A New Macrodiolide and Two New Polycyclic Chromones from the Fungus Penicillium sp. SCSIO041218
Abstract
:1. Introduction
2. Results
3. Experimental Section
3.1. General Experimental Procedures
3.2. Fungal Material
3.3. Fermentation and Purification
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample Availability: Samples of the compounds 1–7 are available from the authors. |
Position | δH, mult, J in Hz | δC |
---|---|---|
1 | 172.0 | |
2 | 2.83 dd (12.5, 3.5) | 33.4 |
2.67 dd (12.5, 5.5) | ||
3 | 3.05 m | 35.8 |
4 | 2.52 m | 27.8 |
2.14 m | ||
5 | 4.43 td (6.5, 1.5) | 66.8 |
4.29 ddd (9.0, 5.0, 5.0) | ||
6 | 179.6 | |
OMe | 3.71 s | 50.8 |
1’ | 172.2 | |
2’ | 2.59 dd (5.0, 1.5) | 36.1 |
3’ | 2.99 dt (11.5, 5.0) | 31.8 |
4’ | 2.75 dd (12.5, 6.5) | 33.3 |
2.36 dd (12.5, 5.5) | ||
5’ | 178.1 | |
6’ | 4.55 dd (6.5, 5.5) | 72.8 |
4.06 dd (6.5, 5.0) | ||
OMe | 3.70 s | 50.9 |
Position | 2 | 3 | ||
---|---|---|---|---|
δH, mult, J in Hz | δC | δH, mult, J in Hz | δC | |
1 | 156.9 | 156.9 | ||
2 | 6.44 d (8.5) | 107.9 | 6.45 d (8.0) | 107.9 |
3 | 7.39 t (8.5) | 138.5 | 7.40 t (8.0) | 138.5 |
4 | 6.59 d (8.5) | 111.3 | 6.60 d (8.0) | 111.4 |
5 | 163.4 | 163.4 | ||
6 | 105.8 | 106.0 | ||
7 | 191.0 | 191.1 | ||
8 | 61.2 | 61.2 | ||
9 | 193.6 | 193.5 | ||
10 | 6.03 s | 127.0 | 6.02 s | 127.1 |
11 | 160.1 | 160.0 | ||
12 | 86.1 | 86.2 | ||
13 | 92.4 | 92.4 | ||
14α | 2.59 dd (7.0, 15.0) | 32.0 | 2.60 dd (7.0, 15.0) | 32.0 |
14β | 2.46 dd (10.0, 15.0) | 2.46 dd (10.0, 14.5) | ||
15 | 3.73 m | 52.5 | 3.74 t (8.0) | 52.5 |
16 | 170.8 | 171.2 | ||
17 | 2.02 s | 19.2 | 2.00 s | 19.0 |
18 | 1.38 s | 13.4 | 1.37 s | 13.4 |
19 | 4.26 m | 61.7 | 3.76 s | 52.5 |
20 | 1.29 t (7.5) | 14.2 |
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Huang, J.; She, J.; Yang, X.; Liu, J.; Zhou, X.; Yang, B. A New Macrodiolide and Two New Polycyclic Chromones from the Fungus Penicillium sp. SCSIO041218. Molecules 2019, 24, 1686. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules24091686
Huang J, She J, Yang X, Liu J, Zhou X, Yang B. A New Macrodiolide and Two New Polycyclic Chromones from the Fungus Penicillium sp. SCSIO041218. Molecules. 2019; 24(9):1686. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules24091686
Chicago/Turabian StyleHuang, Jingxia, Jianglian She, Xiliang Yang, Juan Liu, Xuefeng Zhou, and Bin Yang. 2019. "A New Macrodiolide and Two New Polycyclic Chromones from the Fungus Penicillium sp. SCSIO041218" Molecules 24, no. 9: 1686. https://0-doi-org.brum.beds.ac.uk/10.3390/molecules24091686