period. Between 45 and 75% of Cu was found in the 2–450 nm colloidal fraction. The <450 nm colloidal phase of the drain waters was found to be mainly composed of humic acids (~15 to 60 mg L−1) and clay-rich particles (~100 to 650 mg (Al) L−1). These particles also contained (hydr)oxides of iron and manganese. The concentrations of Fe and Mn were approximately 100 to 200 times lower than those of Al. The majority of humic acids had an apparent molar mass of ≤ 10 kDa. They were distributed along the size continuum: (i) in a population with an average size of ~20 nm, probably consisting of supramolecular entities, and (ii) associated with clay-rich particles with a size of ~120–200 nm. Copper was found to be complexed with humic acids and associated with clays via clay-humic complexes. Copper mobilization from the soil to the water and its transport to the drain water appeared governed by the soil humidity level and the rainfall.
]]>Environments doi: 10.3390/environments11010018
Authors: Paraskevas Parlakidis George S. Adamidis Georgios D. Gikas Sofia Vasiliou Melpomeni Kissa Konstantinos Doitsinis Christos Alexoudis Zisis Vryzas
The use of selective herbicides is one of the best methods for weed management. However, the extensive use of herbicides can have adverse impacts on non-target organisms. The goals of this study were to assess the dissipation kinetics, leaching, and ecological risk assessment of S-metolachlor and benfluralin residues in silty loam soil planted with chickpea (Cicer arietinum L.). The experimental setup included four different layers with four replications corresponding to an experimental randomized complete block design consisting of 16 plots. The application doses of S-metolachlor and benfluralin were 1350 and 1920 g a.i./ha, respectively, according to manufacturer recommendations. Soil samples were split into four depths, 0 to 20 cm (Layer A), 20 to 40 cm (Layer B), 40 to 60 cm (Layer C), and 60 to 80 cm (Layer D), to determine the dissipation kinetics and the leaching behavior of the herbicides. Gas chromatography coupled with the electron capture detector (GC-ECD) method was developed and validated for the determination of S-metolachlor and benfluralin residues in soil. The analytes were extracted from the soil with distilled water and ethyl acetate followed by solid-phase extraction (SPE). The limit of quantification (LOQ) of the method was 0.1 μg/g, and the recoveries of S-metolachlor and benfluralin were in the ranges 81% to 97% and 88% to 101%, respectively, with relative standard deviations (RSD) of less than 9.7%. The dissipation kinetics of S-metolachlor and benfluralin in soil (0–20 cm) followed first-order kinetics with half-lives of 21.66 and 30.13 days, respectively. The results for samples obtained from the 20–80 cm soil profile showed that both benfluralin and S-metolachlor presented high leaching, following preferential flow. Also, a soil ecological risk assessment was conducted in the top 0–20 cm soil profile, estimating the toxicity–exposure ratio (TER) for four soil organisms and the risk quotient (RQ). The mean herbicide levels found at the studied soil profile at 0 days (2 h) and 60 days of the experiment were used for risk assessment. In the first case, the mean pesticide concentration (MPC) gives a worst-case scenario (ws); in the second case, a dissipation scenario (ds) is given using the respective MPC. In all cases, both TER and RQ values showed that benfluralin corresponds to a higher risk than S-metolachlor for soil organisms.
]]>Environments doi: 10.3390/environments11010017
Authors: Eleonora Coppa Giulia Quagliata Rachele Venanzi Alessandro Bruschini Leonardo Bianchini Rodolfo Picchio Stefania Astolfi
The continuous growth of the population, along with climate change and the resulting surge in food demand, requires the development of alternative crop cultivation strategies that reduce the excessive use of freshwater for agricultural purposes. Biochar, which is a carbon-rich material made from organic waste through pyrolysis, has been recommended as a potential soil amendment to mitigate the negative effects of salinity. Biochar has unique properties such as high porosity, an ion exchange capacity, and the ability to retain water and nutrients. The purpose of this study was to evaluate the feasibility and effectiveness of using saline water for the cultivation of tomato plants (Solanum lycopersicum L.) and to investigate the potential use of biochar as a mitigation strategy for salinity-related issues in tomato cultivation. The concentration of NaCl during the experiment was 100 mM. We examined the impact of salt stress on plant growth, protein and chlorophyll content, the activation of the antioxidant response, and nutritional status. Our results indicated that salt treatments led to a significant accumulation of Na and Cl in shoots (regardless of the biochar addition) but did not result in a corresponding reduction in plant growth. However, the degree of oxidative damage caused by NaCl treatment, measured as malondialdehyde (MDA) accumulation, was reduced by biochar addition to the growth medium, most likely because of an increased guaiacol peroxidase (GPX) activity, which led to lower MDA accumulation. The strong positive effect of biochar on GPX activity could be reasonably attributed to increased Mo accumulation. In conclusion, the findings of this study represent a valuable starting point for developing crop management strategies based on biochar application to enhance plant performance under unfavorable conditions and reduce freshwater dependence in agriculture.
]]>Environments doi: 10.3390/environments11010016
Authors: Electra Kanellou Maria Papafotiou Costas Saitanis Garifalia Economou
Spontaneous plants are an integral part of the archaeological landscape. The indigenous vegetation of the archaeological landscape can play a significant role in preserving the atmosphere of a place, as well as an additional element for education and recreation. Spontaneous vegetation was recorded in seven archaeological sites around Greece. Field surveys were conducted over two vegetative seasons, spanning spring and autumn, and data were gathered from both the surfaces of the monuments and the open field areas adjacent to these monuments. Therophytes were dominant on and around monuments across all sites throughout both the spring and autumn recording seasons. The three most abundant botanical families, in terms of species, found within the archaeological sites were Fabaceae, Poaceae, and Asteraceae. Based on the calculation of species diversity and evenness indices, it appeared that the sites exhibited high values during the spring period. The cluster and principal component analyses revealed that plant species tend to form clusters associated with the hosting archaeological sites, while the archaeological sites create variations that concern the species growing within them. The above is particularly significant as it implies that each archaeological site possesses a distinct and unique floristic identity, which can be utilized as an additional layer for education and enjoyment, enhancing the economic sustainability of these sites.
]]>Environments doi: 10.3390/environments11010015
Authors: Alphus Dan Wilson Lisa Beth Forse
The effective monitoring and identification of existing subterranean termite populations within coarse woody debris and infested wood in service depend on accurate detection. These insects are often concealed within logs, wooden support structures, walls, and floorboards of buildings. In the absence of external mud tubes, termite infestations normally must be discovered through the destructive exploration of wooden structures to reveal the physical presence of these insect pests. Subterranean termite species are difficult to identify due to similarities in morphological features, but they may be readily distinguished by differences in volatile emissions from which they are divided into chemotaxonomic groups. Consequently, a more effective and nondestructive approach for detection and identification is to take advantage of unique species-specific emissions of volatile organic compounds (VOCs) from termite bodies which easily pass through wooden structures, allowing for detection without physical damage to wood and avoiding expensive DNA analysis. Electronic aroma detection analyses were conducted with an Aromascan A32S electronic-nose (e-nose) instrument, fitted with a 32-sensor conducting polymer (CP) sensor array, for discrimination between four common subterranean termite species based on differences in volatile emissions. Principal component analysis (PCA) of whole-body volatiles effectively distinguished between four termite species with the first two principal components accounting for more than 98% of sample variance (p < 0.01). Unique electronic aroma signature patterns (smellprints) were produced from e-nose sensor array outputs that allowed for the effective identification of termite species based on distinct differences in volatile metabolites released from their bodies. The e-nose methods were determined to be an improved means for rapidly detecting and monitoring termite species in wood. The method is cheaper than conventional detection methods and allows for the timelier discovery of species-specific termite infestations necessary for better management. The e-nose capability of detecting the Formosan termite in indoor living spaces was particularly significant due to the production of naphthalene, a volatile hazardous gas causing many adverse human health effects in enclosed environments.
]]>Environments doi: 10.3390/environments11010014
Authors: Amadeu D. S. Borges Miguel Oliveira Bruno M. M. Teixeira Frederico Branco
The growing demand for sustainable and environment-friendly energy sources resulted in extensive research in the field of renewable energy. Biomass, derived from organic materials such as agricultural waste, forestry products, and wastewater treatment plant (WWTP) sludge, holds great potential as a renewable energy resource that can reduce greenhouse gas emissions and offer sustainable solutions for energy production. This study focused on diverse biomass materials, including sludge from WWTPs, forest biomass, swine waste, cork powder, and biochar. Chemical and physicochemical characterizations were performed to understand their energy potential, highlighting their elemental composition, proximate analysis, and calorific values. Results showed that different biomasses have varying energy content, with biochar and cork powder emerging as high-energy materials with net heating values of 32.56 MJ/kg and 25.73 MJ/kg, respectively. WWTP sludge also demonstrated considerable potential with net heating values of around 14.87 MJ/kg to 17.44 MJ/kg. The relationships between biomass compositions and their heating values were explored, indicating the significance of low nitrogen and sulphur content and favourable carbon, hydrogen, and moisture balances for energy production. Additionally, this study looked into the possibility of mixing different biomasses to optimize their use and overcome limitations like high ash and moisture contents. Mixtures, such as “75% Santo Emilião WWTP Sludge + 25% Biochar,” showed impressive net heating values of approximately 21.032 MJ/kg and demonstrated reduced emissions during combustion. The study’s findings contribute to renewable energy research, offering insights into efficient and sustainable energy production processes and emphasizing the environmental benefits of biomass energy sources with low nitrogen and sulphur content.
]]>Environments doi: 10.3390/environments11010013
Authors: Daniela Losacco Claudia Campanale Mariangela Triozzi Carmine Massarelli Vito Felice Uricchio
Environmental pollution is caused by the unsustainable use of nitrogen (N) fertilizers and pesticides. Biochar (BC) is a carbon-based material applied to remove excess nutrients and pesticides from the environment. In pot experimental research, N fertilizer and pesticides alone and different biochar types were applied in the soil to evaluate cauliflower growth, soil quality, and leaching of agricultural contaminants. BC addition had increased nutrient availability based on feedstock origin. The surface structure results by SEM showed that the BC pore size was equal to 8.94 and 7.24 µm for mixed biochar and wood biochar, respectively. Nitrate concentrations in percolation water were 43.78 and 76.82 mg/L in mixed biochar and wood biochar, respectively. In soil treated with fertilizer and pesticides, NO3− was equal to 106.76 mg/L. Biochar’s binding with pesticides depends on its nature and structure. Adding wood biochar significantly reduced the leaching of fungicide compared to unamended soil, with a contraction of 327.86 and 3576 ng/L. Mixed biochar was more efficient for herbicide mitigation. FTIR was used to identify the functional groups on biochar-amended soil that play a role in the adsorption of agricultural compounds. Research shows that the BC application greatly affects the pesticide fate and N compounds of agricultural origin in soil.
