Turnover Rate of Metal-Catalyzed Hydroconversion of 2,5-Dimethylfuran: Gas-Phase Versus Liquid-Phase
Abstract
:1. Introduction
2. Results and Discussion
2.1. Gas-Phase Hydroconversion of DMF over Carbon-Supported Noble Metal Catalysts
2.2. Turnover Rate: Gas Phase Versus Liquid Phase
2.3. Hydrogenolysis of Tetrahydrofuran and 2,5-Dimethyltetrahydrofuran
3. Materials and Methods
3.1. Chemicals and Catalysts
3.2. Techniques
3.3. Catalyst Testing
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Catalyst 2 | W/F | Conv. 3 (%) | Product Selectivity 3 (%) | ||||
---|---|---|---|---|---|---|---|
(g·h·mol−1) | Hexane | DMTHF 4 | 2-Hexanone | 2-Hexanol | Other | ||
9.6%Pt/C + SiO2 (20) | 25 | >99 | 11.6 | 13.1 | 0.9 | 72.5 | 1.9 |
9.6%Pt/C + SiO2 (20) 5 | 25 | >99 | 8.8 | 10.7 | 2.1 | 74.2 | 4.2 |
7.0%Pt/C + SiO2 (100) 5,6 | 125 | >99 | 19.8 | 7.3 | 4.6 | 61.4 | 6.9 |
7.8%Pd/C + SiO2 (25) | 31 | >99 | 0.0 | 99.8 | 0.0 | 0.0 | 0.2 |
3.0%Ru/C + SiO2 (67) | 83 | >99 | 0.0 | 94.6 | 0.0 | 4.7 | 0.6 |
4.0%Rh/C + SiO2 (40) | 50 | >99 | 0.0 | 99.6 | 0.0 | 0.3 | 0.1 |
Catalyst 2 | W/F (g·h·mol−1) | Conv. 3 (%) | TOF 4 (s−1) | Product Selectivity 3 (%) | ||||
---|---|---|---|---|---|---|---|---|
Hexane | DMTHF 5 | 2-Hexanone | 2-Hexanol | Other | ||||
9.6%Pt/C (1.0) | 0.63 | 24.2 | 5.6 | 3.3 | 12.9 | 61.3 | 20.8 | 1.7 |
9.6%Pt/C (0.7) 6 | 0.44 | 42.8 | 14 | 5.2 | 10.5 | 60.0 | 23.3 | 1.0 |
4.0%Rh/C (0.2) | 0.13 | 48.8 | 5.4 | 0.0 | 83.6 | 1.4 | 0.0 | 15.0 |
7.8%Pd/C (0.6) | 0.38 | 60.7 | 1.9 | 0.0 | 99.2 | 0.2 | 0.0 | 0.6 |
3.0%Ru/C (3.0) | 1.88 | 12.1 | 0.26 | 0.0 | 84.2 | 6.6 | 1.2 | 8.0 |
Catalyst | W/F (h·g·mol−1) | Conversion 2 (%) | Product Selectivity 2 (%) | |
---|---|---|---|---|
Butane | 1-Butanol | |||
9.6%Pt/C + SiO2 (20) | 7.0 | 0.6 | 6.5 | 93.5 |
7.8%Pd/C + SiO2 (25) | 8.8 | 0.0 |
Catalyst | W/F | Temp. (°C) | Conv. 2 (%) | Product Selectivity 2 (%) | |||
---|---|---|---|---|---|---|---|
(h·g·mol−1) | Hexane | 2-Hexanone | 2-Hexanol | Other | |||
9.6%Pt/C + SiO2 (20) | 17.3 | 90 | 1.6 | 8.1 | 1.4 | 87.6 | 2.9 |
9.6%Pt/C + SiO2 (20) | 17.3 | 100 | 2.9 | 7.4 | 2.7 | 88.3 | 1.7 |
7.8%Pd/C + SiO2 (25) | 21.8 | 100 | 0.1 | 67.0 | 0.0 | 0.0 | 33.0 |
Parameter | DMF 2 | DMTHF 3 | THF 4 |
---|---|---|---|
W/F (g·h·mol−1) | 0.44 | 70 | 42 |
Conversion (%) | 42.8 | 2.8 | 0.67 |
TOF (s−1) 5 | 14 | 0.0058 | 0.0023 |
Catalyst | Surface Area 1 (m2 g−1) | Pore Volume 2 (cm3 g−1) | Pore Diameter 3 (Å) | D4 |
---|---|---|---|---|
7.8%Pd/C | 820 | 0.561 | 27 | 0.326 ± 0.034 |
3.0%Ru/C | 1108 | 0.935 | 34 | 0.232 ± 0.010 |
4.0%Rh/C | 830 | 0.703 | 34 | 0.513 ± 0.032 |
9.6%Pt/C 5 | 713 | 0.558 | 31 | 0.039 ± 0.007 |
7.0%Pt/C 5 | 746 | 0.581 | 31 | 0.039 ± 0.010 |
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Althikrallah, H.; Kunstmann-Olsen, C.; Kozhevnikova, E.F.; Kozhevnikov, I.V. Turnover Rate of Metal-Catalyzed Hydroconversion of 2,5-Dimethylfuran: Gas-Phase Versus Liquid-Phase. Catalysts 2020, 10, 1171. https://0-doi-org.brum.beds.ac.uk/10.3390/catal10101171
Althikrallah H, Kunstmann-Olsen C, Kozhevnikova EF, Kozhevnikov IV. Turnover Rate of Metal-Catalyzed Hydroconversion of 2,5-Dimethylfuran: Gas-Phase Versus Liquid-Phase. Catalysts. 2020; 10(10):1171. https://0-doi-org.brum.beds.ac.uk/10.3390/catal10101171
Chicago/Turabian StyleAlthikrallah, Hanan, Casper Kunstmann-Olsen, Elena F. Kozhevnikova, and Ivan V. Kozhevnikov. 2020. "Turnover Rate of Metal-Catalyzed Hydroconversion of 2,5-Dimethylfuran: Gas-Phase Versus Liquid-Phase" Catalysts 10, no. 10: 1171. https://0-doi-org.brum.beds.ac.uk/10.3390/catal10101171