]]>Environments doi: 10.3390/environments11010012
Authors: Inês Rodrigues Inês João Ferreira Regina M. B. O. Duarte Mário Diniz
Atmospheric particulate matter (PM) contains numerous constituents, including organic molecules, inorganic ions, and metals, with some of them possessing hazardous properties. Although mainly associated with air pollution, PM can rapidly be transferred from air and land to aquatic ecosystems, and consequently poses a risk to marine biota. The aim of this work was to evaluate how urban atmospheric PM (a standard reference mixture of urban PM, known to contain various organic and inorganic contaminants), suspended in seawater, may cause toxicity in marine organisms. To this purpose, mussels (Mytilus galloprovincialis) were exposed to two concentrations of suspended PM: 5.7 and 11.4 mg/L. After 7, 14, and 21 days, the animals were collected and the gills and digestive gland were analysed for stress biomarkers (CAT, SOD, GPX, GST, MDA, and Ubi). In general, the results show that exposure to different concentrations of PM caused an increase in GST, UBI, and GPx activities compared to their respective controls. The average activities of GST (87.65 ± 30.23 nmol/min/mg of total protein) in the gills of the animals exposed to 11.4 mg/L of PM increased after 21 days of exposure, and the activity of GPx (8.04 ± 3.09 nmol/min/mg of total protein) in the gills increased after 14 days in the animals exposed to 5.7 mg/L of PM. MDA results also provided information on cellular damage, with the most pronounced effects being found in the gills of exposed mussels. This study confirms that mussels are useful as “early warning” indicators of environmental contamination and provides important information on the effects of PM on marine biota.
]]>Environments doi: 10.3390/environments11010011
Authors: Konstantinos Katsas Dimitrios V. Diamantis Athena Linos Theodora Psaltopoulou Konstantinos Triantafyllou
Background: Limited evidence suggests a possible connection between natural or occupational exposure to chromium and an increased risk of gastrointestinal cancer. The main objective of this study is to investigate the literature regarding chromium exposure and gastrointestinal health issues (i.e., cancer). Methods: A systematic literature search was performed using PubMed, Google Scholar and ScienceDirect. Included observational studies were assessed for their risk of bias. Results: 16 observational studies and 7 reviews and meta-analyses met the inclusion criteria. Most of the studies investigated gastric and hepatocellular cancer, followed by colorectal, oral, esophageal and pancreatic cancer. There is a limited amount of evidence regarding non-malignant gastrointestinal diseases. Chromium exposure is suspected to increase gastric and colorectal cancer risks. We did not find any convincing indications for increases in oral, esophageal and hepatocellular cancer. Pancreatic, gallbladder and extrahepatic bile ducts carcinogenesis is likely not associated with chromium exposure. Conclusion: We found weak evidence that chromium exposure is associated with gastric and colorectal cancer. Our review also highlights the existing controversial evidence regarding oral, esophageal and hepatocellular cancer, as well as the gap in studies investigating small intestinal cancer and non-malignant gastrointestinal health issues.
]]>Environments doi: 10.3390/environments11010010
Authors: Zena Altahaan Daniel Dobslaw
The war-related contamination of water and sediment of the Tigris River within the urban area of Mosul leads to seasonally independent exceedances of the WHO limit values for Cd, Pb, Cr, and Ni in water and sediments. Furthermore, exceedances consistently occur for conductivity, PO43−, and SO42−, as well as sporadically for salinity and COD in water samples, and consistently for salinity in sediment samples, highlighting the direct impact of war (ammunition, ignition of sulfur fields), as well as indirect effects (destroyed wastewater infrastructure). Conflict-related emissions from the former conflict zone (S5–S7) are highlighted by the sudden increases in load from S4 to S5, although partially masked by the discharge of highly polluted water from the Khosr River (between S3 and S4). Due to the sorption of sediments and the presumed wind-borne discharge of highly polluted particles into the Tigris River, sediments at S10 on the southern edge of Mosul showed the highest pollutant loads. Significant statistical differences were observed through T-test analyses for E.C., TDS, salinity, COD, PO43−, NO3−, SO42−, Cd, Pb, Zn, Cr, and Ni for water samples, as well as salinity, Cd, Pb, Zn, and Cr for the sediment samples for seasonal comparison. Since the percentage difference of water samples at S4–S7 is smaller than upstream and downstream, contaminant input is not limited to rainwater but also occurs via the year-round infiltration of highly polluted wastewater from the surrounding valleys or suburban areas, as well as presumably polluted groundwater or windblown particulate input.
]]>Environments doi: 10.3390/environments11010009
Authors: Mioara Petrus Cristina Popa Ana-Maria Bratu
In urban areas, there has been a recent rise in ground-level ozone. Given its toxicity to both humans and the environment, the investigation of ozone pollution demands attention and should not be overlooked. Therefore, we conducted a study on ozone concentration in three distinct locations within the city of Magurele, Romania. This investigation considered variations in both structure and location during the spring and summer seasons, specifically at a breathing level of 1.5 m above the ground. Our analysis aimed to explore the impact of different locations and meteorological variables on ozone levels. The three measurement points were strategically positioned in diverse settings: within the city, in a forest, and within an industrial area. For these measurements, we used a laser spectroscopy system to determine the system’s sensitivity and selectivity and the influence of humidity in the detection of ozone in ambient air, which is a mixture of trace gases and water vapor. During the March–August campaign, the mean values in the three measuring points were 24.45 ± 16.44 ppb, 11.96 ± 3.80 ppb, and 95.01 ± 37.11 ppb. The peak concentrations of ozone were observed during the summer season. A diurnal analysis revealed that the atmospheric ozone levels were higher in the latter part of the day compared to the earlier part. These measurements suggest that the atmospheric temperature plays a significant role in tropospheric ozone production. Additionally, meteorological variables such as wind speed and direction were found to influence the ozone concentration. Remarkably, despite substantial traffic, the ozone levels remained consistently low throughout the entire period within the forested area. This observation may suggest the remarkable ability of trees to mitigate pollution levels.
]]>Environments doi: 10.3390/environments11010008
Authors: Tolulope Adesoji Annie Pearce
Green Infrastructure (GI) is rooted in ecology and cuts across multiple disciplines, including landscape architecture, environmental sciences, planning, policy, and engineering. Likewise, the definition of this concept also cuts across disciplines, which creates ambiguity around what GI is and what makes up GI in practice—for example, mistaking bioswales for regular tree planters or green space within communities in which they are installed. We undertook a systematic literature review of 38 peer-reviewed articles for this study using the Preferred Reporting Items for Systematic Reviews and Meta-Analysis (PRISMA) method to identify and synthesize the different disciplinary definitions of GI in the literature. This study also presents the types of GI systems mentioned in the peer-reviewed articles while identifying other benefits apart from the primary benefit of GI installation, which is stormwater management. The analysis revealed three clusters of GI definitions: (I) Interconnected natural areas and other open spaces, (II) Strategically planned natural and semi-natural areas, and (III) Decentralized systems and techniques. However, we got rid of the third cluster during the analysis because GI is known to be a decentralized system, and the definition region could not be tracked. These clusters represent a spectrum, one of which employs the structure of natural systems already in place to support human goals (bio-inclusivity). The other includes living systems as components within engineered solutions to achieve objectives (bio-integration). This review points to the need for an encompassing definition that cuts across disciplines with a consensus on the adoption and concise categorization of GI types and the multiple benefits they provide to humans and ecosystems. A consensus definition helps clear misconceptions and improve the understanding of GI, potentially improving receptivity towards these solutions within communities from a community member perspective.
]]>Environments doi: 10.3390/environments11010007
Authors: Laura Oliveira Cleto da Silva Aline Cássia da Fonseca Deicy Carolina Lozano Sivisaca Roberto Lyra Villas Boas Magali Ribeiro da Silva Gian Franco Capra Antonio Ganga Iraê Amaral Guerrini
Sewage sludge in natura is rich in nutrients, water, and organic matter and is essential for plant development. However, sewage sludge is diluted with water when composted, which could hamper plant growth. Therefore, supplementation with chemical fertilization may be necessary. This study evaluated the performance of composted sewage sludge (CSS) in producing Peltophorum dubium (Spreng.) Taub. seedlings with and without chemical fertilization via fertigation. The experiment was completely randomized in a 3 × 4 factorial scheme, with four fertigation (Ca(NO3)2(H2O)x: 0.87; (NH4)(H2PO4): 0.21; KCl: 0.47; (NH4)2SO4: 0.11; CH₄N₂O: 0.54; MgSO4: 0.52; Fe (13%): 0.03; B(OH)3: 6.00; CuSO4: 0.60; ZnSO4: 1.40; MnSO4: 6.00; Na2MoO4: 0.16 g L−1) doses: zero, standard, duplicate, and quadruplicate. In addition, three substrates were used: commercial substrate as the control, sewage sludge composted with sugarcane bagasse (LBC), and sewage sludge composted with Eucalyptus bark (LCE). The development of the seedlings was measured through the following variables: height, stem diameter, shoot/root ratio, leaf dry mass, root dry mass, total dry mass, green color index, the Dickson Quality Index, and the accumulation of nutrients in plant tissue. The seedlings produced with LCE that were subjected to the standard dose (1×) and the quadruplicate dose (4×) had the statistically highest mean values for most variables. Nevertheless, supplementation with chemical fertilization was necessary. Composted sewage sludge with eucalyptus bark, at the standard dosage, can be used for the commercial production of P. dubium seedlings, thus preventing the dangerous disposal of waste and strongly decreasing associated environmental hazards.
]]>Environments doi: 10.3390/environments11010006
Authors: Archana Johny Luís Pinto da Silva Carlos M. Pereira Joaquim C. G. Esteves da Silva
Biomass-derived carbon dots (CDs) are gaining much interest in recent times, as they provide a sustainable option with abundant availability, a low cost and tunable luminescence. Herein, we report a simple green synthesis method to produce highly fluorescent CDs from Eucalyptus globulus leaves using the one-pot hydrothermal approach. The fabricated CDs exhibit strong blue fluorescence with an excitation and emission maxima of 320 nm and 445 nm, respectively. The highest quantum yield (QY) obtained was 60.7%. With the reported optical properties and biocompatibility, CDs can be looked at as a promising candidate for potential biosensing applications. Moreover, we employed a life cycle assessment (LCA) cradle-to-gate approach to study the environmental impacts of the synthesis strategy used for the fabrication of CDs. The results point out that citric acid is the main hotspot in CD synthesis, regarding environmental impacts in most categories. This justifies the introduction of biomass, which reduces the amount of citric acid, thus leading to a more sustainable synthesis strategy for fabricating CDs.
]]>Environments doi: 10.3390/environments11010005
Authors: Aggelos Arvanitidis George S. Adamidis Paraskevas Parlakidis Georgios D. Gikas Christos Alexoudis Zisis Vryzas
The extensive use of fungicides causes their continuous release into the environment through spraying, soil seepage, leaching, and runoff. It has been observed that their residues can be found in foods and a variety of environmental compartments, such as wastewater, lakes, rivers, sediments, drinking water sources (groundwater and surface water), treated water, and drinking water. A sensitive GC-MS/MS, using dynamic multiple reaction monitoring, an analytical method was developed to determine 10 fungicides (azoxystrobin, boscalid, captan, cyproconazole, cyprodinil, hexaconazole, metalaxyl, myclobutanil, paclobutrazol, and prochloraz) in drinking water. A solid-phase extraction method for sample preparations and validations was performed according to SANTE 2019 guidelines. All fungicides demonstrated mild or medium matrix effects (ME) ranging from 40.1% to 11.2%. Their recoveries ranged between 60% and 110%. The limits of detection were equal to or higher than 0.01 μg/L. The method was employed on 18 drinking water samples collected from public taps in Northern Evros, Greece, distributed in six sampling sites. Azoxystrobin, boscalid, cyproconazole, cypronidil, metalaxyl, and paclobutrazol mean concentrations did not surpass the allowable limit of 0.1 μg/L set by EU in any sampling site. Hexaconazole mean concentrations were higher than 0.1 μg/L in one sampling site, while prochloraz mean concentration showed limit exceedances in all sampling sites. Captan was not detected in any sampling site, and myclobutanil mean concentrations demonstrated exceedances of the permissible limit in four sampling sites. The presence of fungicide residues in the studied area is mainly due to the occasional point-sources pollution and preferential flow. Additionally, through the use of water, the risk of pesticides to human health was assessed for two different age groups. The sum of the hazard quotient values in each of the studied drinking water was less than unity. Consequently, the acute risk assessment procedure regards the examined drinking water as safe. Nevertheless, as prochloraz carcinogenic risk values were higher than the safe limit suggested by USEPA for both age groups, the existence of prochloraz residues raises concerns about chronic toxicity.
]]>Environments doi: 10.3390/environments11010004
Authors: James Robert Hodgson Charlotte Benkowitz Brian C. Castellani Amanda Ellison Rammina Yassaie Helen Twohig Roshni Bhudia Otto-Emil Ilmari Jutila Sally Fowler-Davis
Environmental and public health research has given considerable attention to the impact of air quality on brain health, with systematic reviews being widespread. No literature review has been conducted for cognitive frailty—a multidimensional syndrome combining physical frailty and cognitive impairment and their apparent co-dependence, linked to increased vulnerability and adverse health outcomes, including dementia. Instead, cognitive decline and frailty are implicitly explored through research on air quality and comorbid cognitive and physical decline in elderly populations. A scoping review was conducted to explore the need for a systematic review. Combining the Arksey and O’Malley, and PRISMA-ScR checklist, a scoping review of SCOPUS using ‘cogniti*’ + ‘resilience’ + ‘air quality’ or ‘cogniti*’ + ‘ageing’ + ‘air quality’ resulted in n = 2503 articles, screened and reduced using inclusion and exclusion criteria, to n = 16 articles. Air quality appears to be a critical risk factor for cognitive decline, even at air quality levels below WHO targets. Moderate long-term ambient air pollution appears linked to increased risk of cognitive frailty, suggesting earlier and more active interventions to protect older people. There are varied effects on cognition across the life course, with both emotional and functional impacts. Effects may be more detrimental to elderly people with existing conditions, including economic and health inequalities. Generalisation of results is limited due to the absence of a dose–response, variations in methods, controlling for comorbid effects, and variance across studies. No literature review has been performed for cognitive frailty, largely due to the fact that it is not presently treated as an explicit outcome. The findings support the need for more research and a more extensive summary of the literature but suggest that there is worsening cognitive function over the life course as a result of increased PM2.5 concentrations. Furthermore, air quality appears to be a critical risk factor even at levels below World Health Organisation targets.
]]>Environments doi: 10.3390/environments11010003
Authors: Cheng Zhou Sisi Deng Lei Xu Xiang Liu Chunbo Wang Junjun Chang
Dianchi Lake and Yilong Lake, two prominent plateau lakes in Yunnan Province, China, have suffered from Microcystis and Cylindrospermopsis blooms for decades. While cyanobacteria harvest boats utilizing cationic polyacrylamide (CPAM) flocculation and screen filtration have been proven effective for harvesting Microcystis biomass in Dianchi Lake, they struggle against Cylindrospermopsis blooms in Yilong Lake. This study systematically compared the removal of Microcystis and Cylindrospermopsis blooms using flocculation–filtration treatment, aiming to identify key factors influencing flocculation and propose enhancements to improve treatment efficiency for Cylindrospermopsis blooms. The reduction of turbidity, OD680, biovolume and phytoplankton density all revealed significantly better treatment efficiency for Microcystis blooms compared to Cylindrospermopsis blooms. In Dianchi Lake, 1 mg/L CPAM achieved a 95% turbidity reduction, while in Yilong Lake, even with 4.0 mg/L CPAM, the removal efficiency remained below 90%. Post-treatment, Dianchi Lake’s water quality showed substantial improvements, including over 50% reductions in total nitrogen, total phosphorus, permanganate index, and chemical oxygen demand. Conversely, nutrient level reductions were limited in Yilong Lake’s treated water. The average molecular weight of dissolved organic matters (DOM) in Yilong Lake was notably smaller than in Dianchi Lake. The treatment selectively removed high molecular weight, microbial-sourced, and protein-like DOM components, leading to a decrease in average molecular weight and an increase in humification index (HIX) in both lakes. Excessive humic matters in the water of Yilong Lake was found to hamper algae flocculation significantly. Introducing additional acidic polysaccharides or oxidants emerged as potential strategies to enhance Yilong Lake’s treatment efficiency.
]]>Environments doi: 10.3390/environments11010002
Authors: Umut Şen Catarina Nobre Marta Martins Margarida Gonçalves Helena Pereira
Bark is a heterogeneous solid material comprising mainly of phloem and cork fractions. These fractions differ in chemical composition and anatomical structure, and value-added activated carbons produced from these fractions have different surface properties. Low-temperature pyrolysis was shown to be a promising method for producing activated carbon precursors from bark fractions at higher yields than conventional slow pyrolysis. Here, we produced mesoporous activated carbons (ACs) from cork and phloem fractions of Quercus cerris bark by low-temperature pyrolysis followed by steam activation at 900 °C. The results showed steam-activation of biochars from Q. cerris bark fractions yielded ACs with acceptable surface properties. The ACs contained 9.9% and 23.3% ash content, and specific surface areas of 201 m2 g−1 and 512 m2 g−1 for cork and phloem fractions, respectively. Calcium was the principal inorganic component of ACs, followed by potassium, silicon, and iron. Surface functional groups of bark fractions and biochars were lost during steam activation, as evidenced by FT-IR spectroscopy. The burnout temperatures of cork and phloem ACs were 726 °C and 736 °C, respectively. The ACs showed a high methylene blue and methyl orange adsorption capacity, with the removal of 80% and 90% of methylene blue and 58% and 68% of methyl orange after 48 h for cork and phloem ACs, respectively.
]]>Environments doi: 10.3390/environments11010001
Authors: Matteo Pallottini Sarah Pagliarini Marianna Catasti Leonardo Giontella Gianandrea La Porta Roberta Selvaggi Elda Gaino Leonardo Spacone Alessandro Maria Di Giulio Arshad Ali Enzo Goretti
The positive phototaxis showed by adults of some pestiferous chironomid species, annoying to waterfront residents and businesses, was investigated at Lake Trasimeno (Italy) to develop a strategy against their massive swarms. Two experimental devices (ChiroTraps), located at Passignano sul Trasimeno (PA) and at Sant’Arcangelo (SA), were employed in 2019 and 2020. The total biomass attracted by the traps amounted to 6498.78 g at PA and to 8597.05 g at SA. Chironomids biomass constituted 99.66% and 96.59% of the biomass in these sites, respectively. Only a few specimens of other fauna except chironomids were found at PA. In contrast, the values at SA were considerable, being 91- and 35-fold (number of taxa and weight, respectively) higher than in PA. These results demonstrated that exploiting the light attraction behaviour of adult chironomids is an efficient method for managing their pestiferous populations, thereby reducing the necessity of using insecticides. By comparing the biodiversity in the two sites, it was evident that the differences were linked primarily to the environmental conditions. Finally, it is suggested that light trapping systems should be located in urban centres or floated on the lake surface to maximise the efficiency of trapping chironomids and minimising the impact on biodiversity.
]]>Environments doi: 10.3390/environments10120224
Authors: Dani Khoury Maurice Millet Yasmine Jabali Olivier Delhomme
Studies concerning fog water have been rapidly increasing due to its negative impacts on different environmental processes. However, fog water harvesting has become beneficial in various countries to overcome water scarcity. Accurate fog forecasting remains a challenging issue due to its spatio-temporal variability and uncertainties despite the development and efforts made to understand its chemistry and microphysics. The literature proved that the decrease in fog frequency over time in most countries is mainly attributed to the improvement in air quality or the change in regional climatic conditions. The current fog review summarizes its different types and collectors, life cycle, and impacts, the effects of aerosols, and the latest results concerning its forecast challenges and frequency. It also highlights the major chemical processes along with the main field studies performed on fog water. The aim of this work is not to provide a criticism about fog but to present a general comprehensive review of its physical and chemical aspects covering up to 330 research and review papers aimed to serve as a basis for new challenges and findings about fog water.
]]>Environments doi: 10.3390/environments10120223
Authors: Jeff Gearhart Simone Sagovac Tian Xia Md Kamrul Islam Albert Shim Sung-Hee Seo Melissa Cooper Sargent Natalie R. Sampson Jacob Napieralski Ika Danielson Stuart Batterman
Fugitive dust (FD) is a nuisance and potential health issue, particularly in environmental justice communities that can experience high levels of contaminated FD. This community-initiated study examined FD from a scrap metal processor in Detroit, Michigan, to determine whether the FD was contaminated, how it migrated through the community, whether wipe or composite road dust samples were preferable, and whether literature profiles adequately characterized this source. The study was motivated by community concerns, as well as a massive subsidence/upheaval event resulting from excessive accumulation of mill scale, which is a type of scrap metal, at the facility. We collected 57 wipe samples from windows and other surfaces, and 20 composite road dust and surface soil samples, which were analyzed by X-ray fluorescence. Concentrations were expressed using the fraction of the reconstructed mass. We also compared results to air quality monitoring data and calculated pollution indices and enrichment factors. Samples collected near the processor had high levels of Cr, Cu, Fe, Ni, Sr, and Zn compared with background soils, and levels remained elevated in residential areas several blocks distant. Composite road dust/sediment samples appeared preferable to wipe samples for chemical characterization. The available chemical profiles did not match the FD composition, suggesting the need for local profiles. The high level of Fe, which is consistent with mill scale, was a novel finding and caused the road dust to exceed health protection screening levels. Numerous metal scrap facilities operate locally and nationally, and our results show the need to improve controls to limit or eliminate FD emissions from industrial sources using enforced policies that reduce dust generation and truck track-out.
]]>Environments doi: 10.3390/environments10120222
Authors: Kanoko Takahashi Ryosuke Fujinuma Tomoyasu Yoshitomi Yasuo Shimizu Makito Kobayashi
Various artificial materials and facilities are sources of microplastics, including artificial turf sports fields. In artificial turf fields, polyethylene fibers are attached to a basal cloth with adhesives. In the present study, we investigated whether the fibers in the field were detached from the basal cloth or torn in the field, and whether they moved to the surrounding ditches that were connected to sewage pipes. In the field, we collected fibers shorter in length compared to the original and these were free from basal cloth, indicating the tearing of the fibers due to players’ activities. We also collected fibers from the ditches, which indicated a migration of the fibers from the field into the ditches. These results suggest that the fibers in ditches could enter sewage treatment plants and be released into the aquatic environment as microplastics. We also examined whether goldfish, Carassius auratus, ingested these fibers, and observed that the fish ingested them with feed while the fish did not without feed. These results indicate that the fiber ingestion by the fish occurred unintentionally when they swallowed their feed. The present study demonstrated that artificial turf fibers in sports fields could turn into microplastics that can be ingested by wild fishes.
]]>Environments doi: 10.3390/environments10120221
Authors: Lena Hoffmann Keno K. Bressem Jonas Cittadino Christopher Rueger Phillip Suwalski Jakob Meinel Simon Funken Felix Busch
Climate change mitigation depends on actions that affect the public interest and lead to widespread changes in public attitudes and behavior. With the global outbreak of the COVID-19 pandemic, humanity faced a more imminent threat to its well-being and viability. This retrospective cross-sectional study examines how public interest in climate change was attenuated by the severity of the COVID-19 pandemic using Google Trends Search Volume Index (SVI), weather, and climate data on a United States state-level basis during the first two years of the pandemic from 2020 to 2022. To identify channels through which the COVID-19 pandemic affected information demand on climate change, a novel fixed effect regression model of public climate change interest was developed. The measure captures changes in the climate change SVI independent of weather and climate conditions, comprising pandemic-related changes in living circumstances such as COVID-19-related cases and deaths, mask mandates, and the proportion of the vaccinated population. Our results indicate that public interest in climate change was systematically attenuated by the severity of the COVID-19 pandemic. In addition, this study provides an approach for identifying drivers of public interest in climate change.
]]>Environments doi: 10.3390/environments10120220
Authors: Rémi Bouchiat Etienne Veignie Fabien Kaczmarek Julien Dorchy Anne-Danièle Fortunato Catherine Rafin
Water is an essential resource for the functioning of society, where it is involved in key areas such as domestic use, agriculture, energy production, industry, and transport. Climate change exacerbates water scarcity. In the context of preserving water resources, effluents from the automobile sector need to be deeply considered due to their environmental impacts. This review focuses especially on the water effluents generated by car workshops. In car workshops, daily floor washing waters containing organic pollutants, either from vehicle components or from products used for maintenance and repair, can represent large volumes of water (between 15 L and 50 L per day) that are discharged into the wastewater system. These particular industrial organic effluents are not well characterized and can represent severe environmental risks. The aim of this review is to help automotive maintenance and repair professionals better manage these industrial organic effluents. We first describe the potential sources of organic pollution emissions in car workshops with the purpose of identifying the organic compounds to be monitored as a priority in the wash water. Then, we apply a risk prevention management tool, based on the criticality matrix, to identify products with a high risk of leaking onto the ground in order to limit organic pollutants at the source.
]]>Environments doi: 10.3390/environments10120219
Authors: Graziella Orso Roberta Imperatore Elena Coccia Gianluca Rinaldi Domenico Cicchella Marina Paolucci
The aim of the present study was to evaluate the wild freshwater fish health status using a vast array of biomarkers as predictive factors of pollutant exposure. The European eel (Anguilla anguilla) and brown trout (Salmo trutta fario), resident in rivers with different degrees of pollution in the South of Italy (Picentino River with good environmental quality and Tusciano River with low environmental quality), were examined using biometric parameters, histopathological and immunohistochemical biomarkers to evaluate the health status and a possible correlation with the water quality. Several alterations identified in the liver positively correlated with water and soil pollutants: hemorrhage (p ≤ 0.05), cytoplasmic vacuolization (p ≤ 0.01), hemosiderosis (p ≤ 0.05), irregular arrangement of hepatocytes (p ≤ 0.01), lipid accumulation (p ≤ 0.05), necrosis (p ≤ 0.01), cellular hyperplasia (p ≤ 0.05), leukocyte infiltration (p ≤ 0.01) and melanomacrophages centers (MMC) (p ≤ 0.01). In the spleen, only hemosiderosis correlated with water and soil pollutants (p ≤ 0.05). The inflammatory biomarker tumor necrosis factor α (TNFα) and ciclooxigenase 2 (COX2) responded to the environmental pollution, as well as the oxidative stress biomarkers superoxide dismutase (SOD2) and 8-Hydroxy-2′-deoxyguanosine (8-OHdG). Erythrocytic nuclear abnormalities and erythrocytic cellular abnormalities were found to be significantly higher in the blood of both the European eel (p < 0.0001) and brown trout (p < 0.001) in the Tusciano River compared with the Picentino River. Taken together, these results outline the need to increase the number of suitable biomarkers to assess fish health and reinforce the importance of employing additional biomarkers in biomonitoring programs that can be applied to evaluate water quality and in environmental assessment around the world.
]]>Environments doi: 10.3390/environments10120218
Authors: Kenneth Chan Paul Matthews Kamran Munir
This paper presents a new framework, “colours-of-the-wind” (COLD), which is designed to estimate air quality based on images from meteorological cameras, data analytics techniques, and the application of deep learning. Existing air quality estimation systems mainly rely on physical monitoring stations, which are limited by the monitoring stations’ physical constraints. Instead of collecting data from environmental monitoring stations, COLD collects air quality data from meteorological cameras. This approach can collect data from any location where a camera could capture a reliable image, which is otherwise not collectable by the physical environmental monitoring station(s). This approach can also avoid bias due to the location of data collection. The system is evaluated by building a prototype based on the Air Quality Health Index from the Hong Kong Observatory. This is one of the unique data-analytic frameworks based on such air quality measurement. The COLD’s air quality estimation is also based on AQHI, the first machine learning-based estimation framework that generates AQHI as the proposed output. Experimental results suggest that the approach adopted by the COLD prototype is feasible and has some promising outcomes. The results also suggest possible parameters for the CNN model used for the training and analyses of the images.
]]>Environments doi: 10.3390/environments10120217
Authors: Paulo Alexandre Costa Rocha Victor Oliveira Santos Jesse Van Griensven Thé Bahram Gharabaghi
Dissolved oxygen (DO) is a key indicator of water quality and the health of an aquatic ecosystem. Aspiring to reach a more accurate forecasting approach for DO levels of natural streams, the present work proposes new graph-based and transformer-based deep learning models. The models were trained and validated using a network of real-time hydrometric and water quality monitoring stations for the Credit River Watershed, Ontario, Canada, and the results were compared with both benchmarking and state-of-the-art approaches. The proposed new Graph Neural Network Sample and Aggregate (GNN-SAGE) model was the best-performing approach, reaching coefficient of determination (R2) and root mean squared error (RMSE) values of 97% and 0.34 mg/L, respectively, when compared with benchmarking models. The findings from the Shapley additive explanations (SHAP) indicated that the GNN-SAGE benefited from spatiotemporal information from the surrounding stations, improving the model’s results. Furthermore, temperature has been found to be a major input attribute for determining future DO levels. The results established that the proposed GNN-SAGE model outperforms the accuracy of existing models for DO forecasting, with great potential for real-time water quality management in urban watersheds.
]]>Environments doi: 10.3390/environments10120216
Authors: Omid M. Ghoochani Hamed Eskandari Damaneh Hadi Eskandari Damaneh Mansour Ghanian Matthew Cotton
This study uses an Integrated Agent-Centered (IAC) framework to investigate the socio-psychological drivers of Iranian farmers’ unsustainable groundwater management practices. Empirical land use change analysis of US Geological Survey Landsat satellite images of the Jaz-Murian wetland region for 1990, 2010, and 2022, is combined with community surveys conducted with randomly selected farmers in five townships within the region (n = 356). Visual analysis reveals dramatic increases in agricultural land coverage, diminished water bodies, and increased salt lands over the 32-year sampled period. We use survey data to explain the socio-psychological drivers of unsustainable groundwater use that lead to these adverse environmental changes. In the IAC survey analysis, we find that variables for “expectation” and “subjective culture” have a negative influence on pro-environmental “intention”. “Intention” and “habit” have a positive influence and “contextual factors” have a negative influence on the drivers of “unsustainable water use behavior”. We conclude that situational influences, habitual process, intentional process, and normative processes must be considered together to alleviate pressure on wetland ecosystems. Policy makers must provide effective agricultural extension training, deliberative dialogue amongst farmer networks, well-governed local water markets and financial support to shift farmer short-termist economic gain-thinking towards socially-supported pro-environmental habits over the longer term.
]]>Environments doi: 10.3390/environments10120215
Authors: Ying-Chien Chung Chih-Yu Chen
We developed a system combining visible-light photocatalysis with biological treatment for the continuous removal of phthalate esters (PAEs) from both synthetic and real aquaculture wastewater. We investigated the effects of different operating factors, including the coexistence of glucose or PAEs, on individual PAE removal by using a photobiological system (PBS). In wastewater containing a mixture of PAEs, that is, containing di-(2-ethylhexyl)phthalate (DEHP), dibutyl phthalate (DBP), and dimethyl phthalate (DMP), a coimmobilized bioreactor system comprising the bacterium Pseudomonas putida and the microalga Chlorella vulgaris demonstrated a higher removal efficiency than immobilized P. putida alone or a coculture of immobilized P. putida and suspended C. vulgaris did. The PBS employed for the continuous treatment of real aquaculture wastewater containing DEHP (0.62 ± 0.05 mg/L), DBP (8.7 ± 0.9 mg/L), and DMP (17.4 ± 1.5 mg/L) achieved at least 99.5% PAE removal and 99.2% mineralization efficiency under optimal operating conditions. After 42 days of treatment, inoculated Pseudomonas (98.12%) remained the predominant genus in the bioreactor. The results reveal that the symbiotic microalgal–bacterial system is a feasible alternative to a pure P. putida immobilized bioreactor for reducing CO2 emissions from mineralized PAEs through microalgal activity.
]]>Environments doi: 10.3390/environments10120214
Authors: Ido Nir Vladislav Shepelev Lilach Rosh Amir Lybman Liat Aviram Tal Amitay-Rosen Hadar Rotter
Impregnated activated carbon (IAC) is an efficient adsorbent for the filtration of hazardous gases from the air. However, it tends to lose its efficiency after exposure to high humidity, where it adsorbs water molecules. Water adsorption causes changes in metal impregnation, resulting in a loss of adsorption efficiency for certain toxic gases, particularly gases that are adsorbed via chemisorption. Here, an innovative method was developed for the regeneration and reactivation of aged IAC. The method is based on dripping a regeneration solution composed of ammonium hydroxide and ammonium carbonate onto the aged IAC. The developed regeneration method was applied to ASZMT, a common commercially used IAC, that had undergone accelerated aging for six months. After the regeneration process, the protection capacity of the IAC against cyanogen chloride (CK) and toluene was almost fully restored to its initial value. Elemental analysis by energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) showed that after the regeneration procedure, the concentrations of zinc and copper on the external surface of the IAC were decreased. This provides evidence that they were partially incorporated back into the pores. It is reasonable to believe that the developed method can be applied to IACs other than ASZMT impregnated with different kinds of materials. The implementation of this method has economic and environmental consequences. In the future, it may allow the reuse of aged IAC and even the restoration of filters.
]]>Environments doi: 10.3390/environments10120213
Authors: Ophela Zhang Mahdi Takaffoli Myriam Ertz Walid Addar
Given the scale of plastic generation, its persistent presence in the environment, and the urgent need to transition to a net-zero emissions paradigm, managing plastic waste has gained increasing attention globally. Developing an effective strategy for plastic waste management requires a comprehensive assessment of the potential benefits offered by different solutions, particularly with respect to their environmental impact. This study employs the life cycle assessment (LCA) methodology to evaluate the environmental impact of two alternative scenarios to the As-Is scenario for managing plastic waste in the province of British Columbia in Canada. The LCA results suggest that the Zero Plastic Waste scenario, which heavily relies on chemical recycling, may not inherently result in a reduced environmental footprint across all impact categories. This is notable when the focus is solely on end-of-life treatment processes, without considering the produced products and energy. The Intermediate scenario reduces the amount of plastic waste sent to landfills by directing more end-of-life plastic to mechanical recycling facilities. This scenario provides immediate benefits for resource conservation, with a minimal increase in the environmental burden resulting from treatment processes. Nonetheless, achieving a net-zero transition requires combining traditional and emerging recycling technologies. The current study could offer some guidance to policymakers on strategies for fostering more sustainable management of plastic waste.
]]>Environments doi: 10.3390/environments10120212
Authors: Emanuele Ferrentino Nicola Angelo Famiglietti Ferdinando Nunziata Giovanna Inserra Andrea Buono Raffaele Moschillo Antonino Memmolo Gerardo Colangelo Annamaria Vicari Maurizio Migliaccio
This study focuses on a very complex environment, namely the Ionian coast of the Basilicata region, Southern Italy, which includes different kinds of beaches, river mouths and built-up areas. This complex environment is used as a test case to analyze the time variability of the coastline using measurements that were remotely sensed by the satellite European Copernicus Synthetic Aperture Radar (SAR) mission. First, the accuracy of the coastline, extracted by the SAR, is discussed with respect to finer-spatial-resolution drone-based light detection and ranging (LIDAR) measurements. Then, a time series of SAR dual-polarimetric measurements acquired by the European Copernicus mission is used to discuss the time variability of the coastline of the area of interest in a time period spanning from 2015 to 2021. The experimental results show that the accuracy of the SAR-based coastline is better than 15 m, which is reasonably good precision for monitoring the erosion/accretion processes that characterize the area of interest at a moderate scale. The estimated time variability of the extracted coastline suggests a dominant erosion process, which is always within 60 m.
]]>Environments doi: 10.3390/environments10120211
Authors: Carmine Massarelli Claudia Campanale Vito Felice Uricchio
The coast of the Province of Brindisi, located in the south of Italy, is characterised by a large network of wetlands and coastal dunes of great ecological importance. These represent important habitats for flora and fauna, serving as feeding, breeding and migration areas for many bird species. Unfortunately, the state of health of some of these species is subject to various threats that put the ecological balance and local biodiversity at risk. It is essential to conduct regular and thorough monitoring over time to fully understand the presence of impacts on these ecosystems and to quickly take all necessary corrective measures to counter their main human-made threats, such as excessive urbanisation. This work reports the methods and results of the monitoring carried out along coastal dunes and a lagoon to identify their state of health and assess the presence of threatening factors capable of negatively altering their naturalness. The results indicate a situation of degradation affecting the coastal dunes but a good quality of the water resource. The study area is not currently affected by continuous monitoring programs and, therefore, we believe it is necessary to start a process in this sense, given the high naturalistic and historical value of the area. Finally, indications are provided to implement conservation measures to protect and preserve these precious coastal habitats, ensuring their survival for future generations.
]]>Environments doi: 10.3390/environments10120210
Authors: Fortatos Hadjigeorgiou Mountzouris Papadomichelakis
The excessive excretion of nitrogen (N) by farm animals can pose severe environmental risks. In this study, near-infrared reflectance (NIR) spectroscopy (NIRS) was used to explore the feasibility of developing a real-time in situ monitoring tool for fecal N excretion in rabbits. A total of 70 feed and 282 fecal samples from an in vivo digestibility experiment were used. Feed and fecal NIR spectra were employed to develop chemometric models using modified partial least squares (MPLS) for feed and feces, and artificial neural networks (ANN) for feces to predict dietary and fecal N content and fecal N digestibility. Very good accuracy was achieved in predicting feed N (R2val = 0.96; standard error of prediction, SEP = 0.15) and fecal N (R2val = 0.88; SEP = 0.44) content, whereas N digestibility models from wet fecal spectra had a relatively low precision (R2val = 0.70; SEP = 0.018) with MPLS methodology. In contrast, ANNs yielded more robust prediction models for fecal (R2val = 0.98; SEP = 0.25) N content and N digestibility (R2val = 0.91; SEP = 0.012) using wet feces. In conclusion, NIRS calibration with ANNs can be a suitable tool for monitoring the environmental load of N with high precision and accuracy.
]]>Environments doi: 10.3390/environments10120209
Authors: Dimitra Koumparou Spyridon K. Golfinopoulos
Water’s role in shaping human societies, economies, and cultures extends beyond its status as a natural resource. This water quality, the entanglement of the social and natural, constructs the waterscape. This paper discusses how a community fountain and its replica, in a rural community of Greece, constructed by different agents with divergent motivations and objective, form a waterscape, expressing the socionature of water. Perceptions, imaginaries, values, and connotations are considered in the making and (dis)continuity of the waterscape. Community practices, social and cultural meanings, economy, commodification, collective work, privatisation, memory, and nostalgia are schemes that flow within the waterscape, over time. Flows and uses, livability, and emotions display diverse patterns of sense of rootedness on the community space.
]]>Environments doi: 10.3390/environments10120208
Authors: Francesca Borghi Andrea Spinazzè Nicholas De Nardis Serena Straccini Sabrina Rovelli Giacomo Fanti Daniele Oxoli Andrea Cattaneo Domenico Maria Cavallo Maria Antonia Brovelli
Studies on air quality in rural environments are fundamental to obtain first-hand data for the determination of base emissions of air pollutants, to assess the impact of rural-specific airborne pollutants, to model pollutant dispersion, and to develop proper pollution mitigation technologies. The literature lacks a systematic review based on the evaluation of the techniques and methods used for the sampling/monitoring (S/M) of atmospheric pollutants in rural and agricultural settings, which highlights the shortcomings in this field and the need for future studies. This work aims to review the study design applied for on-field monitoring campaigns of airborne pollutants in rural environments and discuss the possible needs and future developments in this field. The results of this literature review, based on the revision of 23 scientific papers, allowed us to determine (i) the basic characteristics related to the study design that should always be reported; (ii) the main techniques and analyses used in exposure assessment studies conducted in this type of setting; and (iii) contextual parameters and descriptors of the S/M site that should be considered to best support the results obtained from the different studies. Future studies carried out to monitor the airborne pollution in rural/agriculture areas should (i) include the use of multiparametric monitors for the contextual measurement of different atmospheric pollutants (as well as meteorological parameters) and (ii) consider the most important boundary information, to better characterize the S/M site.
]]>Environments doi: 10.3390/environments10120207
Authors: Kristina Bule Možar Martina Miloloža Viktorija Martinjak Matija Cvetnić Vesna Ocelić Bulatović Vilko Mandić Arijeta Bafti Šime Ukić Dajana Kučić Grgić Tomislav Bolanča
Biodegradation is the most environmentally friendly and, at the same time, economically acceptable approach to removing various pollutants from the environment. However, its efficiency in removing microplastics (MPs) from the environment is generally low. The successful biodegradation of MPs requires microorganisms capable of producing enzymes that degrade MP polymers into compounds that the microorganisms can use as a source of carbon and energy. Therefore, scientists are screening and characterizing microorganisms that can degrade MPs more efficiently. These microorganisms are often isolated from sites contaminated with MPs because the microorganisms living there are adapted to these pollutants and should be able to better degrade MPs. In this study, five bacterial strains and five yeast strains were isolated from various environmental samples including activated sludge, compost, river sediment, and biowaste. Among them, screening was performed for bacteria and yeasts with the highest potential for the biodegradation of polystyrene (PS) and polyvinyl chloride (PVC) MPs, and the bacterium Delftia acidovorans and the yeast Candida parapsilosis were identified as the best candidates. Optimization of biodegradation of the selected MPs by each of these two microorganisms was performed, focusing on the influence of cell density, agitation speed and pH of the medium. It was found that within the selected experimental ranges, high values of cell density, low agitation speed, and a slightly basic medium favored the biodegradation of PS and PVC MPs by Delftia acidovorans. In the case of Candida parapsilosis, favorable conditions also included high cell density followed by a slightly higher, but not maximum, agitation speed and a weakly acidic medium. Broad spectroscopic and imaging methods indicated that Delftia acidovorans and Candida parapsilosis better adapt to PVC MPs to use it as a carbon and energy source.
]]>Environments doi: 10.3390/environments10120206
Authors: Shaoqing Zhang Jia-Qian Jiang
Neonicotinoid pesticides (NEOs) were initially considered viable alternatives to conventional organo-pesticides extensively used in agriculture, horticulture, and households. However, the increased frequency and concentration of NEOs in waterways have drawn significant attention and concern due to the resulting threats to ecosystems and public health worldwide. The demand for monitoring NEOs in water has led to numerous efforts in many countries and regions. Given occurrence and distribution of these pesticides/insecticides. This study reviews NEOs monitoring in China from 2019 to 2022, aiming to gather and analyse information on China’s efforts in NEOs monitoring to provide reference for future research. The study primarily focuses on the southern and southeastern regions of China, specifically on lakes and tributaries of rivers, including Taihu Lake, Pearl River, Yangtze River, Songhua River, and Liao River. This focus can be attributed to the prioritisation and environmental demands related to the local economic status and major developmental tasks. The evaluation of the corresponding ecological risks of human exposure to NEOs ranged from low to medium-high levels. However, despite these findings, contamination from NEOs is still considered to lack sufficient attention and concern. Additionally, the presence of NEOs in other environmental media, such as indoor dust, wheat grains, vegetables, and teas, requires close attention in the future.
]]>Environments doi: 10.3390/environments10120205
Authors: L. Holly Sweat Sidney J. Busch Casey A. Craig Emily Dark Tess Sailor-Tynes Jessy Wayles Paul E. Sacks Linda J. Walters
Estuaries worldwide are grappling with deteriorating water quality and benthic conditions that coincide with the rising detection of pathogenic and potentially pathogenic microbes (PPM). Both indigenous PPM and those that enter estuaries through urban and agricultural runoff are funneled through suspension-feeding organisms and deposited onto the benthos, where they can be moved through food webs. This study explored PPM communities in the Indian River Lagoon system, a biodiverse but urbanized estuary in east central Florida (USA). PPM were surveyed in estuary water, at stormwater outfalls, and in biodeposits of a key suspension feeder, the eastern oyster Crassostrea virginica. A total of 52 microbial exact sequence variants, with per-sample relative abundances up to 61.4%, were identified as PPM. The biodeposits contained relatively more abundant and diverse PPM than the water samples. PPM community composition also differed between seasons and between biodeposits and water. The community differences were driven primarily by Vibrio and Pseudoalteromonas spp. This investigation provides evidence that, through biodeposition, oyster reefs in the IRL estuary are a reservoir for PPM, and it documents some taxa of concern that should be conclusively identified and investigated for their pathogenicity and potential to pervade food webs and fisheries.
]]>Environments doi: 10.3390/environments10120204
Authors: Kieu Anh Nguyen Uma Seeboonruang Walter Chen
In this study, a machine learning model was used to investigate the potential consequences of climate change on vegetation growth. The methodology involved analyzing the historical Normalized Difference Vegetation Index (NDVI) data and future climate projections under four Shared Socioeconomic Pathways (SSPs). Data from the Global Inventory Monitoring and Modeling System (GIMMS) dataset for the period 1981–2000 were used to train the machine learning model, while CMIP6 (Coupled Model Intercomparison Project Phase 6) global climate projections from 2021–2100 were employed to predict future NDVI values under different SSPs. The study results revealed that the global mean NDVI is projected to experience a significant increase from the period 1981–2000 to the period 2021–2040. Following this, the mean NDVI slightly increases under SSP126 and SSP245 while decreasing substantially under SSP370 and SSP585. In the near-term span of 2021–2040, the average NDVI value of SSP585 slightly exceeds that of SSP245 and SSP370, suggesting a positive vegetation development in response to a more pronounced temperature increase in the near term. However, if the trajectory of SSP585 persists, the mean NDVI will commence a decline over the subsequent three periods (2041–2060, 2061–2080, and 2080–2100) with a faster speed than that of SSP370. This decline is attributed to the adverse effects of a rapid temperature rise on vegetation. Based on the examination of individual continents, it is projected that the NDVI values in Africa, South America, and Oceania will decline over time, except under the scenario SSP126 during 2081–2100. On the other hand, the NDVI values in North America and Europe are anticipated to increase, with the exception of the scenario SSP585 during 2081–2100. Additionally, Asia is expected to follow an increasing trend, except under the scenario SSP126 during 2081–2100. In the larger scope, our research findings carry substantial implications for biodiversity preservation, greenhouse gas emission reduction, and efficient environmental management. The utilization of machine learning technology holds the potential to accurately predict future changes in vegetation growth and pinpoint areas where intervention is imperative.
]]>Environments doi: 10.3390/environments10120203
Authors: Leah Feor Dan Murray Zachary Folger-Laronde Amelia Clarke
Even with the benefits of sustainability and climate change reporting, there is limited information on how municipalities are reporting on performance for external stakeholders in comparison with private sector organizations. The purpose of this research was to gain an understanding of the current state of sustainability and climate change reporting at the local level and to investigate the extent to which municipalities across Ontario, Canada, report. We used content analysis to identify the presence or non-presence of information on the websites of 38 municipalities and analyzed the results using descriptive statistics. Our analysis showed that the sample municipalities were not widely reporting on sustainability or climate change performance. Also, we identified a gap between the number of plans and reports produced by sample municipalities, with the latter being less common, indicating a need for an improved evaluation of plan implementation. Further, we found that a provincial regulation that required municipalities to make their energy conservation and demand management plans public did not guarantee publication of the plan on a municipality’s website. This study contributes to the growing field of sustainability and climate change planning and reporting by local governments and offers empirical evidence specific to Ontario, Canada.
]]>Environments doi: 10.3390/environments10120202
Authors: Marta Martins Maria Amélia Lemos Francisco Lemos Helena Pereira
Forest residues have been gaining interest as a source of renewable fuels due to their availability and the risks they represent for increasing forest fires. A major drawback for their removal and processing is the cost of transportation, which can be overcome through densification procedures, e.g., torrefaction. To optimize the torrefaction parameters, Cistus ladanifer residues from the Portuguese forest were torrefied for 30 min in a lab-scale reactor at 250 and 350 °C. The quality of the torrefied material was assessed, and its energy and mass yields were determined through thermal analysis. The changes in morphological structure occurring during torrefaction were analysed through scanning electron microscopy. When compared to the original biomass, the charcoal obtained at 350 °C had a substantial increase in energy density accompanied by a significant mass reduction. Increasing the mass in the reactor had a positive effect on the energy yield. For the highest mass tested, a mass reduction of around 30% was obtained and a char with no loss in energy content (with a cumulative heat flow (CHF) of 9.0 MJ/kg compared to 5.8 MJ/kg of the original biomass). Modelling of the reactor allowed the analysis of the heat profile required for torrefaction.
]]>Environments doi: 10.3390/environments10120201
Authors: Vaughan S. Langford Minyoung Cha Daniel B. Milligan Jihoon Lee
The pollution of air and water with volatile organic compounds (VOCs), both hazardous and odorous, is of significant concern due to impacts on human health and quality of life, as well as the environment. South Korea is a highly industrialized and densely populated nation and suffers from significant VOC and ozone pollution. In recent years, South Korea has implemented more stringent controls on industry to address air and water pollution, requiring more real-time and on-site analysis. The selected ion flow tube mass spectrometry (SIFT-MS) technique has been increasingly adopted to monitor source emissions and their dispersion, enabling a more rapid response to pollution incidents. To this end, the flexibility of SIFT-MS instrumentation for both laboratory- and field-based analysis, including in mobile laboratories, has been valuable. SIFT-MS has been applied to emission source characterization, fenceline monitoring, ambient monitoring, pollution mapping, and incident response (including the use of drone-based sampling) for hazardous air pollutants (HAPs), odor nuisance species, and compounds that have high ozone formation potential (OFP) and/or contribute to secondary aerosol (SOA) formation. This review summarizes the South Korean application of SIFT-MS to the monitoring of VOC pollutants.
]]>Environments doi: 10.3390/environments10120200
Authors: Yao Zheng Jiawen Hu Gangchun Xu
With the development of modern aquaculture, the number of pathogenic bacteria in fish farms has gradually risen. Studies have shown that traditional Chinese medicinal herbs and natural products have greatly contributed to reducing bacterial growth and reproduction. To explore the changes in different proportions of Houttuynia cordata Thunb and Jussiaea stipulacea on the bacterial composition in water, roots, and sediments, we conducted 16S rRNA gene sequencing on samples of the same to analyze floating beds (60% H. cordata Thunb and 30% H. cordata Thunb, 30% J. stipulacea named HcT1, HcT2, and Jr, respectively) after 30 days in the presence of tilapia culture water, roots, and sediments with bacterial community changes in the respective experimental groups. The results showed that 4811 bacterial operational taxonomic units (OTUs) were obtained; the alterations included decreased Spirochaetae, Nitrospirae, and Elusimicrobia in water; a significant increase in Tenericutes, Chlorobi, and Nitrospirae in HcT1 roots; and decreased Firmicutes and Fusobacteria in HcT2 and Jr roots. Actinobacteria, Nitrospirae, Tenericutes, and Chlamydiae increased in the HcT1 sediment; Fusobacteria and Fibrobacteres increased in the HcT2 sediment; and Cyanobacteria, Gemmatimonadetes, and Acidobacteria increased in the Jr sediment. H. cordata Thunb decreased Tenericutes and Deferribacteres, while Chlorobi, Nitrospirae, and Gemmatimonadetes increased with a 60% planting area, whereas Actinobacteria and Cyanobacteria increased with a 30% planting area, and Jr only increased Fusobacteria and Fibrobacteres. When planting with herbs, Proteobacteria increased, while Deferribacteres and Elusimicrobia decreased. The pathogenic genera may transfer among the water, plant roots, and sediments, and floating cultivation with herbs may be beneficial for blocking the spread of the pathogenic genera found in the samples.
]]>Environments doi: 10.3390/environments10120199
Authors: Agostina Tabilio Di Camillo Diana Maria Paola Galassi Barbara Fiasca Mattia Di Cicco Emma Galmarini Ilaria Vaccarelli Tiziana Di Lorenzo
Understanding trait selection factors is vital for decoding the processes shaping species’ assemblages. However, trait-based studies in freshwater crustacean copepod assemblages are scarce, especially in groundwater environments. We explored how environmental filtering influences functional traits in copepod assemblages across four freshwater habitats (an alluvial aquifer, a hyporheic zone, a stream benthic zone and a lake littoral) along a depth gradient. Each habitat had distinct environmental templates based on light, temperature and dissolved oxygen. We analysed 4898 individuals from 43 copepod species and examined 12 morphological and life history traits. The results revealed significant differences in copepod traits among habitats, notably in ovigerous female biomass, egg biomass and ovigerous female percentages. Furthermore, despite some statistical uncertainty, notable differences were also observed in the number of juveniles, male-to-female abundance ratios and overall biomass. No significant differences were observed in juvenile biomass, egg characteristics, body size dimorphism or juvenile-to-adult ratios among habitats. The trait variations offer insights into copepod-mediated ecosystem services, particularly carbon recycling. To gain a deeper understanding of copepod adaptations to environmental features and anthropogenic changes, future research should consider additional functional traits, such as locomotion and feeding habits.
]]>Environments doi: 10.3390/environments10120198
Authors: Laura Antiñolo Bermúdez Verónica Díaz Mendoza José Manuel Poyatos Capilla María del Mar Muñío Martínez Jaime Martín Pascual
The increasing prevalence of pharmaceutical substances in wastewater is emerging as a pressing ecological issue on a global scale. The purpose of this study was to evaluate the biological influence of pharmaceutical compounds on the heterotrophic biomass residing in a membrane bioreactor. The study examined the way microorganisms react to antibiotic and anti-inflammatory compounds, with the goal of proactively tackling potential issues and developing solutions that may emerge withing wastewater treatment plant bioreactors. Respirometric tests were carried out to determine the kinetic response of the heterotrophic biomass. The same study was carried out in the steady state of the plant under different conditions of hydraulic retention times (6 and 12 h) and biomass concentration (2888 ± 371 mg/L to 7477 ± 869 mg/L). A response surface statistical analysis was applied to determine the effect of the variables on the rate of substrate degradation for organic matter removal and the growth rate of net heterotrophic biomass. The results show that the biological response of the biomass is concerned when exposed to a combination of pharmaceutical substances such as ibuprofen, diclofenac, and erythromycin, in four cycles of operation at 16 varying concentrations of pharmaceuticals in each cycle. This suggests the presence of a synergistic effect among these pharmaceuticals, leading to a noticeable slower kinetic response in the biomass.
]]>Environments doi: 10.3390/environments10110197
Authors: Yuch-Ping Hsieh
Among the three major global carbon cycle components, the terrestrial one has been the most uncertain because of the complexity of the soil organic carbon (SOC) dynamics. Previous tracer studies, however, have shown that SOC consists of labile and resistant pools. Labile pools turn over in decades, and resistant pools turn over in hundreds or thousands of years. Labile pools are active in carbon and nutrient cycles and responsive to land-use management changes, whereas resistant pools are less so. Very few studies have actually quantified labile and resistant SOC pools because the isotopic tracer methods, such as the paired-plot bulk-carbon (PPBC) method, can only be applied to a few special cases. I found a study of SOC in the North America Great Plains, in which some of the data are suitable for the PPBC method. The results revealed that the turnover times of the labile SOC pools ranged from 17 years to 93 years, and the sizes ranged from 1.2 g kg−1 to 17.6 g kg−1. The turnover times of the resistant pools ranged from 899 years to 5138 years, and the sizes ranged from 5.0 g kg−1 to 12.4 g kg−1. Land management practices changed the sizes of the labile pools but not their turnover times. This study also pointed out a possibility that allows the application of the PPBC method to a set of much broader cases.
]]>Environments doi: 10.3390/environments10110196
Authors: Caterina Baars Jelena Barbir João Henrique Paulino Pires Eustachio
Global climate change, induced by anthropogenic causes, has severe consequences for Earth and its inhabitants. With the consequences already visible around the globe, one of them is the impact on food security. The lack of food security has serious impacts on health, especially in vulnerable populations who highly depend on a nutritious diet for a healthy life. The following research aims to assess the current research status of climate change, food security and health. In this context, the interlinkage of the three key concepts is analyzed, as well as the related health consequences. To achieve the aims of this research, a bibliometric analysis was conducted using VOSviewer, (version 1.6.16) including 453 papers. The data were retrieved from the Scopus database on 10 November 2022. Bibliometric analysis can illustrate emerging and key topic areas using keywords and co-occurrence analysis; hence, it is an adequate method to meet the listed research aims. Five different clusters have been derived from the analysis, each representing a different perspective on interlinkage. From the different clusters, the main consequences of climate change on food security could be derived, such as a decrease in crop yields, less availability of fish and livestock, or food contamination through mycotoxins. These can cause serious health implications, predominantly increasing the rate of malnutrition globally. The work showed the importance of action to prevent the consequences of climate change in relation to food security and health nexus. To do so, adaptation strategies are needed that consider the interdisciplinary scope of the problem, building sustainable measures that benefit each concept.
]]>Environments doi: 10.3390/environments10110195
Authors: Gabriela Coronel Vargas Alberto Izzotti Camillo Rosano Sebastiano La Maestra
In the past four decades, the Amazon rainforest has emerged as a crucial zone for crude oil extraction in the South American region. In the Ecuadorian Amazon rainforest, hydrocarbon blocks (called “bloques”) cover vast zones, including agricultural and livestock farms, protected natural regions and the territories of uncontacted indigenous tribes. This study proposes a micronuclei assay on Vicia faba following a 24 h exposure to various soil samples collected from Bloque 57 in Ecuador. Sampling was conducted between the Dayuma and Aguarico zones, approximately 30 km from Nueva Loja city. The research aimed to assess the impact of different soil samples, particularly those from areas affected by crude oil spills, to induce micronuclei and mitotic index changes in V. faba roots. Results: The soil pollution caused by crude oil is not the sole factor contributing to cytotoxicity and genotoxicity in V. faba. Most samples from areas polluted by crude oil outside the small-scale farm showed no significant difference in micronuclei rate compared to negative control and Amazon unpolluted soil. Conversely, samples from the small-scale farm displayed a statistically significant genotoxic effect. Furthermore, samples collected from open-air wastewater pools demonstrated higher levels of cytotoxicity compared to the controls and those from small-scale farms. The mitotic index was lower in seedlings exposed to wastewater in open-air pools, especially for the 20 cm deep samples. This phenomenon could be linked to bitumen-like substances and oils floating on the surface, attaching to the small roots and causing suffocation.
]]>Environments doi: 10.3390/environments10110194
Authors: Christian Ebere Enyoh Arti Devi Hirofumi Kadono Qingyue Wang Mominul Haque Rabin
Microplastics (MPs), small plastic particles resulting from the degradation of larger plastic items and from primary sources such as textiles, engineered plastic pellets, etc., have become a ubiquitous environmental pollutant. As their prevalence in the natural environment grows, concerns about their potential impacts on human health have escalated. This review discusses current research findings on the presence of MPs in organs such as the liver, blood, heart, placenta, breast milk, sputum, semen, testis, and urine, while also exploring plausible mechanisms of translocation. Furthermore, the review emphasizes the importance of understanding the potential toxicological effects of MPs on various physiological processes within these organs and their broader implications for human health. This review also examines the pathways through which MPs can enter and accumulate in human organs and bodily fluids, shedding light on the intricate routes of exposure and potential health implications. It is worth noting that the invasive medical procedures may permit direct access of MPs to the bloodstream and tissues, serving as a potential contamination source. However, it is evident that a comprehensive understanding of MPs’ invasion into human organs is vital for effective mitigation strategies and the preservation of both human health and the environment.
]]>Environments doi: 10.3390/environments10110193
Authors: Francesco Manna Mariagabriella Pugliese Fabrizio Ambrosino Marco Trifuoggi Antonella Giarra Giuseppe La Verde
Drinking water, in addition to the best-known chemical and biological agents, contains radionuclides of both natural and artificial origin, which can contribute significantly to the overall effective dose received by the population. The Italian Decree Law 28/2016, implementing the 2013/51/EURATOM Directive, establishes the activities for risk management and the parameter values for different radionuclide activity concentrations. In addition to the institutions involved, the National Inspectorate for Nuclear Safety and Radiation Protection (ISIN) annually publishes monitoring reports of environmental radioactivity in Italy, including radioactivity in drinking water. The purpose of the study was to integrate ISIN reports with 2018–2020 data by collecting measurements performed by institutional laboratories to obtain more complete information and adding, for the Campania region, some data not yet published. This new updated report was not significantly different from ISIN’s one, meaning that those publications are nevertheless extremely representative of the radioactivity in Italian drinking water. However, the study allowed us to obtain more detailed data, including measurements not considered in ISIN reports, for instance, radon-222 activity concentrations. This may be of great usefulness for all radiation protection stakeholders in order to ensure environmental protection, pollution prevention, and population safety.
]]>Environments doi: 10.3390/environments10110192
Authors: Spyridon Mavroulis Maria Mavrouli Efthymis Lekkas Athanasios Tsakris
Earthquakes have the potential to cause severe and widespread structural damage to buildings and infrastructure in the affected area. Earthquake debris mainly results from building collapses during intense ground motion and the emergency demolition of damaged and unstable buildings following a devastating earthquake. Debris management constitutes a major challenge that must be met by all those participating in disaster management as it poses threats to both the natural environment and public health in an earthquake-affected area. This narrative review examines the hazards that arise throughout the early phases of debris removal, when personnel operate in disaster-affected areas, to the last steps of sorting and disposal. Furthermore, emphasis is also given to the environmental impact caused by unregulated debris disposal on natural habitats that are highly sensitive and susceptible to hazardous substances and materials found in the debris. In the same framework, measures are proposed for alleviating the negative impacts of debris management on the well-being of all individuals involved, including workers, volunteers, and the local community, as well as the surrounding natural environment, encompassing soil, surface and groundwater, as well as air quality.
]]>Environments doi: 10.3390/environments10110191
Authors: Julio A. Poterico Luis Jaramillo-Valverde Nelis Pablo-Ramirez Vicky C. Roa-Linares Catalina Martinez-Jaramillo Sandra Alvites-Arrieta Milward Ubillus Diana Palma-Lozano Rony Castrejon-Cabanillas Samuel Davison Andres Gomez Heinner Guio
Background: Antibiotic resistance is a major public health concern globally. In this study, we aimed to evaluate the abundance and diversity of antibiotic resistance genes (ARGs) in sewage water samples from two hospitals and an adjacent community or urban setting in Huanuco, a Peruvian city located in the highlands. Methods: We collected samples from the community wastewater system and from sewage pipes from the two hospitals in Huanuco. DNA was extracted from 250 mL of sewage water samples (n = 6) and subjected to microbiome profiling using 16S rRNA short amplicon sequencing and shotgun metagenomics. We analyzed the taxonomic and functional content in all samples, including alpha and beta diversity metrics, and searched for ARGs. Results: Our results showed that samples taken from the community wastewater system were compositionally different and harbored greater bacterial taxonomic and functional diversity compared to samples collected from the hospitals’ wastewater system. We found a high abundance of bacteria associated with resistance to beta-lactams, macrolides, aminoglycosides, fluoroquinolones, and tetracyclines in all samples. However, there were no significant differences in the abundance or composition of ARGs between the community wastewater samples and those taken from the two hospitals. Conclusions: Our findings suggest that metagenomics analyses in wastewater sewage could be a useful tool for monitoring antibiotic resistance in urban settings. These data could be used to develop local public health policies, particularly in cities or countries with limited resources to establish large-scale One Health projects.
]]>Environments doi: 10.3390/environments10110190
Authors: Buddhadev Ghosh Pratap Kumar Padhy Soumya Niyogi Pulak Kumar Patra Markus Hecker
Air pollution is an immense problem due to its detrimental health effects on human populations. This study investigates the distribution of particle-bound heavy metals and associated health risks in three diverse areas (Durgapur as an industrial complex, Kolkata as an urban area, and Bolpur as a semi-urban region) in West Bengal, India. Twenty-one (84 samples) sampling sites were chosen, covering industrial, traffic, residential, and sensitive zones. The respirable suspended particulate matter (RSPM) samples were collected using a portable Mini-Vol Tactical Air Sampler, and heavy metal concentrations (Cd, Cr, Mn, Ni, Pb, and As) were analyzed using ICP-OES. The non-carcinogenic and carcinogenic health risks were assessed using exposure concentration (EC), hazard quotient (HQ), hazard index (HI), and additional lifetime cancer cases. The results highlight variations in heavy metal concentrations across the regions, with industrial areas exhibiting higher levels. Principal component analysis (PCA) unveiled distinct metal co-variation patterns, reflecting sources such as industrial emissions, traffic, and natural contributors. The sum of non-carcinogenic risks (HI) of all heavy metals exceeded the US EPA’s risk limit (HI<1) in both Kolkata and Durgapur, except for Bolpur. Similarly, the sum of cancer risk in three distinct areas exceeded the USEPA limits (1.00E-06). The Monte Carlo simulation revealed the 5th and 95th percentile range of cancer risk was 9.12E-06 to 1.12E-05 in Bolpur, 3.72E-05 to 4.49E-05 in Durgapur and 2.13E-05 to 2.57E-05 in Kolkata. Kolkata had the highest additional lifetime cancer cases compared to Bolpur and Durgapur. This study provides information on the complex connections between heavy metal pollution and possible health risks in industrial, urban, and semi-urban regions.
]]>Environments doi: 10.3390/environments10110189
Authors: Noelia Trigo-Tasende Juan A. Vallejo Soraya Rumbo-Feal Kelly Conde-Pérez Mohammed Nasser-Ali Javier Tarrío-Saavedra Inés Barbeito Fernando Lamelo Ricardo Cao Susana Ladra Germán Bou Margarita Poza
Wastewater-based epidemiology (WBE) has become an effective tool in the surveillance of infectious diseases such as COVID-19. In this work, we performed a brief study of monitoring the SARS-CoV-2 viral load in wastewater from six nursing homes located in the metropolitan area of A Coruña (Spain) between December 2020 and March 2021. The main objective was to detect SARS-CoV-2 outbreaks among residents and study the efficacy of the vaccination campaign. SARS-CoV-2 viral load (RNA copies per L of wastewater) was determined by reverse-transcription quantitative PCR (RT-qPCR) using the quantification cycle (Cq) values for the nucleocapsid (N) gene. Our results showed that the increase in viral load preceded the increase in clinical cases, favoring an early warning system that detects COVID-19 outbreaks in advance, making it possible to contain and stop the transmission of the virus among residents. In addition, the efficacy of the new COVID-19 vaccines was evidenced, since after the vaccination campaign in nursing homes in A Coruña, it was observed that many residents did not present any symptoms of the disease, although they excreted high amounts of virus in their feces. WBE is a cost-effective strategy that should be implemented in all cities to prevent new emerging diseases or future pandemic threats.
]]>Environments doi: 10.3390/environments10110188
Authors: Monika R. Snowdon Robert F. L. Liang Avneet Kaur Erika A. Burton Shasvat Rathod Wenkai Fang Hadi A. Dhiyebi Leslie M. Bragg Norman Y. Zhou Mark R. Servos Marina Freire-Gormaly
We investigated the effectiveness of TiO2 cenospheres in reducing the concentrations of three common harmful compounds, ammonium, nitrate, and nitrite, in fish aquariums. These cenospheres can contribute to more sustainable and eco-friendly aquarium filtration systems while also improving the health of fish. We designed a 30-day experiment with three treatment groups based on the filter type: (1) a control group with a conventional aquarium filter, (2) a group with a TiO2 cenosphere filter, and (3) a group with a dark TiO2 cenosphere filter. The water quality was the same baseline in all groups, and each tank was monitored daily for changes in temperature, pH, ammonia, nitrate, and nitrite concentrations. We found that the TiO2 cenosphere filter was effective in reducing the concentrations of all three pollutants. By the end of the experimental period, the average concentration of nitrite in the control group was 10.7 µM, while the average concentration in the TiO2 cenosphere filter group dropped 55% to 4.7 µM from the baseline. The average concentration of nitrate was reduced by 17% and ammonia by 28% in the cenosphere-treated group. Hence, the cenospheres were effective in reducing the concentrations of all three pollutants, with the greatest reduction seen for nitrite. These findings support further investigation for incorporating TiO2 cenospheres into aquarium filtration to help reduce the environmental burden of the aquarium industry.
]]>Environments doi: 10.3390/environments10110187
Authors: Rafael Rodríguez Zenaida Hernández Begoña Fernández Marc Bascompta
Mercury (Hg) emissions into the air can in some cases be a critical problem for public health and environmental protection. Hence, it is crucial to find cost-effective solutions to tackle this issue. An innovative solution is presented in this study using two case studies, diminishing drastically the emissions through covering high Hg-contaminated debris with industrial subproducts (fly-ashes and blast furnace slags). This solution is compared with other two conventional alternatives: (1) removal of the debris to an authorized landfill and (2) in situ encapsulation. The analysis is carried out by comparing costs, carbon footprint and the Environmental–Social–Governance (ESG) impact. It has been noted that the solution proposed has some advantages with respect to conventional alternatives, from both economic and environmental points of view, presenting lower costs and a lower carbon footprint. The worst solution is to remove the debris for ex situ treatment, while the encapsulation represents a middle solution with advantages and disadvantages. The findings of the study can be a step forward in the usage of industrial subproducts, that are currently placed in waste disposal, to solve the problem of sites contaminated by mercury and eliminate its emissions.
]]>Environments doi: 10.3390/environments10100186
Authors: Bruna Rijo Ana Paula Soares Dias Nicole de Jesus Manuel Francisco Pereira
With the increase in population, large amounts of food waste are produced worldwide every day. These leftovers can be used as a source of lignocellulosic waste, oils, and polysaccharides for renewable fuels. In a fixed bed reactor, low-temperature catalytic pyrolysis was investigated using biomass gathered from domestic garbage. Thermogravimetry, under N2 flow, was used to assess the pyrolysis behavior of tea and coffee grounds, white potato, sweet potato, banana peels, walnut, almonds, and hazelnut shells. A mixture of biomass was also evaluated by thermogravimetry. Waste inorganic materials (marble, limestone, dolomite, bauxite, and spent Fluid Catalytic Cracking (FCC) catalyst) were used as catalysts (16.7% wt.) in the pyrolysis studies at 400 °C in a fixed bed reactor. Yields of bio-oil in the 22–36% wt. range were attained. All of the catalysts promoted gasification and a decrease in the bio-oil carboxylic acids content. The marble dust catalyst increased the bio-oil volatility. The results show that it is possible to valorize lignocellulosic household waste by pyrolysis using inorganic waste materials as catalysts.
]]>Environments doi: 10.3390/environments10100185
Authors: Arindam Malakar Sanjit Das Samirul Islam Rajneesh Singh Sugata Ray
For arsenic decontamination from groundwater, arsenic crystallization is becoming adopted due to its sustainability and economic benefits. However, arsenic crystallization technology is a two-step process, which makes it complex and generates hazardous waste. Successful efforts toward making it a single-step process are presented here. The addition of nanorods and ball-milled zinc sulfide nanoparticles to arsenic-contaminated water result in highly monodispersed and high-arsenic-containing mineralized nanowaste with a crystalline structure similar to the mineral Tooeleite ((Fe3+6(As3+O3)4SO4(OH)4·4H2O)). This study reports the results of a short-term stability test based on a toxicity characteristic leaching procedure and a long-term stability test of the mineralized synthetic nanowaste produced from water treatment. The Tooeleite-like mineralized nanowaste passed short-term stability tests. Arsenic in the leachate were found to be 1.1 ± 0.2 mg L−1 and 4.8 ± 0.3 mg L−1 from waste generated by the nanorod and ball-milled nanoparticles, respectively. The crystallinity was well preserved, as observed from the post-stability-test diffraction patterns, consequently proving that the waste product can be non-hazardous and therefore would not require any secondary treatment before final disposal.
]]>Environments doi: 10.3390/environments10100184
Authors: Kwanyong Lee Hung-Soo Joo
Aerobic denitrifier Alcaligenes faecalis No. 4 removes ammonium-nitrogen to nitrogen gas via denitrification in a single aerobic condition. In our previous studies, factors such as ammonium removal rate, denitrification ratio, and cell growth were tested in various conditions. The removal pathway from ammonium to nitrogen gas still needs to be determined in detail. To clarify this pathway of Alcaligenes faecalis No. 4, we in this study investigated the effects of several factors on ammonium removal, such as foam-recycle, initial pH, initial ammonium concentration, and airflow rate. Denitrification ratio was improved by up to 23% through foam-recycle. The improvement of the denitrification ratio was resulted by the higher enzyme activity of hydroxylamine oxidoreductase (HAO) in the produced foam, which was about 28 times higher than that in the culture broth (i.e., without foam-recycle). The stripped ammonia was significantly high (above pH 9). The initial ammonium concentration and airflow rate also influenced the denitrification ratio.
]]>Environments doi: 10.3390/environments10100183
Authors: Lidia Kim Adriana Cuciureanu Luoana Florentina Pascu Oana Cătălina Tache (Țăpurică) Gina Alina Catrina (Trăistaru)
In the European Union List of Wastes, the category of “mirror entry” waste refers to either hazardous or non-hazardous waste, depending on their composition and specificity. Classifying waste as hazardous or non-hazardous is essential because it influences the feasibility and economic viability of subsequent management methods. Thus, waste classification represents a challenge both for the scientific community and for the producers/holders of waste. The methodology presented in this paper describes the stages that are the basis for evaluating the dangerousness of “mirror entry” waste and the potential factors that influence the evaluation process. Three case studies that represented three types of industrial waste were selected: waste from the non-metallic minerals industry (W1), waste from glass manufacturing (W2), and waste from the iron and steel industry (W3). The case studies were characterized and evaluated according to hazardous properties and the assignment of a waste code. The W1 and W2 waste samples did not present the hazardous properties HP1–HP15 and were included in the non-hazardous waste list. The W3 waste sample exhibited five dangerous properties and was classified as hazardous waste. The assessed wastes maintain the classifications as long as there are no changes in the technological process generation and in their composition.
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